It is urgent to develop catalysts with application potential for oxidative coupling of methane(OCM)at relatively lower temperature.Herein,three-dimensional ordered macro porous(3 DOM)La_(2-x)Sr_(x)Ce_(2-y)CayO_(7-δ)(...It is urgent to develop catalysts with application potential for oxidative coupling of methane(OCM)at relatively lower temperature.Herein,three-dimensional ordered macro porous(3 DOM)La_(2-x)Sr_(x)Ce_(2-y)CayO_(7-δ)(A_(2)B_(2)O_(7)-type)catalysts with disordered defective cubic fluorite phased structure were successfully prepared by a colloidal crystal template method.3DOM structure promotes the accessibility of the gaseous reactants(O2and CH4)to the active sites.The co-doping of Ca and Sr ions in La_(2-x)Sr_(x)Ce_(2-y)CayO_(7-δ)catalysts improved the formation of oxygen vacancies,thereby leading to increased density of surface-active oxygen species(O_(2)^(-))for the activation of CH4and the formation of C2products(C2H6and C2H4).3DOM La_(2-x)Sr_(x)Ce_(2-y)CayO_(7-δ)catalysts exhibit high catalytic activity for OCM at low temperature.3DOM La1.7Sr0.3Ce1.7Ca0.3O7-δcatalyst with the highest density of O_(2)^(-)species exhibited the highest catalytic activity for low-temperature OCM,i.e.,its CH4conversion,selectivity and yield of C2products at 650℃are 32.2%,66.1%and 21.3%,respectively.The mechanism was proposed that the increase in surface oxygen vacancies induced by the co-doping of Ca and Sr ions boosts the key step of C-H bond breaking and C-C bond coupling in catalyzing low-temperature OCM.It is meaningful for the development of the low-temperature and high-efficient catalysts for OCM reaction in practical application.展开更多
The Domain Name System(DNS) is suffering from the vulnerabilities exploited to launch the cache poisoning attack. Inspired by biodiversity, we design and implement a non-intrusive and tolerant secure architecture Mult...The Domain Name System(DNS) is suffering from the vulnerabilities exploited to launch the cache poisoning attack. Inspired by biodiversity, we design and implement a non-intrusive and tolerant secure architecture Multi-DNS(MDNS) to deal with it. MDNS consists of Scheduling Proxy and DNS server pool with heterogeneous DNSs in it. And the Scheduling Proxy dynamically schedules m DNSs to provide service in parallel and adopts the vote results from majority of DNSs to decide valid replies. And benefit from the centralized control of software defined networking(SDN), we implement a proof of concept for it. Evaluation results prove the validity and availability of MDNS and its intrusion/fault tolerance, while the average delay can be controlled in 0.3s.展开更多
Software.defined networking(SDN) enables third.part companies to participate in the network function innovations. A number of instances for one network function will inevitably co.exist in the network. Although some o...Software.defined networking(SDN) enables third.part companies to participate in the network function innovations. A number of instances for one network function will inevitably co.exist in the network. Although some orchestration architecture has been proposed to chain network functions, rare works are focused on how to optimize this process. In this paper, we propose an optimized model for network function orchestration, function combination model(FCM). Our main contributions are as following. First, network functions are featured with a new abstraction, and are open to external providers. And FCM identifies network functions using unique type, and organizes their instances distributed over the network with the appropriate way. Second, with the specialized demands, we can combine function instances under the global network views, and formulate it into the problem of Boolean linear program(BLP). A simulated annealing algorithm is designed to approach optimal solution for this BLP. Finally, the numerical experiment demonstrates that our model can create outstanding composite schemas efficiently.展开更多
The vibrational motions are usually neglected when calculating(e,2e) triple differential cross sections(TDCSs) of molecules. Here, multi-center distorted-wave method(MCDW) has been modified by including molecular vibr...The vibrational motions are usually neglected when calculating(e,2e) triple differential cross sections(TDCSs) of molecules. Here, multi-center distorted-wave method(MCDW) has been modified by including molecular vibrations. This vibrational MCDW method is employed to calculate the TDCSs of 1b3gorbital of ethylene at low(100 eV) and medium(250 eV) incident electron energies in coplanar asymmetric kinematic condition. The results show that molecular vibrations significantly influence the angular distributions of the TDCSs, especially in the binary region along momentum transfer near the Bethe ridge.展开更多
We report theoretical studies of electron impact triple differential cross sections of two bio-molecules,pyrimidine and tetrahydrofurfuryl alcohol,in the coplanar asymmetric kinematic conditions with the impact energy...We report theoretical studies of electron impact triple differential cross sections of two bio-molecules,pyrimidine and tetrahydrofurfuryl alcohol,in the coplanar asymmetric kinematic conditions with the impact energy of 250 eV and ejected electron energy of 20 eV at three scattering angles of-5°,-10°,and-15°.Present multi-center distorted-wave method well describes the experimental data,which was obtained by performing(e,2e)experiment.The calculations show that the secondary electron produced by the primary impact electron is strongly influenced by the molecular ionic multi-center potential,which must be considered when the low energy electron interacts with DNA analogues.展开更多
基金supported by the National Key Research and Development Program of China(Nos.2022YFB3504100,2022YFB3506200)the National Natural Science Foundation of China(Nos.22208373,22376217)+1 种基金the Beijing Nova Program(No.20220484215)the Science Foundation of China University of Petroleum,Beijing(No.2462023YJRC030)。
文摘It is urgent to develop catalysts with application potential for oxidative coupling of methane(OCM)at relatively lower temperature.Herein,three-dimensional ordered macro porous(3 DOM)La_(2-x)Sr_(x)Ce_(2-y)CayO_(7-δ)(A_(2)B_(2)O_(7)-type)catalysts with disordered defective cubic fluorite phased structure were successfully prepared by a colloidal crystal template method.3DOM structure promotes the accessibility of the gaseous reactants(O2and CH4)to the active sites.The co-doping of Ca and Sr ions in La_(2-x)Sr_(x)Ce_(2-y)CayO_(7-δ)catalysts improved the formation of oxygen vacancies,thereby leading to increased density of surface-active oxygen species(O_(2)^(-))for the activation of CH4and the formation of C2products(C2H6and C2H4).3DOM La_(2-x)Sr_(x)Ce_(2-y)CayO_(7-δ)catalysts exhibit high catalytic activity for OCM at low temperature.3DOM La1.7Sr0.3Ce1.7Ca0.3O7-δcatalyst with the highest density of O_(2)^(-)species exhibited the highest catalytic activity for low-temperature OCM,i.e.,its CH4conversion,selectivity and yield of C2products at 650℃are 32.2%,66.1%and 21.3%,respectively.The mechanism was proposed that the increase in surface oxygen vacancies induced by the co-doping of Ca and Sr ions boosts the key step of C-H bond breaking and C-C bond coupling in catalyzing low-temperature OCM.It is meaningful for the development of the low-temperature and high-efficient catalysts for OCM reaction in practical application.
基金partly supported by the National key Research and Development Program of China (No.2016YFB0800100, 2016YFB0800101)the National Natural Science Fund for Creative Research Groups Project (No.61521003)the National Natural Science Fund for Youth Found Project (No.61602509)
文摘The Domain Name System(DNS) is suffering from the vulnerabilities exploited to launch the cache poisoning attack. Inspired by biodiversity, we design and implement a non-intrusive and tolerant secure architecture Multi-DNS(MDNS) to deal with it. MDNS consists of Scheduling Proxy and DNS server pool with heterogeneous DNSs in it. And the Scheduling Proxy dynamically schedules m DNSs to provide service in parallel and adopts the vote results from majority of DNSs to decide valid replies. And benefit from the centralized control of software defined networking(SDN), we implement a proof of concept for it. Evaluation results prove the validity and availability of MDNS and its intrusion/fault tolerance, while the average delay can be controlled in 0.3s.
基金supported by the China Postdoctoral Fund Project (No.44603)the National Natural Science Foundation of China (No.61309020)+1 种基金the National key Research and Development Program of China (No.2016YFB0800100, 2016YFB0800101)the National Natural Science Fund for Creative Research Groups Project(No.61521003)
文摘Software.defined networking(SDN) enables third.part companies to participate in the network function innovations. A number of instances for one network function will inevitably co.exist in the network. Although some orchestration architecture has been proposed to chain network functions, rare works are focused on how to optimize this process. In this paper, we propose an optimized model for network function orchestration, function combination model(FCM). Our main contributions are as following. First, network functions are featured with a new abstraction, and are open to external providers. And FCM identifies network functions using unique type, and organizes their instances distributed over the network with the appropriate way. Second, with the specialized demands, we can combine function instances under the global network views, and formulate it into the problem of Boolean linear program(BLP). A simulated annealing algorithm is designed to approach optimal solution for this BLP. Finally, the numerical experiment demonstrates that our model can create outstanding composite schemas efficiently.
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 12004370 and 12127804)the Strategic Priority Research Program of the Chinese Academy of Sciences (Grant No. XDB34020000)。
文摘The vibrational motions are usually neglected when calculating(e,2e) triple differential cross sections(TDCSs) of molecules. Here, multi-center distorted-wave method(MCDW) has been modified by including molecular vibrations. This vibrational MCDW method is employed to calculate the TDCSs of 1b3gorbital of ethylene at low(100 eV) and medium(250 eV) incident electron energies in coplanar asymmetric kinematic condition. The results show that molecular vibrations significantly influence the angular distributions of the TDCSs, especially in the binary region along momentum transfer near the Bethe ridge.
基金the National Natural Science Foundation of China(Grant Nos.12004370,11534011,and 11934004)the National Key Research and Development Program of China(Grant Nos.2017YFA0402300 and 2019YFA0210004).
文摘We report theoretical studies of electron impact triple differential cross sections of two bio-molecules,pyrimidine and tetrahydrofurfuryl alcohol,in the coplanar asymmetric kinematic conditions with the impact energy of 250 eV and ejected electron energy of 20 eV at three scattering angles of-5°,-10°,and-15°.Present multi-center distorted-wave method well describes the experimental data,which was obtained by performing(e,2e)experiment.The calculations show that the secondary electron produced by the primary impact electron is strongly influenced by the molecular ionic multi-center potential,which must be considered when the low energy electron interacts with DNA analogues.
