Blast furnace gas(BFG)is an important by-product energy for the iron and steel industry and has been widely used for heating or electricity generation.However,the undesirable contaminants in BFG(especially H_(2)S)gene...Blast furnace gas(BFG)is an important by-product energy for the iron and steel industry and has been widely used for heating or electricity generation.However,the undesirable contaminants in BFG(especially H_(2)S)generate harmful environmental emissions.The desulfurization of BFG is urgent for integrated steel plants due to the stringent ultra-low emission standards.Compared with other desulfurization materials,zeolite-based adsorbents represent a viable option with low costs and long service life.In this study,an ammonia-induced CuO modified 13X adsorbent(NH_(3)–CuO/13X)was prepared for H_(2)S removal from simulated BFG at low temperature.The XRD,H_(2)-TPR and TEM analysis proved that smaller CuO particles were formed and the dispersion of Cu on the surface of 13X zeolite was improved via the induction of ammonia.Evaluation on H_(2)S adsorption performance of the adsorbent was carried out using simulated BFG,and the results showed that NH_(3)–CuO/13X-3 has better breakthrough sulfur capacity,which was more than twice the sulfur capacity of CuO/13X.It is proposed that the enhanced desulfurization performance of NH_(3)–CuO/13X is attributed to an abundant pore of 13X,and combined action of 13X and CuO.This work provided an effective way to improve the sulfur capacity of zeolite-based adsorbents via impregnation method by ammonia induction.展开更多
The heterogeneity of coalbed methane(CBM) resources was not taken into account when the current indiscriminate subsidy policy was developed. In it, limited subsidy funds are given first to high-quality resources and e...The heterogeneity of coalbed methane(CBM) resources was not taken into account when the current indiscriminate subsidy policy was developed. In it, limited subsidy funds are given first to high-quality resources and even to subsidize profitable projects. Thus, the policy has had less than the intended effect in improving CBM production. To implement a new type of differential subsidy, it is necessary to grade the CBM resources, as will be discussed in this paper. After the factors affecting the resources value are systemically examined, sorted and merged, the relationship between the key factors and economic value is analyzed by an engineering economics method, and the production profile type, peak production(or stable production) and buried depth are used as grading factors. The production profile type is used to categorize, and peak production and buried depth are used to grade resources within the same category. The grading method is as follows: use subsidy levels at the economic critical point(NPV = 0) to identify the grades of resources, and determine the combination of peak production and buried depth for different resources grades base on indifference curves drawn according to the relationship between the economic value and peak production and buried depth.展开更多
基金financially supported by National Natural Science Foundation of China(Grant.22076189)National Key Research and Development Program of China(No.2023YFC3707003)the Joint Fund of Yulin University and Dalian National Laboratory for Clean Energy(Grant.YLU-DNL Fund 2022003).
文摘Blast furnace gas(BFG)is an important by-product energy for the iron and steel industry and has been widely used for heating or electricity generation.However,the undesirable contaminants in BFG(especially H_(2)S)generate harmful environmental emissions.The desulfurization of BFG is urgent for integrated steel plants due to the stringent ultra-low emission standards.Compared with other desulfurization materials,zeolite-based adsorbents represent a viable option with low costs and long service life.In this study,an ammonia-induced CuO modified 13X adsorbent(NH_(3)–CuO/13X)was prepared for H_(2)S removal from simulated BFG at low temperature.The XRD,H_(2)-TPR and TEM analysis proved that smaller CuO particles were formed and the dispersion of Cu on the surface of 13X zeolite was improved via the induction of ammonia.Evaluation on H_(2)S adsorption performance of the adsorbent was carried out using simulated BFG,and the results showed that NH_(3)–CuO/13X-3 has better breakthrough sulfur capacity,which was more than twice the sulfur capacity of CuO/13X.It is proposed that the enhanced desulfurization performance of NH_(3)–CuO/13X is attributed to an abundant pore of 13X,and combined action of 13X and CuO.This work provided an effective way to improve the sulfur capacity of zeolite-based adsorbents via impregnation method by ammonia induction.
基金Financial support from the Ministry of Science and Technology of China (No. 2016ZX05042-002-004)Science Foundation of China University of Petroleum, Beijing (No. 2462015YQ0718)
文摘The heterogeneity of coalbed methane(CBM) resources was not taken into account when the current indiscriminate subsidy policy was developed. In it, limited subsidy funds are given first to high-quality resources and even to subsidize profitable projects. Thus, the policy has had less than the intended effect in improving CBM production. To implement a new type of differential subsidy, it is necessary to grade the CBM resources, as will be discussed in this paper. After the factors affecting the resources value are systemically examined, sorted and merged, the relationship between the key factors and economic value is analyzed by an engineering economics method, and the production profile type, peak production(or stable production) and buried depth are used as grading factors. The production profile type is used to categorize, and peak production and buried depth are used to grade resources within the same category. The grading method is as follows: use subsidy levels at the economic critical point(NPV = 0) to identify the grades of resources, and determine the combination of peak production and buried depth for different resources grades base on indifference curves drawn according to the relationship between the economic value and peak production and buried depth.
