Microwave absorbing materials(MAMs)characterized by high absorption efficiency and good environmental tolerance are highly desirable in practical applications.Both silicon carbide and carbon are considered as stable M...Microwave absorbing materials(MAMs)characterized by high absorption efficiency and good environmental tolerance are highly desirable in practical applications.Both silicon carbide and carbon are considered as stable MAMs under some rigorous conditions,while their composites still fail to produce satisfactory microwave absorption performance regardless of the improvements as compared with the individuals.Herein,we have successfully implemented compositional and structural engineering to fabricate hollow Si C/C microspheres with controllable composition.The simultaneous modulation on dielectric properties and impedance matching can be easily achieved as the change in the composition of these composites.The formation of hollow structure not only favors lightweight feature,but also generates considerable contribution to microwave attenuation capacity.With the synergistic effect of composition and structure,the optimized SiC/C composite exhibits excellent performance,whose the strongest reflection loss intensity and broadest effective absorption reach-60.8 dB and 5.1 GHz,respectively,and its microwave absorption properties are actually superior to those of most SiC/C composites in previous studies.In addition,the stability tests of microwave absorption capacity after exposure to harsh conditions and Radar Cross Section simulation data demonstrate that hollow SiC/C microspheres from compositional and structural optimization have a bright prospect in practical applications.展开更多
Carbides/carbon composites are emerging as a new kind of binary dielectric systems with good microwave absorption performance.Herein,we obtain a series of tungsten carbide/carbon composites through a simple solvent-fr...Carbides/carbon composites are emerging as a new kind of binary dielectric systems with good microwave absorption performance.Herein,we obtain a series of tungsten carbide/carbon composites through a simple solvent-free strategy,where the solid mixture of dicyandiamide(DCA)and ammonium metatungstate(AM)is employed as the precursor.Ultrafine cubic WC1-x nanoparticles(3-4 nm)are in situ generated and uniformly dispersed on carbon nanosheets.This configuration overcomes some disadvantages of conventional carbides/carbon composites and is greatly helpful for electromagnetic dissipation.It is found that the weight ratio of DCA to AM can regulate chemical composition of these composites,while less impact on the average size of WC1-x nanoparticles.With the increase in carbon nanosheets,the relative complex permittivity and dielectric loss ability are constantly enhanced through conductive loss and polarization relaxation.The different dielectric properties endow these composites with distinguishable attenuation ability and impedance matching.When DCA/AM weight ratio is 6.0,the optimized composite can produce good microwave absorption performance,whose strongest reflection loss intensity reaches up to-55.6 dB at 17.5 GHz and qualified absorption bandwidth covers 3.6-18.0 GHz by manipulating the thickness from 1.0 to 5.0 mm.Such a performance is superior to many conventional carbides/carbon composites.展开更多
Forest gaps restrict the restoration of temperate secondary forest to broad-leaved Korean pine forest in zonal climax vegetation by affecting the growth of Korean pine(Pinus koraiensis).However,the photo synthetic ada...Forest gaps restrict the restoration of temperate secondary forest to broad-leaved Korean pine forest in zonal climax vegetation by affecting the growth of Korean pine(Pinus koraiensis).However,the photo synthetic adaptability of Korean pine to gap size and position within the gap is unclear.In order to explore the adaptability of young Korean pine(35 years) to different gap sizes in Xiaoxing’anling,photo synthetic capacity and microenvironmental factors(leaf temperature,light transmittance) of Korean pine needles in three positions in the gap(central,transition,and edge areas) were investigated.Three gaps were identified in the secondary Populus davidiana forest:a large 201 m^(2) gap,a middle 112 m^(2) gap,and a small 50 m^(2) gap;12 m^(2) of the understory was sampled as a control.The results show that:(1) maximum net photosynthetic rate(P_(max)) in needles of Korean pine growing in the large gap was higher than in the small gap,and P_(max) in the centre in the same gap was higher than in the transition and edge areas;(2) light saturation point(LSP) and photosynthetic quantum yield(AQY)of needles in the large gap were higher than in the small gap,while the light compensation point(LCP) and chlorophyll contents of needles were lower in the small gap;and,(3)P_(max) had a significant positive correlation with temperature and light transmittance.It is suggested that the larger the gap in secondary Populus davidiana forests,the greater the change in light intensity and temperatures,the stronger the light adaption of Korean pine needles and the higher the photosynthetic capacity.Therefore,in the recovery of broadleaved/Korean pine forests,suitable gaps should be created and gap microhabitats fully utilized to accelerate the restoration process.展开更多
Electrocatalytic oxygen reduction reaction(ORR)and hydrogen evolution reaction(HER)in acidic media are vital for the applications of renewable energy electrolyzers.However,the low mass activity of noble Pt urgently ne...Electrocatalytic oxygen reduction reaction(ORR)and hydrogen evolution reaction(HER)in acidic media are vital for the applications of renewable energy electrolyzers.However,the low mass activity of noble Pt urgently needs to be improved due to the strong binding energetics of oxygen species(*O)with Pt sites.Here we report fine PtxSr alloy(-2 nm)supported on N-doped carb on(NC)pyrolyzing from ZIF-8 as bifunctional electrocatalysts toward ORR and HER in acidic media.The representative Pt_(2)Sr/NC exhibits an onset potential of 0.94 V vs.RHE and half-wave potential of 0.84 V toward ORR,and a low over-potential of 27 mV(10 mA cm^(-2))toward HER,respectively.Significantly,the mass activities of Pt_(2)Sr/NC are 6.2 and 2.6 times higher than that of Pt/C toward ORR(at 0.9 V)and HER(at-30 mV),respectively.Simultaneously,Pt_(2)Sr/NC possesses a retention rate of 90.97%toward acidic ORR after 35000 s of continuous operation.Through density functional theory(DFT)calculations and X-ray photoelectron spectroscopy analysis,the incorporation of Sr into Pt forming Pt_(2)Sr alloy redistributes the electronic structures of Pt-Pt bonds,changing the rate-determining step for the ORR on Pt sites from the formation of*OH from*O to the generation of*OOH along with decreasing the energy barrier,which is also confirmed by the downshift of d band center.Meanwhile,the downshift of d band center also leads to the optimization of the adsorption energy(H*)with Pt,significantly improving Pt_(2)Sr/NC toward HER.展开更多
Security analysis of public-key cryptosystems is of fundamental significance for both theoretical research and applications in cryptography. In particular, the security of widely used public-key cryptosystems merits d...Security analysis of public-key cryptosystems is of fundamental significance for both theoretical research and applications in cryptography. In particular, the security of widely used public-key cryptosystems merits deep research to protect against new types of attacks. It is therefore highly meaningful to research cryptanalysis in the quantum computing environment. Shor proposed a wellknown factoring algorithm by finding the prime factors of a number n =pq, which is exponentially faster than the best known classical algorithm. The idea behind Shor's quantum factoring algorithm is a straightforward programming consequence of the following proposition: to factor n, it suffices to find the order r; once such an r is found, one can compute gcd( a^(r/2) ±1, n)=p or q. For odd values of r it is assumed that the factors of n cannot be found(since a^(r/2) is not generally an integer). That is, the order r must be even. This restriction can be removed, however, by working from another angle. Based on the quantum inverse Fourier transform and phase estimation, this paper presents a new polynomial-time quantum algorithm for breaking RSA, without explicitly factoring the modulus n. The probability of success of the new algorithm is greater than 4φ( r)/π~2 r, exceeding that of the existing quantum algorithm forattacking RSA based on factorization. In constrast to the existing quantum algorithm for attacking RSA, the order r of the fixed point C for RSA does not need to be even. It changed the practices that cryptanalysts try to recover the private-key, directly from recovering the plaintext M to start, a ciphertext-only attack attacking RSA is proposed.展开更多
Two novel nonlinear mode coupling processes for reversed shear Alfvén eigenmode(RSAE) nonlinear saturation are proposed and investigated. In the first process, the RSAE nonlinearly couples to a co-propagating tor...Two novel nonlinear mode coupling processes for reversed shear Alfvén eigenmode(RSAE) nonlinear saturation are proposed and investigated. In the first process, the RSAE nonlinearly couples to a co-propagating toroidal Alfvén eigenmode(TAE) with the same toroidal and poloidal mode numbers, and generates a geodesic acoustic mode. In the second process, the RSAE couples to a counter-propagating TAE and generates an ion acoustic wave quasi-mode. The condition for the two processes to occur is favored during current ramp. Both the processes contribute to effectively saturate the Alfvénic instabilities, as well as nonlinearly transfer of energy from energetic fusion alpha particles to fuel ions in burning plasmas.展开更多
Plant growth and productivity are negatively affected by soil salinity.This study investigated the effects of the rhizosphere-promoting bacterium,Bacillus paramycoides JYZ-SD5,and the ectomycorrhizal fungus,Schizophyl...Plant growth and productivity are negatively affected by soil salinity.This study investigated the effects of the rhizosphere-promoting bacterium,Bacillus paramycoides JYZ-SD5,and the ectomycorrhizal fungus,Schizophyllum commune Be,on the growth of Metasequoia glyptostroboides under salt stress.Changes in biomass,root growth,root ion distribution and in vivo enzyme activities were determined under different treatments(Be,JYZ-SD5,and Be+JYZ-SD5).The results show that all inoculations increased chlorophyll content,shoot length and root diameter with or without salt stress,and the effect of Be+JYZ-SD5was the strongest.JYZ-SD5 and Be+JYZ-SD5 treatments significantly increased root length,surface area,bifurcation number,tip number,main root length and diameter under salt stress.Normal chloroplast structures developed under both single and double inoculations.Relative to the control,root activities of M.glyptostroboides in the Be,JYZSD5,and Be+JYZ-SD5 treatments increased by 31.3%,17.2%,and 33.7%.All treatments increased the activities of superoxide dismutase(SOD),peroxidase(POD),Na^(+)-K^(+)-ATPase and Ca^(2+)-Mg^(2+)-ATPase.The strongest effect was by Be+JYZ-SD5.Analysis of root ion distribution showed that,under salt stress,Na^(+)and K^(+)decreased and were concentrated in the epidermis or cortex.Na/K ratios also decreased.The Be+JYZ-SD5 treatment increased betaine by 130.3%and 97.9%under 50 mM and 100 mM salt stress,respectively.Together,these changes result in the activation of physiological and biochemical processes involved in the mitigation of salinity-induced stress in M.glyptostroboides.展开更多
The parametric decay process of a reversed shear Alfvén eigenmeode(RSAE)into a geodesic acoustic mode and a kinetic RSAE is investigated using nonlinear gyrokinetic theory.The excitation conditions mainly require...The parametric decay process of a reversed shear Alfvén eigenmeode(RSAE)into a geodesic acoustic mode and a kinetic RSAE is investigated using nonlinear gyrokinetic theory.The excitation conditions mainly require the pump RSAE amplitude to exceed a certain threshold,which could be readily satisfied in burning plasmas operated in steady-state advanced scenario.This decay process can contribute to thermal plasma heating and confinement improvement.展开更多
Manipulation of electromagnetic waves is essential to various microwave applications,and absorbing devices composed of low-pressure gas discharge tubes and radar-absorbing materials(RAM)can bring new solutions to broa...Manipulation of electromagnetic waves is essential to various microwave applications,and absorbing devices composed of low-pressure gas discharge tubes and radar-absorbing materials(RAM)can bring new solutions to broadband electromagnetic stealth.The microwave transmission method is used to measure the physical parameters of the plasma unit.The designed structure exhibits superior absorption performance and radar cross-section(RCS)reduction capability in the 2–18 GHz band,with unique absorption advantage in the S and C frequency bands.It is found that the combination of the plasma and the RAM can significantly broaden the absorption frequency band and improve the absorption performance with excellent synergistic stealth capability.Experimental and simulation results present that broadband,wide-angle,tunable electromagnetic wave absorption and RCS reduction can be achieved by adjusting the spatial layout of the combined plasma layer and the type of RAMs,which creates opportunities for microwave transmission and selective stealth of equipment.Therefore,the wave manipulation by combined plasma array and RAM provides a valuable reference for developing numerous applications,including radar antenna stealth,spatial filter,and high power microwave shielding.展开更多
基金supported by the National Natural Science Foundation of China(No.21676065 and No.52373262)China Postdoctoral Science Foundation(2021MD703944,2022T150782).
文摘Microwave absorbing materials(MAMs)characterized by high absorption efficiency and good environmental tolerance are highly desirable in practical applications.Both silicon carbide and carbon are considered as stable MAMs under some rigorous conditions,while their composites still fail to produce satisfactory microwave absorption performance regardless of the improvements as compared with the individuals.Herein,we have successfully implemented compositional and structural engineering to fabricate hollow Si C/C microspheres with controllable composition.The simultaneous modulation on dielectric properties and impedance matching can be easily achieved as the change in the composition of these composites.The formation of hollow structure not only favors lightweight feature,but also generates considerable contribution to microwave attenuation capacity.With the synergistic effect of composition and structure,the optimized SiC/C composite exhibits excellent performance,whose the strongest reflection loss intensity and broadest effective absorption reach-60.8 dB and 5.1 GHz,respectively,and its microwave absorption properties are actually superior to those of most SiC/C composites in previous studies.In addition,the stability tests of microwave absorption capacity after exposure to harsh conditions and Radar Cross Section simulation data demonstrate that hollow SiC/C microspheres from compositional and structural optimization have a bright prospect in practical applications.
基金supported by National Natural Science Foundation of China(21676065 and 21776053)。
文摘Carbides/carbon composites are emerging as a new kind of binary dielectric systems with good microwave absorption performance.Herein,we obtain a series of tungsten carbide/carbon composites through a simple solvent-free strategy,where the solid mixture of dicyandiamide(DCA)and ammonium metatungstate(AM)is employed as the precursor.Ultrafine cubic WC1-x nanoparticles(3-4 nm)are in situ generated and uniformly dispersed on carbon nanosheets.This configuration overcomes some disadvantages of conventional carbides/carbon composites and is greatly helpful for electromagnetic dissipation.It is found that the weight ratio of DCA to AM can regulate chemical composition of these composites,while less impact on the average size of WC1-x nanoparticles.With the increase in carbon nanosheets,the relative complex permittivity and dielectric loss ability are constantly enhanced through conductive loss and polarization relaxation.The different dielectric properties endow these composites with distinguishable attenuation ability and impedance matching.When DCA/AM weight ratio is 6.0,the optimized composite can produce good microwave absorption performance,whose strongest reflection loss intensity reaches up to-55.6 dB at 17.5 GHz and qualified absorption bandwidth covers 3.6-18.0 GHz by manipulating the thickness from 1.0 to 5.0 mm.Such a performance is superior to many conventional carbides/carbon composites.
基金This research was funded by national key research and development project of the"13th Five-Year Plan"of China-(2017YFC0504102).
文摘Forest gaps restrict the restoration of temperate secondary forest to broad-leaved Korean pine forest in zonal climax vegetation by affecting the growth of Korean pine(Pinus koraiensis).However,the photo synthetic adaptability of Korean pine to gap size and position within the gap is unclear.In order to explore the adaptability of young Korean pine(35 years) to different gap sizes in Xiaoxing’anling,photo synthetic capacity and microenvironmental factors(leaf temperature,light transmittance) of Korean pine needles in three positions in the gap(central,transition,and edge areas) were investigated.Three gaps were identified in the secondary Populus davidiana forest:a large 201 m^(2) gap,a middle 112 m^(2) gap,and a small 50 m^(2) gap;12 m^(2) of the understory was sampled as a control.The results show that:(1) maximum net photosynthetic rate(P_(max)) in needles of Korean pine growing in the large gap was higher than in the small gap,and P_(max) in the centre in the same gap was higher than in the transition and edge areas;(2) light saturation point(LSP) and photosynthetic quantum yield(AQY)of needles in the large gap were higher than in the small gap,while the light compensation point(LCP) and chlorophyll contents of needles were lower in the small gap;and,(3)P_(max) had a significant positive correlation with temperature and light transmittance.It is suggested that the larger the gap in secondary Populus davidiana forests,the greater the change in light intensity and temperatures,the stronger the light adaption of Korean pine needles and the higher the photosynthetic capacity.Therefore,in the recovery of broadleaved/Korean pine forests,suitable gaps should be created and gap microhabitats fully utilized to accelerate the restoration process.
基金supported by the Fundamental Research Funds for the Central Universities (2020XZZX002-07)the National Natural Science Foundation of China (21776248, 21676246)supported by Major Scientific Project of Zhejiang Lab, Grant/Award Numbers: 2020MC0AD01.
文摘Electrocatalytic oxygen reduction reaction(ORR)and hydrogen evolution reaction(HER)in acidic media are vital for the applications of renewable energy electrolyzers.However,the low mass activity of noble Pt urgently needs to be improved due to the strong binding energetics of oxygen species(*O)with Pt sites.Here we report fine PtxSr alloy(-2 nm)supported on N-doped carb on(NC)pyrolyzing from ZIF-8 as bifunctional electrocatalysts toward ORR and HER in acidic media.The representative Pt_(2)Sr/NC exhibits an onset potential of 0.94 V vs.RHE and half-wave potential of 0.84 V toward ORR,and a low over-potential of 27 mV(10 mA cm^(-2))toward HER,respectively.Significantly,the mass activities of Pt_(2)Sr/NC are 6.2 and 2.6 times higher than that of Pt/C toward ORR(at 0.9 V)and HER(at-30 mV),respectively.Simultaneously,Pt_(2)Sr/NC possesses a retention rate of 90.97%toward acidic ORR after 35000 s of continuous operation.Through density functional theory(DFT)calculations and X-ray photoelectron spectroscopy analysis,the incorporation of Sr into Pt forming Pt_(2)Sr alloy redistributes the electronic structures of Pt-Pt bonds,changing the rate-determining step for the ORR on Pt sites from the formation of*OH from*O to the generation of*OOH along with decreasing the energy barrier,which is also confirmed by the downshift of d band center.Meanwhile,the downshift of d band center also leads to the optimization of the adsorption energy(H*)with Pt,significantly improving Pt_(2)Sr/NC toward HER.
基金partially supported by he State Key Program of National Natural Science of China No. 61332019Major State Basic Research Development Program of China (973 Program) No. 2014CB340601+1 种基金the National Science Foundation of China No. 61202386, 61402339the National Cryptography Development Fund No. MMJJ201701304
文摘Security analysis of public-key cryptosystems is of fundamental significance for both theoretical research and applications in cryptography. In particular, the security of widely used public-key cryptosystems merits deep research to protect against new types of attacks. It is therefore highly meaningful to research cryptanalysis in the quantum computing environment. Shor proposed a wellknown factoring algorithm by finding the prime factors of a number n =pq, which is exponentially faster than the best known classical algorithm. The idea behind Shor's quantum factoring algorithm is a straightforward programming consequence of the following proposition: to factor n, it suffices to find the order r; once such an r is found, one can compute gcd( a^(r/2) ±1, n)=p or q. For odd values of r it is assumed that the factors of n cannot be found(since a^(r/2) is not generally an integer). That is, the order r must be even. This restriction can be removed, however, by working from another angle. Based on the quantum inverse Fourier transform and phase estimation, this paper presents a new polynomial-time quantum algorithm for breaking RSA, without explicitly factoring the modulus n. The probability of success of the new algorithm is greater than 4φ( r)/π~2 r, exceeding that of the existing quantum algorithm forattacking RSA based on factorization. In constrast to the existing quantum algorithm for attacking RSA, the order r of the fixed point C for RSA does not need to be even. It changed the practices that cryptanalysts try to recover the private-key, directly from recovering the plaintext M to start, a ciphertext-only attack attacking RSA is proposed.
基金Supported by the National Key R&D Program of China(Grant No.2017YFE0301900)the National Natural Science Foundation of China(Grant No.11875233)the China Postdoctoral Science Foundation(Grant No.2020M670756)。
文摘Two novel nonlinear mode coupling processes for reversed shear Alfvén eigenmode(RSAE) nonlinear saturation are proposed and investigated. In the first process, the RSAE nonlinearly couples to a co-propagating toroidal Alfvén eigenmode(TAE) with the same toroidal and poloidal mode numbers, and generates a geodesic acoustic mode. In the second process, the RSAE couples to a counter-propagating TAE and generates an ion acoustic wave quasi-mode. The condition for the two processes to occur is favored during current ramp. Both the processes contribute to effectively saturate the Alfvénic instabilities, as well as nonlinearly transfer of energy from energetic fusion alpha particles to fuel ions in burning plasmas.
基金supported by the National Key Research and Development Program of China (2017YFD0600104)the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)。
文摘Plant growth and productivity are negatively affected by soil salinity.This study investigated the effects of the rhizosphere-promoting bacterium,Bacillus paramycoides JYZ-SD5,and the ectomycorrhizal fungus,Schizophyllum commune Be,on the growth of Metasequoia glyptostroboides under salt stress.Changes in biomass,root growth,root ion distribution and in vivo enzyme activities were determined under different treatments(Be,JYZ-SD5,and Be+JYZ-SD5).The results show that all inoculations increased chlorophyll content,shoot length and root diameter with or without salt stress,and the effect of Be+JYZ-SD5was the strongest.JYZ-SD5 and Be+JYZ-SD5 treatments significantly increased root length,surface area,bifurcation number,tip number,main root length and diameter under salt stress.Normal chloroplast structures developed under both single and double inoculations.Relative to the control,root activities of M.glyptostroboides in the Be,JYZSD5,and Be+JYZ-SD5 treatments increased by 31.3%,17.2%,and 33.7%.All treatments increased the activities of superoxide dismutase(SOD),peroxidase(POD),Na^(+)-K^(+)-ATPase and Ca^(2+)-Mg^(2+)-ATPase.The strongest effect was by Be+JYZ-SD5.Analysis of root ion distribution showed that,under salt stress,Na^(+)and K^(+)decreased and were concentrated in the epidermis or cortex.Na/K ratios also decreased.The Be+JYZ-SD5 treatment increased betaine by 130.3%and 97.9%under 50 mM and 100 mM salt stress,respectively.Together,these changes result in the activation of physiological and biochemical processes involved in the mitigation of salinity-induced stress in M.glyptostroboides.
基金supported by the National Key R&D Program of China(No.2017YFE0301900)National Natural Science Foundation of China(No.11875233)Users of Excellence Program of Hefei Science Center CAS(No.2021HSC-UE016)。
文摘The parametric decay process of a reversed shear Alfvén eigenmeode(RSAE)into a geodesic acoustic mode and a kinetic RSAE is investigated using nonlinear gyrokinetic theory.The excitation conditions mainly require the pump RSAE amplitude to exceed a certain threshold,which could be readily satisfied in burning plasmas operated in steady-state advanced scenario.This decay process can contribute to thermal plasma heating and confinement improvement.
基金supported by National Natural Science Foundation of China(No.51907198)Natural Science Research Foundation of Anhui Province(No.1908085MF205)+1 种基金Director Fund of State Key Laboratory of Pulsed Power Laser Technology(Nos.SKL2021ZR07,SKL2021ZR06)China Postdoctoral Science Foundation(No.2021MD703944).
文摘Manipulation of electromagnetic waves is essential to various microwave applications,and absorbing devices composed of low-pressure gas discharge tubes and radar-absorbing materials(RAM)can bring new solutions to broadband electromagnetic stealth.The microwave transmission method is used to measure the physical parameters of the plasma unit.The designed structure exhibits superior absorption performance and radar cross-section(RCS)reduction capability in the 2–18 GHz band,with unique absorption advantage in the S and C frequency bands.It is found that the combination of the plasma and the RAM can significantly broaden the absorption frequency band and improve the absorption performance with excellent synergistic stealth capability.Experimental and simulation results present that broadband,wide-angle,tunable electromagnetic wave absorption and RCS reduction can be achieved by adjusting the spatial layout of the combined plasma layer and the type of RAMs,which creates opportunities for microwave transmission and selective stealth of equipment.Therefore,the wave manipulation by combined plasma array and RAM provides a valuable reference for developing numerous applications,including radar antenna stealth,spatial filter,and high power microwave shielding.
