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ICP-MS/MS法测定儿童彩妆类化妆品中的7种元素
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作者 吴莉 庞庆林 +2 位作者 张妤琳 耿悦 陈民辉 《日用化学工业(中英文)》 北大核心 2025年第1期98-103,共6页
建立了电感耦合等离子体串联质谱法(ICP-MS/MS)测定儿童彩妆类化妆品中7种元素的含量测定方法。样品经硝酸-氢氟酸的消解酸体系破坏、超级微波消解法进行消解,采用ICP-MS/MS法同时测定儿童彩妆类化妆品中硼(B)、钛(Ti)、锗(Ge)、钼(Mo)... 建立了电感耦合等离子体串联质谱法(ICP-MS/MS)测定儿童彩妆类化妆品中7种元素的含量测定方法。样品经硝酸-氢氟酸的消解酸体系破坏、超级微波消解法进行消解,采用ICP-MS/MS法同时测定儿童彩妆类化妆品中硼(B)、钛(Ti)、锗(Ge)、钼(Mo)、锡(Sn)、锑(Sb)、碲(Te)7种元素的含量,选用铑(Rh)作为内标。分别以霜类、粉类、口红类为基质进行方法学考察,结果表明,所测元素在各自质量浓度范围内线性关系良好,相关系数均大于0.9967。在2个加标水平下,三种基质的平均回收率范围分别为81.1%~104.6%、84.0%~116.0%、80.8%~113.1%,RSD分别为2.2%~7.5%、0.5%~7.1%、0.8%~7.3%。该方法采用硝酸-氢氟酸体系、超级微波消解法进行样品前处理,应用ICPMS/MS技术对儿童彩妆类化妆品中元素进行含量测定,解决了不同类型样品尤其是组成复杂、基质干扰大的彩妆类样品在元素检测中的难题,为各类化妆品的样品前处理和元素分析提供了新思路,填补了现有法定标准中尚未建立的7种元素检测方法的空白。 展开更多
关键词 电感耦合等离子体串联质谱法(ICP-MS/MS) 超级微波消解 氢氟酸 儿童彩妆 元素分析
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含聚硅氧烷链段邻苯二甲腈树脂的制备及性能 被引量:1
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作者 蒋欣欣 赵星诺 +4 位作者 章宇琳 刘小僮 王文蓓 周权 张钧钧 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2024年第2期1-8,共8页
以端羟基聚二甲基硅氧烷和4-硝基邻苯二甲腈为原料,在强极性溶剂中进行亲核取代反应合成了含聚硅氧烷链段邻苯二甲腈树脂(SIPH),并利用氨基改性剂(AWL)与该树脂进行反应制备了改性含聚硅氧烷链段邻苯二甲腈树脂预聚物(SIPH-AL)。通过红... 以端羟基聚二甲基硅氧烷和4-硝基邻苯二甲腈为原料,在强极性溶剂中进行亲核取代反应合成了含聚硅氧烷链段邻苯二甲腈树脂(SIPH),并利用氨基改性剂(AWL)与该树脂进行反应制备了改性含聚硅氧烷链段邻苯二甲腈树脂预聚物(SIPH-AL)。通过红外光谱和核磁共振表征了SIPH树脂的化学结构;采用差示扫描量热法、红外光谱法、热重分析和动态力学热分析表征了SIPH-AL的固化行为和固化物的耐热性。结果表明,SIPH-AL起始固化温度为207℃,其固化物在空气和氮气中失重5%的温度(T_(d5))及1000℃质量保留率分别是453℃,29%和500℃,77%;石英纤维增强SIPH-AL复合材料室温和600℃时的弯曲强度分别为515.5 MPa和94.5 MPa,玻璃化转变温度(T_(g))高于500℃。 展开更多
关键词 含聚硅氧烷链段邻苯二甲腈树脂 氨基改性剂 耐热性 复合材料
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3,3',4,4'-联苯四胺改性邻苯二甲腈树脂及其复合材料性能 被引量:1
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作者 董俊宇 赵星诺 +4 位作者 章宇琳 刘小僮 王文蓓 周权 吴霄 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2024年第2期65-73,共9页
采用3,3',4,4'-联苯四胺(LBS)与联苯型邻苯二甲腈树脂(BPh)进行预聚反应制备改性联苯型邻苯二甲腈树脂预聚物(BLBS)。利用红外光谱法、差示扫描量热仪、旋转流变仪和热重分析对BLBS的固化行为、流变性能和耐温性能进行研究。结... 采用3,3',4,4'-联苯四胺(LBS)与联苯型邻苯二甲腈树脂(BPh)进行预聚反应制备改性联苯型邻苯二甲腈树脂预聚物(BLBS)。利用红外光谱法、差示扫描量热仪、旋转流变仪和热重分析对BLBS的固化行为、流变性能和耐温性能进行研究。结果表明,BLBS最低可在240℃前开始固化,但仍需要较高的温度才能固化完全;BLBS-3固化物在氮气和空气氛围中的质量损失5%时的温度(Td5)分别为549.4℃和555.6℃。石英纤维增强BLBS复合材料(QF/BLBS)具有优异的力学性能和耐热性能,玻璃化转变温度(T_(g))大于500°C,室温弯曲强度和层间剪切强度分别为711.5 MPa和48.5 MPa,400℃热处理2 h后弯曲强度和层间剪切强度分别为680.5 MPa和31.3 MPa。 展开更多
关键词 联苯型邻苯二甲腈 3 3' 4 4'-联苯四胺 耐热性能 力学性能 复合材料
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A framework for equipment systems-of-systems effectiveness evaluation using parallel experiments approach 被引量:8
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作者 Zilong Cheng Li Fan yulin zhang 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 2015年第2期292-300,共9页
Equipment systems-of-systems (SOS) effectiveness evaluation can provide important reference for construction and optimization of the equipment SoS. After discussing the basic theory and methods of parallel experimen... Equipment systems-of-systems (SOS) effectiveness evaluation can provide important reference for construction and optimization of the equipment SoS. After discussing the basic theory and methods of parallel experiments, we depict an SoS effectiveness analysis and evaluation method using parallel expe- riments theory in detail. A case study is carried out which takes the missile defense system as an example. An artificial system of the missile defense system is constructed with the multi-agent modeling method. Then, single factor, multiple factors and defense position deployment computational experiments are carried out and evaluated with the statistical analysis method. Experiment re- sults show that the altitude of the secondary interception missile is not the key factor which affects SoS effectiveness and putting the defense position ahead will increase defense effectiveness. The case study demonstrates the feasibility of the proposed method. 展开更多
关键词 agent based modeling parallel experiments computational experiments missile defense system effectiveness evaluation
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Multi-agent decision support system for missile defense based on improved PSO algorithm 被引量:5
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作者 Zilong Cheng Li Fan yulin zhang 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 2017年第3期514-525,共12页
Ballistic missile defense system (BMDS) is important for its special role in ensuring national security and maintaining strategic balance. Research on modeling and simulation of the BMDS beforehand is essential as dev... Ballistic missile defense system (BMDS) is important for its special role in ensuring national security and maintaining strategic balance. Research on modeling and simulation of the BMDS beforehand is essential as developing a real one requires lots of manpower and resources. BMDS is a typical complex system for its nonlinear, adaptive and uncertainty characteristics. The agent-based modeling method is well suited for the complex system whose overall behaviors are determined by interactions among individual elements. A multi-agent decision support system (DSS), which includes missile agent, radar agent and command center agent, is established based on the studies of structure and function of BMDS. Considering the constraints brought by radar, intercept missile, offensive missile and commander, the objective function of DSS is established. In order to dynamically generate the optimal interception plan, the variable neighborhood negative selection particle swarm optimization (VNNSPSO) algorithm is proposed to support the decision making of DSS. The proposed algorithm is compared with the standard PSO, constriction factor PSO (CFPSO), inertia weight linear decrease PSO (LDPSO), variable neighborhood PSO (VNPSO) algorithm from the aspects of convergence rate, iteration number, average fitness value and standard deviation. The simulation results verify the efficiency of the proposed algorithm. The multi-agent DSS is developed through the Repast simulation platform and the constructed DSS can generate intercept plans automatically and support three-dimensional dynamic display of missile defense process. 展开更多
关键词 agent-based modeling missile defense system decision support system (DSS) variable neighborhood negative selection particle swarm optimization (PSO)
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Self-organizing strategy design and validation forintegrated air-ground detection swarm
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作者 Meiyan An Zhaokui Wang yulin zhang 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 2016年第5期1018-1027,共10页
A self-organized integrated air-ground detection swarmis tentatively applied to achieve reentry vehicle landing detection,such as searching and rescuing a manned spaceship. The detectionswarm consists of multiple unma... A self-organized integrated air-ground detection swarmis tentatively applied to achieve reentry vehicle landing detection,such as searching and rescuing a manned spaceship. The detectionswarm consists of multiple unmanned aerial vehicles (UAVs)and unmanned ground vehicles (UGVs). The UAVs can accessa detected object quickly for high mobility, while the UGVs cancomprehensively investigate the object due to the variety of carriedequipment. In addition, the integrated air-ground detectionswarm is capable of detecting from the ground and the air simultaneously.To accomplish the coordination of the UGVs andUAVs, they are all regarded as individuals of the artificial swarm.Those individuals make control decisions independently of othersbased on the self-organizing strategy. The overall requirements forthe detection swarm are analyzed, and the theoretical model ofthe self-organizing strategy based on a combined individual andenvironmental virtual function is established. The numerical investigationproves that the self-organizing strategy is suitable andscalable to control the detection swarm. To further inspect the engineeringreliability, an experiment set is established in laboratory,and the experimental demonstration shows that the self-organizingstrategy drives the detection swarm forming a close range and multiangularsurveillance configuration of a landing spot. 展开更多
关键词 artificial swarm virtual potential field self-organizing integrated air-ground detection swarm.
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