In this paper, the treatment of phenol-containing wastewater is studied by using UV/H 2O 2 system in a bench scale. The influence factors including concentration of H 2O 2 and phenol, pH, and some metal ions are inves...In this paper, the treatment of phenol-containing wastewater is studied by using UV/H 2O 2 system in a bench scale. The influence factors including concentration of H 2O 2 and phenol, pH, and some metal ions are investigated. The addition of H 2O 2 was favorable to the removal of phenol, however, the excess of H 2O 2 does not significantly affect the removal efficiency. It has shown that changes in reaction rates are rather insignificant over a wide pH range from 3 to 8. The co-existence of metal ions has significant influence upon the photocatalytic reaction rates, Fe 2+ increases the reaction rates, but Co 2O 3 and Zn 2+ given negative results. The mechanism of the reaction process is also discussed with chromatograms of phenol and its intermediate products.展开更多
The adsorption and separation of β nephthalenesulfonic acid(NSA) from synthetic waste water by microporous resins have been investigated as function of temperature, acidity and co existed acids. The thermodynamic par...The adsorption and separation of β nephthalenesulfonic acid(NSA) from synthetic waste water by microporous resins have been investigated as function of temperature, acidity and co existed acids. The thermodynamic parameters have been preliminary calculated. The kinetic study for the adsorption process indicated resin Indion 860 appeared an effective adsorbent for NSA.展开更多
文摘In this paper, the treatment of phenol-containing wastewater is studied by using UV/H 2O 2 system in a bench scale. The influence factors including concentration of H 2O 2 and phenol, pH, and some metal ions are investigated. The addition of H 2O 2 was favorable to the removal of phenol, however, the excess of H 2O 2 does not significantly affect the removal efficiency. It has shown that changes in reaction rates are rather insignificant over a wide pH range from 3 to 8. The co-existence of metal ions has significant influence upon the photocatalytic reaction rates, Fe 2+ increases the reaction rates, but Co 2O 3 and Zn 2+ given negative results. The mechanism of the reaction process is also discussed with chromatograms of phenol and its intermediate products.
文摘The adsorption and separation of β nephthalenesulfonic acid(NSA) from synthetic waste water by microporous resins have been investigated as function of temperature, acidity and co existed acids. The thermodynamic parameters have been preliminary calculated. The kinetic study for the adsorption process indicated resin Indion 860 appeared an effective adsorbent for NSA.