Electrochemical catalysts for oxygen evolution reaction are a critical component for many renewable energy applications. To improve their catalytic kinetics and mass activity are essential for sustainable industrial a...Electrochemical catalysts for oxygen evolution reaction are a critical component for many renewable energy applications. To improve their catalytic kinetics and mass activity are essential for sustainable industrial applications. Here, we report a rare-earth metal-based oxide electrocatalyst comprised of ultrathin amorphous La2O3 nanosheets hybridized with uniform La2O3 nanoparticles(La2O3@NP-NS). Significantly improved OER performance is observed from the nanosheets with a nanometer-scale thickness. The as-synthesized 2.27-nm La2O3@NP-NS exhibits excellent catalytic kinetics with an overpotential of 310 mV at 10 m A cm^-2, a small Tafel slope of 43.1 mV dec^-1, and electrochemical impedance of 38 Ω. More importantly, due to the ultrasmall thickness, its mass activity, and turnover frequency reach as high as 6666.7 A g^-1 and 5.79 s^-1, respectively, at an overpotential of 310 mV. Such a high mass activity is more than three orders of magnitude higher than benchmark OER electrocatalysts, such as IrO2 and RuO2. This work presents a sustainable approach toward the development of highly e cient electrocatalysts with largely reduced mass loading of precious elements.展开更多
The popularization of EVs(electric vehicles) has brought an increasingly heavy burden to the development of charging facilities. To meet the demand of rapid energy supply during the driving period, it is necessary to ...The popularization of EVs(electric vehicles) has brought an increasingly heavy burden to the development of charging facilities. To meet the demand of rapid energy supply during the driving period, it is necessary to establish a fast charging station in public area. However, EVs arrive at the charging station randomly and connect to the distribution network for fast charging, it causes the grid power to fluctuate greatly and the peak-valley loads to alternate frequently, which is harmful to the stability of distribution network. In order to reduce the power fluctuation of random charging, the energy storage is used for fast charging stations. The queuing model is determined to demonstrate the load characteristics of fast charging station, and the state space of fast charging station system is described by Markov chain. After that the power of grid and energy storage is quantified as the number of charging pile, and each type of power is configured rationally to establish the random charging model of energy storage fast charging station. Finally, the economic benefit is analyzed according to the queuing theory to verify the feasibility of the model.展开更多
Recently,coded caching has been treated as a promising technique to alleviate the traffic burden in wireless networks.To support high efficient coded caching multicast transmissions,the time-varying heterogeneous chan...Recently,coded caching has been treated as a promising technique to alleviate the traffic burden in wireless networks.To support high efficient coded caching multicast transmissions,the time-varying heterogeneous channel conditions need to be considered.In this paper,a practical and novel multi-source spinal coding(MSSC)scheme is developed for coded caching multicast transmissions under heterogeneous channel conditions.By exploring joint design of network coding and spinal coding(SC),MSSC can achieve unequal link rates in multicast transmissions for different users.Moreover,by leveraging the rateless feature of SC in our design,MSSC can well adapt the link rates of all users in multicast transmissions without any feedback of time-varying channel conditions.A maximum likelihood(ML)based decoding process for MSSC is also developed,which can achieve a linear complexity with respect to the user number in the multicast transmission.Simulation results validate the effectiveness of the MSSC scheme.Compared to the existing scheme,the sum rate of MSSC in multicast transmissions is improved by about 20%.When applying MSSC in coded caching systems,the total transmission time can be reduced by up to 48% for time-varying channels.展开更多
基金supported by Army Research O ce(ARO)under Grant W911NF-16-1-0198the National Science Foundation(DMR-1709025)China Scholarship Council
文摘Electrochemical catalysts for oxygen evolution reaction are a critical component for many renewable energy applications. To improve their catalytic kinetics and mass activity are essential for sustainable industrial applications. Here, we report a rare-earth metal-based oxide electrocatalyst comprised of ultrathin amorphous La2O3 nanosheets hybridized with uniform La2O3 nanoparticles(La2O3@NP-NS). Significantly improved OER performance is observed from the nanosheets with a nanometer-scale thickness. The as-synthesized 2.27-nm La2O3@NP-NS exhibits excellent catalytic kinetics with an overpotential of 310 mV at 10 m A cm^-2, a small Tafel slope of 43.1 mV dec^-1, and electrochemical impedance of 38 Ω. More importantly, due to the ultrasmall thickness, its mass activity, and turnover frequency reach as high as 6666.7 A g^-1 and 5.79 s^-1, respectively, at an overpotential of 310 mV. Such a high mass activity is more than three orders of magnitude higher than benchmark OER electrocatalysts, such as IrO2 and RuO2. This work presents a sustainable approach toward the development of highly e cient electrocatalysts with largely reduced mass loading of precious elements.
基金Supported by National Key Research Program of China(2016YFB0101800)SGCC Scientific and Technological Project(520940170017)State Grid Shanghai Municipal Electric Power Company Scientific and Technological Projects(5209001500KP)
文摘The popularization of EVs(electric vehicles) has brought an increasingly heavy burden to the development of charging facilities. To meet the demand of rapid energy supply during the driving period, it is necessary to establish a fast charging station in public area. However, EVs arrive at the charging station randomly and connect to the distribution network for fast charging, it causes the grid power to fluctuate greatly and the peak-valley loads to alternate frequently, which is harmful to the stability of distribution network. In order to reduce the power fluctuation of random charging, the energy storage is used for fast charging stations. The queuing model is determined to demonstrate the load characteristics of fast charging station, and the state space of fast charging station system is described by Markov chain. After that the power of grid and energy storage is quantified as the number of charging pile, and each type of power is configured rationally to establish the random charging model of energy storage fast charging station. Finally, the economic benefit is analyzed according to the queuing theory to verify the feasibility of the model.
基金supported by National Natural Science Foundation of China(No.61801290 and 61771312).
文摘Recently,coded caching has been treated as a promising technique to alleviate the traffic burden in wireless networks.To support high efficient coded caching multicast transmissions,the time-varying heterogeneous channel conditions need to be considered.In this paper,a practical and novel multi-source spinal coding(MSSC)scheme is developed for coded caching multicast transmissions under heterogeneous channel conditions.By exploring joint design of network coding and spinal coding(SC),MSSC can achieve unequal link rates in multicast transmissions for different users.Moreover,by leveraging the rateless feature of SC in our design,MSSC can well adapt the link rates of all users in multicast transmissions without any feedback of time-varying channel conditions.A maximum likelihood(ML)based decoding process for MSSC is also developed,which can achieve a linear complexity with respect to the user number in the multicast transmission.Simulation results validate the effectiveness of the MSSC scheme.Compared to the existing scheme,the sum rate of MSSC in multicast transmissions is improved by about 20%.When applying MSSC in coded caching systems,the total transmission time can be reduced by up to 48% for time-varying channels.
