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聚吡咯@二氧化锰/碳纳米管薄膜电极的制备及在高性能锌离子电池中的应用 被引量:4
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作者 沈晓帆 王晓娜 +7 位作者 俞能晟 杨薇 周雨融 石艳红 王玉莲 董立忠 邸江涛 李清文 《物理化学学报》 SCIE CAS CSCD 北大核心 2022年第5期52-59,共8页
中性/弱酸性水系锌锰电池因其能量密度高、价格低廉、环境友好等优势受到广泛关注。然而,现有的二氧化锰正极材料存在导电性能差,在充放电过程中易于溶解等问题。这严重影响了电池的倍率性能和循环稳定性,阻碍了中性锌锰电池的应用。为... 中性/弱酸性水系锌锰电池因其能量密度高、价格低廉、环境友好等优势受到广泛关注。然而,现有的二氧化锰正极材料存在导电性能差,在充放电过程中易于溶解等问题。这严重影响了电池的倍率性能和循环稳定性,阻碍了中性锌锰电池的应用。为了解决上述问题,本文设计了以碳纳米管(CNT)网络薄膜为导电基底沉积聚吡咯(PPy)包覆二氧化锰(PPy@MnO_(2)/CNT)的多级结构电极。碳纳米管和聚吡咯组装形成高比表面积的三维交联导电网络,为活性材料提供了快速的电子、离子传输通道;聚吡咯包覆纳米级二氧化锰能够有效地抑制二氧化锰的溶解,进而提升电池的倍率特性和循环稳定性。以PPy@MnO_(2)/CNT作为正极材料组装的水系锌锰电池在1 A·g^(-1)的电流密度下,比容量达到210 mAh·g^(-1),循环1000圈后,电池依然具有较高的容量保持率(85.7%)。本工作的导电聚合物包覆活性物质的策略可为发展高稳定柔性储能器件提供新思路。 展开更多
关键词 锌离子电池 聚吡咯@二氧化锰 碳纳米管 柔性电池 长循环
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Dual-Ion Co-Regulation System Enabling High-Performance Electrochemical Artificial Yarn Muscles with Energy-Free Catch States 被引量:1
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作者 Ming Ren lizhong dong +11 位作者 Xiaobo Wang Yuxin Li Yueran Zhao Bo Cui Guang Yang Wei Li Xiaojie Yuan Tao Zhou Panpan Xu Xiaona Wang Jiangtao Di Qingwen Li 《Nano-Micro Letters》 SCIE EI CAS CSCD 2023年第10期15-27,共13页
Artificial yarn muscles show great potential in applications requiring low-energy consumption while maintaining high performance. However, conventional designs have been limited by weak ion-yarn muscle interactions an... Artificial yarn muscles show great potential in applications requiring low-energy consumption while maintaining high performance. However, conventional designs have been limited by weak ion-yarn muscle interactions and inefficient “rocking-chair” ion migration. To address these limitations, we present an electrochemical artificial yarn muscle design driven by a dual-ion co-regulation system. By utilizing two reaction channels, this system shortens ion migration pathways, leading to faster and more efficient actuation. During the charging/discharging process, PF_6~- ions react with carbon nanotube yarn, while Li~+ ions react with an Al foil. The intercalation reaction between PF_6~- and collapsed carbon nanotubes allows the yarn muscle to achieve an energy-free high-tension catch state. The dual-ion coordinated yarn muscles exhibit superior contractile stroke, maximum contractile rate, and maximum power densities, exceeding those of “rocking-chair” type ion migration yarn muscles. The dual-ion co-regulation system enhances the ion migration rate during actuation, resulting in improved performance. Moreover, the yarn muscles can withstand high levels of isometric stress, displaying a stress of 61 times that of skeletal muscles and 8 times that of “rocking-chair” type yarn muscles at higher frequencies. This technology holds significant potential for various applications, including prosthetics and robotics. 展开更多
关键词 Artificial muscles Carbon nanotube yarns Electrochemical actuators Catch state Dual-ion co-regulation
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