In this paper,the synthesis of a novel polyoxovanadiumborate Cd_(0.75) Na_2 Ni_(0.5) [V_(12) B_(18) O_(50.5)(OH)_(9.5)]·27.5 H_2 O by hydrothermal method.The compound consists of metal M(Cd,Na,Ni)and V_(12) B_(18...In this paper,the synthesis of a novel polyoxovanadiumborate Cd_(0.75) Na_2 Ni_(0.5) [V_(12) B_(18) O_(50.5)(OH)_(9.5)]·27.5 H_2 O by hydrothermal method.The compound consists of metal M(Cd,Na,Ni)and V_(12) B_(18) O_(60) cluster units connected through the M-O bond to form a three-dimensional structure.We performed a series of characterizations of Compound 1 of our team and tested its fluorescence properties at the same time.The luminescence investigations show that the compound 1 displays an interesting luminescence property.The compound 1 exhibits a good potential as a luminescent multi-responsive sensing material for Fe^(3+)ions.展开更多
基金supported by the NNSFC(21473030,1371033)the Natural Science Foundation of Fujian Province(2013J01042)
文摘In this paper,the synthesis of a novel polyoxovanadiumborate Cd_(0.75) Na_2 Ni_(0.5) [V_(12) B_(18) O_(50.5)(OH)_(9.5)]·27.5 H_2 O by hydrothermal method.The compound consists of metal M(Cd,Na,Ni)and V_(12) B_(18) O_(60) cluster units connected through the M-O bond to form a three-dimensional structure.We performed a series of characterizations of Compound 1 of our team and tested its fluorescence properties at the same time.The luminescence investigations show that the compound 1 displays an interesting luminescence property.The compound 1 exhibits a good potential as a luminescent multi-responsive sensing material for Fe^(3+)ions.
