La_(2)NiO_(4)has a similar structure to La_(2)CuO_(4)and was proposed as a high-temperature superconductor based on magnetic-moment measurements decades ago.Nevertheless,with the exception for electrical resistance dr...La_(2)NiO_(4)has a similar structure to La_(2)CuO_(4)and was proposed as a high-temperature superconductor based on magnetic-moment measurements decades ago.Nevertheless,with the exception for electrical resistance drop behavior of about 4 orders of magnitude that is claimed to originate from the superconductivity ever observed in Sr-doped La_(N)iO_(4),most electrical data reported to date in La_(N)iO_(4)system exhibit a trivial insulating ground state.Here,we definitively identify the similar electrical resistance drop behavior of more than 3 orders of magnitude in La_(2)NiO_(4+δ).However,our extensive investigations reveal that this phenomenon is a novel insulatorto-metal transition,distinct from superconductivity.Intriguingly,compared to the weak magnetic-field effects,pressure can significantly suppress the transition and transform from the metallic to an insulating ground state,accompanied by an isostructural phase transition.Our work not only elucidates the fundamental properties of the metallic conducting ground state in La_(N)iO_(4)+δ,but also critically challenges the notion of superconductivity in single-layer lanthanum nickelates.展开更多
The rapid improvement in the gel polymer electrolytes(GPEs)with high ionic conductivity brought it closer to practical applications in solid-state Li-metal batteries.The combination of solvent and polymer enables quas...The rapid improvement in the gel polymer electrolytes(GPEs)with high ionic conductivity brought it closer to practical applications in solid-state Li-metal batteries.The combination of solvent and polymer enables quasi-liquid fast ion transport in the GPEs.However,different ion transport capacity between solvent and polymer will cause local nonuniform Li+distribution,leading to severe dendrite growth.In addition,the poor thermal stability of the solvent also limits the operating-temperature window of the electrolytes.Optimizing the ion transport environment and enhancing the thermal stability are two major challenges that hinder the application of GPEs.Here,a strategy by introducing ion-conducting arrays(ICA)is created by vertical-aligned montmorillonite into GPE.Rapid ion transport on the ICA was demonstrated by 6Li solid-state nuclear magnetic resonance and synchrotron X-ray diffraction,combined with computer simulations to visualize the transport process.Compared with conventional randomly dispersed fillers,ICA provides continuous interfaces to regulate the ion transport environment and enhances the tolerance of GPEs to extreme temperatures.Therefore,GPE/ICA exhibits high room-temperature ionic conductivity(1.08 mS cm^(−1))and long-term stable Li deposition/stripping cycles(>1000 h).As a final proof,Li||GPE/ICA||LiFePO_(4) cells exhibit excellent cycle performance at wide temperature range(from 0 to 60°C),which shows a promising path toward all-weather practical solid-state batteries.展开更多
Ecological stoichiometry is an important indicator of biogeochemical cycles and nutrient limitations in terrestrial ecosystems.However,little is known about the response of ecological stoichiometry to plant growth.In ...Ecological stoichiometry is an important indicator of biogeochemical cycles and nutrient limitations in terrestrial ecosystems.However,little is known about the response of ecological stoichiometry to plant growth.In this study,carbon(C),nitrogen(N),and phosphorus(P)concentrations were evaluated in plant tissues(trees,shrubs,and herbs),litter,and soil of young(≤40-year-old),middle-aged(41–60-year-old),near-mature(61–80-year-old),and mature(81–120-year-old)Quercus secondary forests on the Loess Plateau,China.Vegetation composition,plant biomass,and C stock were determined to illustrate their interaction with stoichiometry.Only tree biomass C signifi cantly increased with stand development.Leaf N and trunk P concentrationsgenerally increased,but branch P decreased with growth stage.Fine roots had the highest C and P concentrations at the middle-aged stage.In contrast,shrubs,herbs,litter,and soil C:N:P stoichiometry did not change signifi cantly during stand development.Leaf N and P were positively correlated with soil C,N,P,and their ratios.However,there was no signifi cant correlation between litter and leaves in terms of C:N:P stoichiometry.A redundancy analysis showed that soil N best explained leaf N and P variance,and tree biomass and C stock were related to biotic factors such as tree age and shrub biomass.Hierarchical partitioning analysis indicated that,compared with soil or litter variables,stand age only accounted for a relatively small proportion of leaf C,N,and P variation.Thus,secondary Quercus ecosystems might have inherent ability to maintain sensitive responses of metabolically active organs to environmental factors during stand aging.The results of this work help to elucidate the biogeochemical cycling of secondary forest ecosystems in tree development,provide novel insights into the adaptation strategies of plants in diff erent organs and growth stages,and could be used to guide fertilization programs and optimize forest structure.展开更多
The sublevel top coal caving(SLTCC)mining technology is extensively employed in steeply inclined thick coal seams.Because of the typical characteristics of the short coal face in this mining method,a signifi-cant port...The sublevel top coal caving(SLTCC)mining technology is extensively employed in steeply inclined thick coal seams.Because of the typical characteristics of the short coal face in this mining method,a signifi-cant portion of the top coal is lost at the face end.For reducing the coal loss,the partially reverse drawing technique(PRDT)is proposed as a novel top coal drawing technique.Meanwhile,based on the Bergmark-Roos model(B-R model),a theoretical method for calculating the recovery ratio of top coal based on the top coal boundary equation and residual top coal amount is proposed.The mechanism of PRDT to reduce top coal loss at the face end is revealed by comparing with single-round sequential drawing technique(SSDT).Physical experiments and in-site observation data were used to verify the theoretical model.The results show that PRDT can effectively reduce the amount of residual coal near the roof by optimizing the shape characteristics of top coal boundary.Suggestions for improve recovery ratio in Wudong Coal Mine were given based on its face parameters.展开更多
Strontium titanate(SrTiO_(3))is a typical perovskite-type ceramic oxide and studying its high-pressure phases are critical to understand the ferroelastic phase transition.SrTiO_(3)also can be used as an important anal...Strontium titanate(SrTiO_(3))is a typical perovskite-type ceramic oxide and studying its high-pressure phases are critical to understand the ferroelastic phase transition.SrTiO_(3)also can be used as an important analog of davemaoite(CaSiO_(3))to understand the compositional and velocity structure of the Earth’s interior.However,the high-pressure studies on the cubic-to-tetragonal phase transition pressure and elastic properties remain unclear for SrTiO_(3).Here,we investigate the phase transition and elasticity of single-crystal SrTiO_(3)by Raman and Brillouin scattering combined with diamond anvil cell.The acoustic velocities of single-crystal SrTiO_(3)and the independent elastic constants of cubic and tetragonal SrTiO_(3)are determined up to 27.5 GPa at room temperature.This study indicates that C_(11),C_(12),and C_(44)exhibit abnormal changes at 10.3 GPa,which is related to the cubicto-tetragonal phase transition.Interestingly,a significant softening on shear modulus and a large anisotropy of shear wave splitting(A_(S)^(PO))jump are observed at 10.3 GPa.Using obtained elastic constants,the coefficients of the Landau potential are calculated to understand the phase transition between cubic and tetragonal.The calculated coefficients of the Landau potential are,λ_(2)=3.12×10^(-2)GPa,λ_(4)=-2.02×10^(-2)GPa,B~*=1.34×10^(-4)GPa and B=1.66×10^(-4)GPa.The elastic results have profound implications in understanding the structure of the Earth’s interior and indicate that the presence of tetragonal Ti-bearing CaSiO_(3)helps to explain the large APO S of the Earth’s mid-mantle.展开更多
Amide proton transfer (APT) magnetic resonance imaging (MRI) is an important molecularimaging technique at the protein level in tissue. Neurodegenerative diseases have a highlikelihood of causing abnormal protein accu...Amide proton transfer (APT) magnetic resonance imaging (MRI) is an important molecularimaging technique at the protein level in tissue. Neurodegenerative diseases have a highlikelihood of causing abnormal protein accumulation in the brain, which can be detectedby APT MRI. This article briefly introduces the principles and image processing technologyof APT MRI, and reviews the current state of research on Alzheimer's disease and Parkinson's disease using this technique. Early applications of this approach in these twoneurodegenerative diseases are encouraging, which also suggests continued technicaldevelopment and larger clinical trials to gauge the value of this technique.展开更多
Edible oils derived from aquatic products are rich in lipids beneficial to human health.However,the volatile flavor characteristics of flesh oil and liver oil from Doederleinia berycoides remain unclear.In this study,...Edible oils derived from aquatic products are rich in lipids beneficial to human health.However,the volatile flavor characteristics of flesh oil and liver oil from Doederleinia berycoides remain unclear.In this study,flesh oil and liver oil were extracted from Doederleinia berycoides,revealing different fatty acid compositions and contents.Lipidomics analysis identified a total of 124 differential lipids between the flesh oil and liver oil,including 42 glycerophospholipids(GPs),33 glycerolipids(GLs),23 free fatty acids(FAs),13 sphingolipids(SPs),10 sterols(STs),and 3 prenol lipids(PRs).Analysis using HS-GC-IMS identified 12 key volatile compounds that significantly contributed to the distinct volatile flavors of the flesh and liver oils.The volatile flavors originated from these volatile compounds,which had different Relative Odor Activity Values(ROAVs).Further results from HSSPME-GC-MS showed that the volatile flavors of the flesh oil and liver oil were respectively attributed to 64 and 35 volatile compounds,each with unique key volatile compounds exhibiting different ROAVs.There were significant positive or negative correlations between 18 key differential lipids and 24 volatile compounds in both flesh oil and liver oil.Therefore,the complex lipid profiles are responsible for the unique volatile flavors of flesh oil and liver oil,and the differential lipids play a central role in their volatile flavor formation.These findings provide a foundation for understanding the volatile flavor differences in fish oils and hold promise for further exploration of the molecular mechanisms underlying oil volatile flavors.展开更多
基金supported by the National Key Research and Development Program of China(Grant No.2023YFF0804100)the National Natural Science Foundation of China(Grant Nos.12274168,12074141,and 42102030)+3 种基金Jilin Provincial Science and Technology Development Project(Grant Nos.20210402054GH and 20220101011JC)the Program for Jilin University Science and Technology Innovative Research Team(Grant No.2021-TD-05)the support from the Fundamental Research Funds for the Central UniversitiesNational Major Science Facility Synergetic Extreme Condition User Facility Achievement Transformation Platform Construction(Grant No.2021FGWCXNLJSKJ01)。
文摘La_(2)NiO_(4)has a similar structure to La_(2)CuO_(4)and was proposed as a high-temperature superconductor based on magnetic-moment measurements decades ago.Nevertheless,with the exception for electrical resistance drop behavior of about 4 orders of magnitude that is claimed to originate from the superconductivity ever observed in Sr-doped La_(N)iO_(4),most electrical data reported to date in La_(N)iO_(4)system exhibit a trivial insulating ground state.Here,we definitively identify the similar electrical resistance drop behavior of more than 3 orders of magnitude in La_(2)NiO_(4+δ).However,our extensive investigations reveal that this phenomenon is a novel insulatorto-metal transition,distinct from superconductivity.Intriguingly,compared to the weak magnetic-field effects,pressure can significantly suppress the transition and transform from the metallic to an insulating ground state,accompanied by an isostructural phase transition.Our work not only elucidates the fundamental properties of the metallic conducting ground state in La_(N)iO_(4)+δ,but also critically challenges the notion of superconductivity in single-layer lanthanum nickelates.
基金This work was supported partially by the National Natural Science Foundation of China(No.51973171)China Postdoctoral Science Foundation(No.2019M663687)+1 种基金National Natural Science Foundation of China(No.52105587),the Foundation of State Key Laboratory of Organic-Inorganic Composites(oic-202001003)the University Joint Project-Key Projects of Shaanxi Province(No.2021GXLH-Z-042).
文摘The rapid improvement in the gel polymer electrolytes(GPEs)with high ionic conductivity brought it closer to practical applications in solid-state Li-metal batteries.The combination of solvent and polymer enables quasi-liquid fast ion transport in the GPEs.However,different ion transport capacity between solvent and polymer will cause local nonuniform Li+distribution,leading to severe dendrite growth.In addition,the poor thermal stability of the solvent also limits the operating-temperature window of the electrolytes.Optimizing the ion transport environment and enhancing the thermal stability are two major challenges that hinder the application of GPEs.Here,a strategy by introducing ion-conducting arrays(ICA)is created by vertical-aligned montmorillonite into GPE.Rapid ion transport on the ICA was demonstrated by 6Li solid-state nuclear magnetic resonance and synchrotron X-ray diffraction,combined with computer simulations to visualize the transport process.Compared with conventional randomly dispersed fillers,ICA provides continuous interfaces to regulate the ion transport environment and enhances the tolerance of GPEs to extreme temperatures.Therefore,GPE/ICA exhibits high room-temperature ionic conductivity(1.08 mS cm^(−1))and long-term stable Li deposition/stripping cycles(>1000 h).As a final proof,Li||GPE/ICA||LiFePO_(4) cells exhibit excellent cycle performance at wide temperature range(from 0 to 60°C),which shows a promising path toward all-weather practical solid-state batteries.
基金supported by the National Nature Science Foundation of China(No.41977418 and 42130717)National Key R&D Program of China(2016YFC0501703 and 2017YFC0504605)CAS“Light of West China”Program(XAB201702).
文摘Ecological stoichiometry is an important indicator of biogeochemical cycles and nutrient limitations in terrestrial ecosystems.However,little is known about the response of ecological stoichiometry to plant growth.In this study,carbon(C),nitrogen(N),and phosphorus(P)concentrations were evaluated in plant tissues(trees,shrubs,and herbs),litter,and soil of young(≤40-year-old),middle-aged(41–60-year-old),near-mature(61–80-year-old),and mature(81–120-year-old)Quercus secondary forests on the Loess Plateau,China.Vegetation composition,plant biomass,and C stock were determined to illustrate their interaction with stoichiometry.Only tree biomass C signifi cantly increased with stand development.Leaf N and trunk P concentrationsgenerally increased,but branch P decreased with growth stage.Fine roots had the highest C and P concentrations at the middle-aged stage.In contrast,shrubs,herbs,litter,and soil C:N:P stoichiometry did not change signifi cantly during stand development.Leaf N and P were positively correlated with soil C,N,P,and their ratios.However,there was no signifi cant correlation between litter and leaves in terms of C:N:P stoichiometry.A redundancy analysis showed that soil N best explained leaf N and P variance,and tree biomass and C stock were related to biotic factors such as tree age and shrub biomass.Hierarchical partitioning analysis indicated that,compared with soil or litter variables,stand age only accounted for a relatively small proportion of leaf C,N,and P variation.Thus,secondary Quercus ecosystems might have inherent ability to maintain sensitive responses of metabolically active organs to environmental factors during stand aging.The results of this work help to elucidate the biogeochemical cycling of secondary forest ecosystems in tree development,provide novel insights into the adaptation strategies of plants in diff erent organs and growth stages,and could be used to guide fertilization programs and optimize forest structure.
基金supported by the Beijing Natural Science Foundation(No.2232059)the National Natural Science Foundation of China(Nos.52121003,52374148,52204163 and 51934008)+1 种基金the Fundamental Research Funds for the Central Universities(Nos.2023JCCXNY04 and 2023YQTD02)the Open Fund of Key laboratory of Xinjiang Coal Resources Green Mining,Ministry of Education(No.KLXGY-KB2408)。
文摘The sublevel top coal caving(SLTCC)mining technology is extensively employed in steeply inclined thick coal seams.Because of the typical characteristics of the short coal face in this mining method,a signifi-cant portion of the top coal is lost at the face end.For reducing the coal loss,the partially reverse drawing technique(PRDT)is proposed as a novel top coal drawing technique.Meanwhile,based on the Bergmark-Roos model(B-R model),a theoretical method for calculating the recovery ratio of top coal based on the top coal boundary equation and residual top coal amount is proposed.The mechanism of PRDT to reduce top coal loss at the face end is revealed by comparing with single-round sequential drawing technique(SSDT).Physical experiments and in-site observation data were used to verify the theoretical model.The results show that PRDT can effectively reduce the amount of residual coal near the roof by optimizing the shape characteristics of top coal boundary.Suggestions for improve recovery ratio in Wudong Coal Mine were given based on its face parameters.
基金support from China Postdoctoral Science Foundation(Grant No.2020M670841)support from the National Key Research and Development Program of China(Grant No.2017YFA0403704)+3 种基金supports from the National Natural Science Foundation of China(Grant Nos.12074141,42102030,and 11974129)support from Jilin Provincial Science and Technology Development Project(Grant Nos.20210402054GH and 20210509038RQ)support from the Program for Science and Technology of Education Department of Jilin Province(Grant No.JJKH20211036KJ)the Fundamental Research Funds for the Central Universities。
文摘Strontium titanate(SrTiO_(3))is a typical perovskite-type ceramic oxide and studying its high-pressure phases are critical to understand the ferroelastic phase transition.SrTiO_(3)also can be used as an important analog of davemaoite(CaSiO_(3))to understand the compositional and velocity structure of the Earth’s interior.However,the high-pressure studies on the cubic-to-tetragonal phase transition pressure and elastic properties remain unclear for SrTiO_(3).Here,we investigate the phase transition and elasticity of single-crystal SrTiO_(3)by Raman and Brillouin scattering combined with diamond anvil cell.The acoustic velocities of single-crystal SrTiO_(3)and the independent elastic constants of cubic and tetragonal SrTiO_(3)are determined up to 27.5 GPa at room temperature.This study indicates that C_(11),C_(12),and C_(44)exhibit abnormal changes at 10.3 GPa,which is related to the cubicto-tetragonal phase transition.Interestingly,a significant softening on shear modulus and a large anisotropy of shear wave splitting(A_(S)^(PO))jump are observed at 10.3 GPa.Using obtained elastic constants,the coefficients of the Landau potential are calculated to understand the phase transition between cubic and tetragonal.The calculated coefficients of the Landau potential are,λ_(2)=3.12×10^(-2)GPa,λ_(4)=-2.02×10^(-2)GPa,B~*=1.34×10^(-4)GPa and B=1.66×10^(-4)GPa.The elastic results have profound implications in understanding the structure of the Earth’s interior and indicate that the presence of tetragonal Ti-bearing CaSiO_(3)helps to explain the large APO S of the Earth’s mid-mantle.
文摘Amide proton transfer (APT) magnetic resonance imaging (MRI) is an important molecularimaging technique at the protein level in tissue. Neurodegenerative diseases have a highlikelihood of causing abnormal protein accumulation in the brain, which can be detectedby APT MRI. This article briefly introduces the principles and image processing technologyof APT MRI, and reviews the current state of research on Alzheimer's disease and Parkinson's disease using this technique. Early applications of this approach in these twoneurodegenerative diseases are encouraging, which also suggests continued technicaldevelopment and larger clinical trials to gauge the value of this technique.
基金supported by the R&D Projects in Key Areas of Guangdong Province(2023B0202080003)the National Natural Science Foundation of China(32472272,32302135,32072291)+1 种基金“Pioneer”and“Leading Goose”R&D Program of Zhejiang(2023C02006)Youth S&T Talent Support Programme of Guangdong Provincial Association for Science and Technology(SKXRC202401)。
文摘Edible oils derived from aquatic products are rich in lipids beneficial to human health.However,the volatile flavor characteristics of flesh oil and liver oil from Doederleinia berycoides remain unclear.In this study,flesh oil and liver oil were extracted from Doederleinia berycoides,revealing different fatty acid compositions and contents.Lipidomics analysis identified a total of 124 differential lipids between the flesh oil and liver oil,including 42 glycerophospholipids(GPs),33 glycerolipids(GLs),23 free fatty acids(FAs),13 sphingolipids(SPs),10 sterols(STs),and 3 prenol lipids(PRs).Analysis using HS-GC-IMS identified 12 key volatile compounds that significantly contributed to the distinct volatile flavors of the flesh and liver oils.The volatile flavors originated from these volatile compounds,which had different Relative Odor Activity Values(ROAVs).Further results from HSSPME-GC-MS showed that the volatile flavors of the flesh oil and liver oil were respectively attributed to 64 and 35 volatile compounds,each with unique key volatile compounds exhibiting different ROAVs.There were significant positive or negative correlations between 18 key differential lipids and 24 volatile compounds in both flesh oil and liver oil.Therefore,the complex lipid profiles are responsible for the unique volatile flavors of flesh oil and liver oil,and the differential lipids play a central role in their volatile flavor formation.These findings provide a foundation for understanding the volatile flavor differences in fish oils and hold promise for further exploration of the molecular mechanisms underlying oil volatile flavors.
