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基于琥珀酸衍生物为单体的聚酯的合成与表征 被引量:2
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作者 程正载 周佳丽 +6 位作者 刘盼盼 谢聪 王云 胡海 曾胜 丁玲 Mario Gauthier 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2019年第11期17-22,共6页
以1,4-环己二酮-2,5-二甲酸二甲酯(DMSS)为起始原料,采用两步法成功制备了2,5-二甲氧基对苯二甲酸二甲酯(DMDMT)。分别以DMDMT和不同碳链的脂肪二醇为单体,在三氧化二锑的催化作用下,采用熔融共聚酯交换法合成了4种由脂肪族二元醇-芳香... 以1,4-环己二酮-2,5-二甲酸二甲酯(DMSS)为起始原料,采用两步法成功制备了2,5-二甲氧基对苯二甲酸二甲酯(DMDMT)。分别以DMDMT和不同碳链的脂肪二醇为单体,在三氧化二锑的催化作用下,采用熔融共聚酯交换法合成了4种由脂肪族二元醇-芳香族二元酸构成的聚酯。经过溶解、沉淀、离心等分离手段,得到目标聚酯a^d。通过红外光谱、核磁共振氢谱、凝胶渗透色谱、差示扫描量热分析和热重分析对其进行表征和分析。聚酯a^d的PDI在1.95~2.70之间,数均相对分子质量(Mn)在10000~15200之间。研究了聚合物中分子主链柔顺性对聚合物的热性能的影响,其中,聚酯a的熔点(Tm)较高,达到90℃,其初始分解温度(T5%)高达363℃;随着脂肪族碳链的碳数增加,所合成的聚酯a^d的熔点和初始分解温度(T5%)下降,这为新型脂肪族-芳香族聚酯的分子设计与合成提供了有益的参考。 展开更多
关键词 2 5-二甲氧基对苯二甲酸二甲酯 脂肪族-芳香族聚酯 热性能 熔融共聚酯交换法
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First proof-of-principle experiment with the post-accelerated isotope separator on-line beam at BRIF:measurement of the angular distribution of ^(23)Na+^(40)Ca elastic scattering 被引量:13
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作者 Wei Nan Bing Guo +34 位作者 Cheng-Jian Lin Lei Yang Dong-Xi Wang Yang-Ping Shen Bing Tang Bao-Qun Cui Tao Ge Yin-Long Lyu Hui-Ming Jia Yun-Ju Li Chen Chen Li-Hua Chen Qi-Wen Fan Xin-Yue Li Gang Lian Jian-Cheng Liu Tian-Peng Luo Nan-Ru Ma Rui-Gang Ma Xie Ma Ying-Jun Ma Wei-Ke Nan Dan-Yang Pang You-Bao Wang Pei-Wei Wen Feng Yang Yong-Jin Yao sheng zeng Hao Zhang Fu-Peng Zhong Shan-Hao Zhong Zhi-Hong Li Tian-Jue Zhang Wei-Ping Liu BRIF Collaboration 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2021年第5期101-106,共6页
The reaction dynamics of exotic nuclei near the drip line is one of the main research topics of current interest.Elastic scattering is a useful probe for investigating the size and surface diffuseness of exotic nuclei... The reaction dynamics of exotic nuclei near the drip line is one of the main research topics of current interest.Elastic scattering is a useful probe for investigating the size and surface diffuseness of exotic nuclei.The development of rare isotope accelerators offers opportunities for such studies.To date,many relevant measurements have been performed at accelerators using the projectile fragmentation technique,while the measurements at accelerators using isotope separator on-line(ISOL)systems are still quite scarce.In this work,we present the first proof-of-principle experiment with a post-accelerated ISOL beam at the Beijing Radioactive Ion Beam Facility(BRIF)by measuring the angular distribution of elastic scattering for the stable nucleus^(23)Na from the doubly magic nucleus^(40)Ca at energies above the Coulomb barrier.The angular distribution measured by a silicon strip detector array in a scattering chamber using the ISOL beam at BRIF is in good agreement with that measured by the high-precision Q3 D magnetic spectrograph using the nonISOL beam at nearly the same energy.This work provides useful background for making BRIF a powerful tool for the investigation of the reaction dynamics of exotic nuclei. 展开更多
关键词 BRIF Exotic nuclei Elastic scattering Angular distribution
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3D characterization of porosity and minerals of low-permeability uranium-bearing sandstone based on multi-resolution image fusion 被引量:8
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作者 Bing Sun Shan-Shan Hou +3 位作者 sheng zeng Xin Bai Shu-Wen Zhang Jing Zhang 《Nuclear Science and Techniques》 SCIE CAS CSCD 2020年第10期115-134,共20页
In the process of in situ leaching of uranium,the microstructure controls and influences the flow distribution,percolation characteristics,and reaction mechanism of lixivium in the pores of reservoir rocks and directl... In the process of in situ leaching of uranium,the microstructure controls and influences the flow distribution,percolation characteristics,and reaction mechanism of lixivium in the pores of reservoir rocks and directly affects the leaching of useful components.In this study,the pore throat,pore size distribution,and mineral composition of low-permeability uranium-bearing sandstone were quantitatively analyzed by high pressure mercury injection,nuclear magnetic resonance,X-ray diffraction,and wavelength-dispersive X-ray fluorescence.The distribution characteristics of pores and minerals in the samples were qualitatively analyzed using energy-dispersive scanning electron microscopy and multi-resolution CT images.Image registration with the landmarks algorithm provided by FEI Avizo was used to accurately match the CT images with different resolutions.The multi-scale and multi-mineral digital core model of low-permeability uranium-bearing sandstone is reconstructed through pore segmentation and mineral segmentation of fusion core scanning images.The results show that the pore structure of low-permeability uranium-bearing sandstone is complex and has multi-scale and multi-crossing characteristics.The intergranular pores determine the main seepage channel in the pore space,and the secondary pores have poor connectivity with other pores.Pyrite and coffinite are isolated from the connected pores and surrounded by a large number of clay minerals and ankerite cements,which increases the difficulty of uranium leaching.Clays and a large amount of ankerite cement are filled in the primary and secondary pores and pore throats of the low-permeability uraniumbearing sandstone,which significantly reduces the porosity of the movable fluid and results in low overall permeability of the cores.The multi-scale and multi-mineral digital core proposed in this study provides a basis for characterizing macroscopic and microscopic pore-throat structures and mineral distributions of low-permeability uranium-bearing sandstone and can better understand the seepage characteristics. 展开更多
关键词 Low-permeability uranium-bearing sandstone Digital core MICRO-CT SEM–EDS Image fusion
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