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电解银催化甲醇氧化制甲醛实验的课程思政设计 被引量:1
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作者 刘永梅 孙立森 +1 位作者 黄镇 涂涛 《大学化学》 CAS 2024年第2期67-71,共5页
将具有工业生产特色的“电解银催化甲醇选择性氧化”转化为一个综合的物理化学实验,通过实验学生可以掌握气固相反应装置运行的规范操作及反应条件的控制对催化性能的调控,推动了工科和理科融合渗透。同时引导学生理解催化技术对提高工... 将具有工业生产特色的“电解银催化甲醇选择性氧化”转化为一个综合的物理化学实验,通过实验学生可以掌握气固相反应装置运行的规范操作及反应条件的控制对催化性能的调控,推动了工科和理科融合渗透。同时引导学生理解催化技术对提高工业生产经济效益和可持续绿色发展的重要意义,该实验的开展可以强化学生学以致用的意识,增强对化工生产问题的综合性和复杂性的认识,还可以培养学生团队意识和合作能力,培养科技创新促进化工生产的意识和抓住事物本质从根本上解决问题的意识,强化学生的学科素养和社会责任感。 展开更多
关键词 电解银 催化氧化 甲醇氧化
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黏度测定服务于厨余垃圾处理设备运行条件优化的实验教学设计 被引量:1
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作者 孙立森 郝永梅 +1 位作者 黄镇 刘永梅 《大学化学》 CAS 2024年第2期52-56,共5页
厨余垃圾的不当处置会造成土地和水资源的污染,随着垃圾分类政策在全国的推行,有效处理厨余垃圾成为解决环境问题的热点议题。厨余垃圾黏度的大小可直接影响处理设备的选型和工艺参数确定。将厨余垃圾的黏度测定作为实际应用案例引入物... 厨余垃圾的不当处置会造成土地和水资源的污染,随着垃圾分类政策在全国的推行,有效处理厨余垃圾成为解决环境问题的热点议题。厨余垃圾黏度的大小可直接影响处理设备的选型和工艺参数确定。将厨余垃圾的黏度测定作为实际应用案例引入物理化学实验教学,结合实际改进实验,对不同组成厨余垃圾的黏度值进行测量,考察含固率、转子型号、搅拌速度选择等对黏度值的影响,为厨余垃圾处理设备选型及工艺参数选择提供理论依据。改进后的实验可以强化学生学以致用的意识,增强对工程问题的综合性和复杂性的认识,启迪学生对厨余垃圾资源化利用的探索思考,实现基于“双碳”和绿色环保的创新思维学科素养培养,增强社会责任感。 展开更多
关键词 厨余垃圾 黏度测定 含固率
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单孔与单操作孔胸腔镜治疗自发性气胸的对比研究 被引量:21
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作者 沈国义 张奕 +1 位作者 黄镇 张文山 《中国内镜杂志》 北大核心 2017年第3期30-33,共4页
目的比较单孔胸腔镜手术(uniportal VATS)与单操作孔胸腔镜手术(single utility port VATS)治疗自发性气胸的疗效。方法回顾性收集2013年1月-2015年12月收治自发性气胸行uniportal VATS治疗的53例患者作为实验组,对照同期53例行single u... 目的比较单孔胸腔镜手术(uniportal VATS)与单操作孔胸腔镜手术(single utility port VATS)治疗自发性气胸的疗效。方法回顾性收集2013年1月-2015年12月收治自发性气胸行uniportal VATS治疗的53例患者作为实验组,对照同期53例行single utility port VATS治疗的患者作为对照组,比较两组的手术时间、术中出血量、胸管放置时间、术后住院时间、术后疼痛、术后并发症及远期复发等临床指标。结果 106例患者均顺利完成手术,无死亡及严重并发症发生。实验组和对照组比较,术后24 h疼痛视觉模拟评分(VAS)为(2.60±0.71)vs(3.38±0.84),术后72 h VAS为(1.30±0.51)vs(1.58±0.62),实验组较对照组术后24和72 h疼痛减轻(P<0.05)。两组患者手术时间、术中出血、胸管引流时间、术后住院时间、手术费用和术后并发症的差异均无统计学意义(P>0.05)。随访时间5~36个月,平均19个月,术后无气胸复发。结论单孔胸腔镜治疗自发性气胸与单操作孔两种方法同样安全有效,但单孔法术后疼痛程度更轻,近期疗效满意,值得进一步临床推广。 展开更多
关键词 自发性气胸 单孔胸腔镜手术 单操作孔胸腔镜手术
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年龄和OCT特征与抗VEGF治疗视网膜中央静脉阻塞性黄斑水肿效果的相关性 被引量:13
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作者 邓玉梦 宋艳萍 +3 位作者 黄珍 叶娅 闫明 黄晓莉 《国际眼科杂志》 CAS 北大核心 2021年第6期1062-1067,共6页
目的:探讨年龄和OCT特征与抗血管内皮生长因子(VEGF)药物治疗视网膜中央静脉阻塞(CRVO)性黄斑水肿效果的相关性。方法:回顾性病例对照研究。将2017-07/2019-07确诊为CRVO的患者47例47眼纳入研究,根据发病年龄分为老年组(年龄>50岁,27... 目的:探讨年龄和OCT特征与抗血管内皮生长因子(VEGF)药物治疗视网膜中央静脉阻塞(CRVO)性黄斑水肿效果的相关性。方法:回顾性病例对照研究。将2017-07/2019-07确诊为CRVO的患者47例47眼纳入研究,根据发病年龄分为老年组(年龄>50岁,27眼)和中青年组(年龄≤50岁,20眼)。所有患者均行玻璃体腔注射抗VEGF治疗(3+PRN),至少随访12mo。观察两组患者治疗前后最佳矫正视力(BCVA)、强反射点(HRD)数量、平均视网膜厚度(ART)、中央视网膜厚度(CRT)变化情况,比较两组患者抗VEGF治疗次数、外界膜(ELM)和椭圆体带(EZ)转归率,并分析影响视力预后的相关指标。结果:抗VEGF治疗后两组患者BCVA均较治疗前改善、HRD数量减少、CRT和ART变薄。治疗后第12mo随访时,老年组患者行玻璃体腔注射抗VEGF药物次数高于中青年组(8.4±2.1次vs 7.3±1.7次,P=0.047),但两组患者ELM、EZ转归率均无差异(P>0.05),老年组患者BCVA与发病年龄、HRD、ELM及EZ具有相关性(均P<0.05),中青年组患者BCVA与发病年龄、ART、HRD、ELM及EZ具有相关性(均P<0.05)。结论:玻璃体腔注射抗VEGF药物可有效治疗CRVO性黄斑水肿,且中青年患者比老年患者预后更好,年龄和OCT指标HRD、ELM及EZ等与视力预后相关。 展开更多
关键词 血管内皮生长因子 视网膜中央静脉阻塞 玻璃体注射 炎性因子 光学相干断层扫描
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Effects of confining pressure on acoustic emission and failure characteristics of sandstone 被引量:8
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作者 zhen huang Qixiong Gu +4 位作者 Yufan Wu Yun Wu Shijie Li Kui Zhao Rui Zhang 《International Journal of Mining Science and Technology》 SCIE EI CAS CSCD 2021年第5期963-974,共12页
In this study,uniaxial and triaxial compression acoustic emission(AE)tests were implemented to investigate the AE effect and failure characteristics of sandstone under different confining pressures(σ3).The evolution ... In this study,uniaxial and triaxial compression acoustic emission(AE)tests were implemented to investigate the AE effect and failure characteristics of sandstone under different confining pressures(σ3).The evolution of AE parameters in the rock failure process and fracture fractal dimension characteristics after failure were analyzed.The results revealed that the activity of the AE signal is strongly related toσ3.The evolution of the Ib value can be divided into the I-fluctuation,II-stability,and III-decrease stages.In the first stage,the Ib value of the AE was relatively high,and the AE energy was low.Then,the Ib value tended to be stable;however,the fluctuation amplitude decreased,and the AE energy rapidly increased.In the stage of decrease,the AE energy sharply increased before the load approached the peak value,and the Ib value significantly decreased and dropped to the lowest point before the peak value.Asσ3 increased,the rock’s failure mode changed from tensile failure to shear failure and became more coordinated.As the confining pressure increased,the shape dimension decreased,and the order degree of rock failure increased.The confining pressure exerted a certain control effect on the rock failure. 展开更多
关键词 SANDSTONE Acoustic emission Ib value Failure mode Fractal dimension
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CNTs@S composite as cathode for all-solid-state lithium-sulfur batteries with ultralong cycle life 被引量:7
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作者 Qiang Zhang Ning huang +3 位作者 zhen huang Liangting Cai Jinghua Wu Xiayin Yao 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2020年第1期151-155,I0006,共6页
The main challenges in development of traditional liquid lithium-sulfur batteries are the shuttle effect at the cathode caused by the polysulfide and the safety concern at the Li metal anode arose from the dendrite fo... The main challenges in development of traditional liquid lithium-sulfur batteries are the shuttle effect at the cathode caused by the polysulfide and the safety concern at the Li metal anode arose from the dendrite formation.All-solid-state lithium-sulfur batteries have been proposed to solve the shuttle effect and prevent short circuits.However,solid-solid contacts between the electrodes and the electrolyte increase the interface resistance and stress/strain,which could result in the limited electrochemical performances.In this work,the cathode of all-solid-state lithium-sulfur batteries is prepared by depositing sulfur on the surface of the carbon nanotubes(CNTs@S)and further mixing with Li10GeP2S12 electrolyte and acetylene black agents.At 60℃,CNTs@S electrode exhibits superior electrochemical performance,delivering the reversible discharge capacities of 1193.3,959.5,813.1,569.6 and 395.5 mAhg^-1 at the rate of 0.1,0.5,1,2 and 5 C,respectively.Moreover,the CNTs@S is able to demonstrate superior high-rate capability of 660.3 mAhg^-1 and cycling stability of 400 cycles at a high rate of 1.0 C.Such uniform distribution of the CNTs,S and Li10GeP2S12 electrolyte increase the electronic and ionic conductivity between the cathode and the electrolyte hence improves the rate performance and capacity retention. 展开更多
关键词 CNTs@S composite All-solid-state lithium-sulfur battery Electronic conduction network Interfacial contact Ultralong cycle life
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Risk assessment of fault water inrush during deep mining 被引量:3
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作者 Zhaodan Cao Qixiong Gu +1 位作者 zhen huang Jiaju Fu 《International Journal of Mining Science and Technology》 SCIE EI CAS CSCD 2022年第2期423-434,共12页
With the gradual depletion of shallow coal resources,the Yanzhou mine in China will enter the lower coal seam mining phase.However,as mining depth increases,lower coal seam mining in Yanzhou is threatened by water inr... With the gradual depletion of shallow coal resources,the Yanzhou mine in China will enter the lower coal seam mining phase.However,as mining depth increases,lower coal seam mining in Yanzhou is threatened by water inrush in the Benxi Formation limestone and Ordovician limestone.The existing prediction models for the water burst at the bottom of the coal seam are less accurate than expected owing to various controlling factors and their intrinsic links.By analyzing the hydrogeological exploration data of the Baodian lower seam and combining the results of the water inrush coefficient method and the Yanzhou mine pressure seepage test,an evaluation model of the seepage barrier capacity of the fault was established.The evaluation results show the water of the underlying limestone aquifer in the Baodian mine area mainly threatens the lower coal mining through the fault fracture zone.The security of mining above confined aquifer in the Baodian mine area gradually decreases from southwest to northeast.By comparing the water inrush coefficient method and the evaluation model of fault impermeability,the results show the evaluation model based on seepage barrier conditions is closer to the actual situation when analyzing the water breakout situation at the working face. 展开更多
关键词 Lower coal seam Mining above confined aquifer Water inrush coefficient Water injection test Impermeability strength Water-inrush in fault
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Self-Assembled Al Nanostructure/ZnO Quantum Dot Heterostructures for High Responsivity and Fast UV Photodetector 被引量:4
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作者 Sisi Liu Ming‑Yu Li +4 位作者 Jianbing Zhang Dong Su zhen huang Sundar Kunwar Jihoon Lee 《Nano-Micro Letters》 SCIE EI CAS CSCD 2020年第9期96-108,共13页
Light confinement induced by spontaneous near-surface resonance is inherently determined by the location and geometry of metallic nanostructures(NSs),offering a facile and effective approach to break through the limit... Light confinement induced by spontaneous near-surface resonance is inherently determined by the location and geometry of metallic nanostructures(NSs),offering a facile and effective approach to break through the limitation of the light-mater interaction within the photoactive layers.Here,we demonstrate high-performance Al NS/ZnO quantum dots(Al/ZnO) heterostructure UV photodetectors with controllable morphologies of the self-assembled Al NSs.The Al/ZnO heterostructures exhibit a superior light utilization than the ZnO/Al heterostructures,and a strong morphological dependence of the Al NSs on the optical properties of the heterostructures.The inter-diffusion of Al atoms into ZnO matrixes is of a great benefit for the carrier transportation.Consequently,the optimal photocurrent of the Al/ZnO heterostructure photodetectors is significantly increased by 275 times to ~1.065 mA compared to that of the pristine ZnO device,and an outstanding photoresponsivity of 11.98 A W-1 is correspondingly achieved under 6.9 MW cm-2 UV light illumination at 10 V bias.In addition,a relatively fast response is similarly witnessed with the Al/ZnO devices,paving a path to fabricate the high-performance UV photodetectors for applications. 展开更多
关键词 Al/ZnO heterostructure photodetectors Plasmonic enhancement ZnO quantum dots Self-assembled Al nanostructures
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Different oxidation routes for lattice oxygen recovery of double-perovskite type oxides LaSrFeCoO6 as oxygen carriers for chemical looping steam methane reforming 被引量:3
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作者 Kun Zhao Yang Shen +5 位作者 zhen huang Fang He Guoqiang Wei Anqing zheng Haibin Li Zengli Zhao 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2017年第3期501-509,共9页
Double-perovskite type oxide LaSrFeCoO(LSFCO) was used as oxygen carrier for chemical looping steam methane reforming(CL-SMR) due to its unique structure and reactivity. Two different oxidation routes,steam-oxidat... Double-perovskite type oxide LaSrFeCoO(LSFCO) was used as oxygen carrier for chemical looping steam methane reforming(CL-SMR) due to its unique structure and reactivity. Two different oxidation routes,steam-oxidation and steam-air-stepwise-oxidation, were applied to investigate the recovery behaviors of the lattice oxygen in the oxygen carrier. The characterizations of the oxide were determined by X-ray diffraction(XRD), X-ray photoelectron spectroscopy(XPS), hydrogen temperature-programmed reduction(H-TPR) and scanning electron microscopy(SEM). The fresh sample LSFCO exhibits a monocrystalline perovskite structure with cubic symmetry and high crystallinity, except for a little impurity phase due to the antisite defect of Fe/Co disorder. The deconvolution distribution of XPS patterns indicated that Co,and Fe are predominantly in an oxidized state(Feand Fe) and(Coand Co), while O 1s exists at three species of lattice oxygen, chemisorbed oxygen and physical adsorbed oxygen. The double perovskite structure and chemical composition recover to the original state after the steam and air oxidation, while the Co ion cannot incorporate into the double perovskite structure and thus form the CoO just via individual steam oxidation. In comparison to the two different oxidation routes, the sample obtained by steam-oxidation exhibits even higher CHconversion, CO and Hselectivity and stronger hydrogen generation capacity. 展开更多
关键词 DOUBLE-PEROVSKITE Chemical looping Lattice oxygen Oxidizing agent Redox
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康柏西普与雷珠单抗治疗nARMD伴纤维血管性色素上皮脱离的效果比较 被引量:3
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作者 张香闺 宋艳萍 +4 位作者 黄珍 吴乔伟 陈晓 闫明 叶娅 《国际眼科杂志》 CAS 北大核心 2022年第6期1025-1031,共7页
目的:比较康柏西普与雷珠单抗治疗新生血管性年龄相关性黄斑变性(nARMD)1型黄斑新生血管(MNV)伴纤维血管性色素上皮脱离(fPED)的疗效。方法:回顾性临床研究。纳入2019-01/2020-12于我院确诊的nARMD 1型MNV伴fPED患者48例48眼,根据治疗... 目的:比较康柏西普与雷珠单抗治疗新生血管性年龄相关性黄斑变性(nARMD)1型黄斑新生血管(MNV)伴纤维血管性色素上皮脱离(fPED)的疗效。方法:回顾性临床研究。纳入2019-01/2020-12于我院确诊的nARMD 1型MNV伴fPED患者48例48眼,根据治疗药物分为康柏西普组(26例26眼)和雷珠单抗组(22例22眼),均采用3+PRN的治疗方案。随访12mo,观察两组患者最佳矫正视力(BCVA),并采用光相干断层扫描(OCT)测量黄斑中心凹厚度(CFT)、视网膜色素上皮脱离(PED)的消退程度(高度、面积、体积)。结果:两组患者治疗前BCVA、CFT及PED高度、面积和体积均无显著差异(P>0.05)。治疗(首次玻璃体内注射)后3、6、12mo两组患者PED高度均较治疗前显著改善(P<0.05),但PED面积和体积均无显著改善(P>0.05)。治疗后两组患者BCVA较治疗前均无显著改善(P>0.05)。治疗后3、6、12mo康柏西普组患者CFT均较治疗前显著改善(P<0.05),雷珠单抗组仅在治疗后3mo较治疗前显著改善(P<0.05)。治疗后3、6、12mo两组间BCVA、CFT及PED高度、面积和体积均无显著差异(P>0.05)。结论:康柏西普和雷珠单抗治疗nARMD 1型MNV伴fPED均有较好疗效,能降低PED高度及CFT,稳定视力、PED面积和体积,而康柏西普减轻黄斑水肿的持续时间更为持久。 展开更多
关键词 新生血管性年龄相关性黄斑变性(nARMD) 1型黄斑新生血管 纤维血管性视网膜色素上皮脱离 血管生成抑制剂
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La2Zr2O7 and MgO co-doped composite Li-Garnet solid electrolyte 被引量:2
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作者 Jiu Lin Linbin Wu +2 位作者 zhen huang Xiaoxiong Xu Jiheng Liu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2020年第1期132-136,I0005,共6页
Various solid electrolytes,such as sulfides(10^-3-10^-2 S cm^-1)and oxides(10^-4–10^-3 S cm^-1)are explored and developed to solve the safety problems in commercial Li-ion batteries using liquid flammable electrolyte... Various solid electrolytes,such as sulfides(10^-3-10^-2 S cm^-1)and oxides(10^-4–10^-3 S cm^-1)are explored and developed to solve the safety problems in commercial Li-ion batteries using liquid flammable electrolytes.Metallic Li anode is required for pursuing high power density(>300 Wh kg^-1)for solid-state batteries[1,2]. 展开更多
关键词 Li-Garnet Li7La3Zr2O12 Composite electrolyte High conductivity LA2ZR2O7 MGO
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一步乙氧基化合成甲基丙烯酸聚乙二醇单酯 被引量:2
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作者 张志勇 黄振 +2 位作者 舒鑫 杨勇 冉千平 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2019年第3期22-26,共5页
通过甲基丙烯酸羟乙酯(HEMA)与环氧乙烷(EO)的一步乙氧基化开环聚合,制备了含末端双键和亲水性聚氧乙烯结构的甲基丙烯酸聚乙二醇单酯大分子单体(PEGMA)。研究了各种反应参数对反应的影响,最佳的工艺条件为:采用1%的四甲基哌啶氮氧化物(... 通过甲基丙烯酸羟乙酯(HEMA)与环氧乙烷(EO)的一步乙氧基化开环聚合,制备了含末端双键和亲水性聚氧乙烯结构的甲基丙烯酸聚乙二醇单酯大分子单体(PEGMA)。研究了各种反应参数对反应的影响,最佳的工艺条件为:采用1%的四甲基哌啶氮氧化物(TEMPO)作为阻聚剂,采用1.25%的三氟化硼乙醚-四氯化锡(摩尔比为4∶1~6∶1)作为复合催化剂,反应温度为105~115℃,压力为0.3~0.4 MPa。红外光谱和核磁共振氢谱证实了大分子单体的结构与预期设计一致。水泥净浆流动度实验和混凝土实验显示采用该大分子单体合成的聚羧酸减水剂达到工业品的水平。 展开更多
关键词 甲基丙烯酸聚乙二醇单酯 乙氧基化 一步法 聚羧酸高性能减水剂
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Comparative microsporogenesis and flower development in Eucalyptus urophylla×E.grandis 被引量:2
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作者 Jun Yang Jun Lan +2 位作者 Pengqiang Yao zhen huang Xiangyang Kang 《Journal of Forestry Research》 SCIE CAS CSCD 2016年第2期257-263,共7页
Microsporogenesis and flower development in Eucalyptus urophylla × E. grandis were examined using chromosome tableting to provide a method to predict the meiotic stages in this species. Although microsporogenesis... Microsporogenesis and flower development in Eucalyptus urophylla × E. grandis were examined using chromosome tableting to provide a method to predict the meiotic stages in this species. Although microsporogenesis was normal, cytokinesis during meiosis of pollen mother cells occurred simultaneously, with strong asynchronism observed in the two different lengths of stamens in a flower bud. In a single flower, the developmental period of microsporogenesis in anthers on the longer stamens was always ahead of those on the shorter stamens. Flower development was also asynchronous at different locations on a branch. Flower buds on the upper side of the branch were larger in diameter than those on the lower side. In addition, a correlation was observed between microsporogenesis development and flower bud diameter growth. The pachy- tene stage was first observed when the diameter of the flower buds increased to 3.0 mm, and the majority of the meiotic stages were observed when bud diameters ranged from 3.5 to 5.0 mm. This study showed that the developmental stages of microsporogenesis in Eucalyptus urophylla × E. grandis could be distinguished readily, which may be applicable to future breeding studies. 展开更多
关键词 Eucalyptus urophylla × E. grandis MICROSPOROGENESIS Flower development
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Design and Implementation of Partial Shared Digital Channelized Receiver 被引量:2
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作者 Lei Shi zhen huang Xuefeng Feng 《Journal of Beijing Institute of Technology》 EI CAS 2021年第2期186-193,共8页
A novel efficient partial sharing channelization structure with odd and even stacking is designed and implemented. There are two special designs in the proposed structure. Firstly, by the intensive channel overlap des... A novel efficient partial sharing channelization structure with odd and even stacking is designed and implemented. There are two special designs in the proposed structure. Firstly, by the intensive channel overlap design, for non-cooperative wideband signals, the proposed structure can achieve good parameter estimation accuracy and high probability of complete interception.Secondly, based on the partial sharing design developed in this paper, the computation burden of the proposed structure can be greatly reduced compared with the traditional directly implemented structures. Experiments and numerical simulations are conducted to evaluate the proposed structure, which shows its improvements over traditional methods in terms of field programmable gate arrays(FPGA) resource consumption and parameter estimation accuracy. 展开更多
关键词 digital channelized receiver field programmable gate arrays(FPGA) NON-COOPERATIVE pulse interception
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Evaluation of multi-cycle performance of chemical looping dry reforming using CO_2 as an oxidant with Fe–Ni bimetallic oxides 被引量:6
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作者 zhen huang Huanqi Jiang +7 位作者 Fang He Dezhen Chen Guoqiang Wei Kun Zhao Anqing zheng Yipeng Feng Zengli Zhao Haibin Li 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2016年第1期62-70,共9页
Chemical looping dry reforming(CLDR) is an innovative technology for CO2 utilization using the chemical looping principle.The CLDR process consists of three stages,i.e.CH4 reduction,CO2 reforming,and air oxidation.S... Chemical looping dry reforming(CLDR) is an innovative technology for CO2 utilization using the chemical looping principle.The CLDR process consists of three stages,i.e.CH4 reduction,CO2 reforming,and air oxidation.Spinel nickel ferrite(NiFe2O4) was prepared and its multi-cycle performance as an oxygen carrier for CLDR was experimentally investigated.X-ray diffraction(XRD) and Laser Raman spectroscopy showed that a pure spinel crystalline phase(NiFe2O4) was obtained by a parallel flow co-precipitating method.NiFe2O4was reduced into Fe-Ni alloy and wustite(FexO) during the CH4 reduction process.Subsequent oxidation of the reduced oxygen carrier was performed with CO2 as an oxidant to form an intermediate state:a mixture of spinel Ni(1-x)Fe(2+x)O4,Fe(2+y)O4 and metallic Ni.And CO was generated in parallel during this stage.Approximate 185 mL of CO was generated for 1 g spinel NiFe2O4 in a single cycle.The intermediate oxygen carrier was fully oxidized in the air oxidation stage to form a mixture of Ni(1+x)Fe(2-x)O4 and Fe2O3.Although the original state of oxygen carrier(NiFe2O4) was not fully regenerated and agglomeration was observed,a good recyclability was shown in 10 successive redox cycles. 展开更多
关键词 Chemical looping Oxygen carrier Nickel ferrite CO2 utilization Multi-cycle performance
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A Distributed Computing Framework Based on Lightweight Variance Reduction Method to Accelerate Machine Learning Training on Blockchain 被引量:1
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作者 zhen huang Feng Liu +2 位作者 Mingxing Tang Jinyan Qiu Yuxing Peng 《China Communications》 SCIE CSCD 2020年第9期77-89,共13页
To security support large-scale intelligent applications,distributed machine learning based on blockchain is an intuitive solution scheme.However,the distributed machine learning is difficult to train due to that the ... To security support large-scale intelligent applications,distributed machine learning based on blockchain is an intuitive solution scheme.However,the distributed machine learning is difficult to train due to that the corresponding optimization solver algorithms converge slowly,which highly demand on computing and memory resources.To overcome the challenges,we propose a distributed computing framework for L-BFGS optimization algorithm based on variance reduction method,which is a lightweight,few additional cost and parallelized scheme for the model training process.To validate the claims,we have conducted several experiments on multiple classical datasets.Results show that our proposed computing framework can steadily accelerate the training process of solver in either local mode or distributed mode. 展开更多
关键词 machine learning optimization algorithm blockchain distributed computing variance reduction
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