Polyvinylidene fluoride/lead zirconate titanate(PVDF/PZT)composite films have been prepared by direct ink writing and the effect of PZT content on crystallization behavior and electrical properties of film were system...Polyvinylidene fluoride/lead zirconate titanate(PVDF/PZT)composite films have been prepared by direct ink writing and the effect of PZT content on crystallization behavior and electrical properties of film were systematically investigated.The composite films were characterized by scanning electron microscope(SEM),X-ray diffractometer(XRD),Flourier transform infrared spectroscope(FTIR)and differential scanning calorimeter(DSC).The results show that,surface modified PZT powder(PZT@PDA)is successfully coated by polydopamine(PDA),resulting in a large number of polar groups that interact with the-CF_(2)-groups in PVDF,inducing the generation of polarβphase due to hydrogen bonding formed in the interaction.Theβphase content in composite film increases with increasing PZT@PDA content,up to 28.09%as with 5 wt.%PZT@PDA.PZT@PDA plays a role of nucleating agent to promote the generation of polar phases in the film and also acts as an impurity hindering the growth of nuclei to reduce crystallinity.Moreover,the presence of PZT@PDA in interfaces provides more sites for the occurrence of interfacial polarization and thus improving the electrical properties of films.The composite film with 5 wt.%PZT@PDA possesses the highest dielectric constant(8.61)and residual polarization value(0.6803μC/cm^(2)).展开更多
Piezocatalysis and pyrocatalysis can achieve catalytic action with the application of external mechanical energy and varying temperatures.These catalytic processes have been widely applied in various fields,providing ...Piezocatalysis and pyrocatalysis can achieve catalytic action with the application of external mechanical energy and varying temperatures.These catalytic processes have been widely applied in various fields,providing innovative solutions to issues such as water pollution,energy shortages,and global warming.Despite the continuous breakthroughs in the catalytic performance of piezocatalysts and pyrocatalysts,powder-based catalysts face significant limitations due to their inability to be retrieved and the risk of secondary pollution,severely restricting their application.Methods such as compression molding,3 D printing,and the preparation of ceramic-polymer bulk composites can effectively address the issue of catalyst retrievability.However,bulk catalysts,which lose a significant amount of surface area,still need their catalytic performance further enhanced.Therefore,achieving piezocatalysts and pyrocatalysts with excellent catalytic performance and retrievability is of increasing importance.展开更多
基金Project(22020JJ4729)supported by the Natural Science Foundation of Hunan Province,China。
文摘Polyvinylidene fluoride/lead zirconate titanate(PVDF/PZT)composite films have been prepared by direct ink writing and the effect of PZT content on crystallization behavior and electrical properties of film were systematically investigated.The composite films were characterized by scanning electron microscope(SEM),X-ray diffractometer(XRD),Flourier transform infrared spectroscope(FTIR)and differential scanning calorimeter(DSC).The results show that,surface modified PZT powder(PZT@PDA)is successfully coated by polydopamine(PDA),resulting in a large number of polar groups that interact with the-CF_(2)-groups in PVDF,inducing the generation of polarβphase due to hydrogen bonding formed in the interaction.Theβphase content in composite film increases with increasing PZT@PDA content,up to 28.09%as with 5 wt.%PZT@PDA.PZT@PDA plays a role of nucleating agent to promote the generation of polar phases in the film and also acts as an impurity hindering the growth of nuclei to reduce crystallinity.Moreover,the presence of PZT@PDA in interfaces provides more sites for the occurrence of interfacial polarization and thus improving the electrical properties of films.The composite film with 5 wt.%PZT@PDA possesses the highest dielectric constant(8.61)and residual polarization value(0.6803μC/cm^(2)).
基金Project(2022YFB3807404)supported by the National Key Research and Development Program of ChinaProject(52302158)supported by the National Natural Science Foundation of China。
文摘Piezocatalysis and pyrocatalysis can achieve catalytic action with the application of external mechanical energy and varying temperatures.These catalytic processes have been widely applied in various fields,providing innovative solutions to issues such as water pollution,energy shortages,and global warming.Despite the continuous breakthroughs in the catalytic performance of piezocatalysts and pyrocatalysts,powder-based catalysts face significant limitations due to their inability to be retrieved and the risk of secondary pollution,severely restricting their application.Methods such as compression molding,3 D printing,and the preparation of ceramic-polymer bulk composites can effectively address the issue of catalyst retrievability.However,bulk catalysts,which lose a significant amount of surface area,still need their catalytic performance further enhanced.Therefore,achieving piezocatalysts and pyrocatalysts with excellent catalytic performance and retrievability is of increasing importance.
