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不同粘土矿物对赖氨酸的吸附行为对比研究 被引量:4
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作者 开炜 蔡元峰 +1 位作者 蔡进功 季峻峰 《高校地质学报》 CAS CSCD 北大核心 2018年第5期671-680,共10页
以皂石、高岭石、绿泥石和伊利石为原材料,分别与赖氨酸进行反应,研究赖氨酸在上述粘土矿物上的吸附行为,并运用粉末X-射线衍射技术(XRD)、傅里叶变换红外吸收光谱术(FTIR)和热重(TG)等分析方法,表征反应前后粘土矿物的变化。实验结果表... 以皂石、高岭石、绿泥石和伊利石为原材料,分别与赖氨酸进行反应,研究赖氨酸在上述粘土矿物上的吸附行为,并运用粉末X-射线衍射技术(XRD)、傅里叶变换红外吸收光谱术(FTIR)和热重(TG)等分析方法,表征反应前后粘土矿物的变化。实验结果表明,不同粘土矿物对赖氨酸的吸附等温线均符合Freundlich等温方程,且不同粘土矿物对赖氨酸的饱和吸附量大小顺序为:皂石>蒙脱石>绿泥石>高岭石>伊利石;XRD结果表明皂石对赖氨酸的吸附发生在矿物层间,而绿泥石、高岭石和伊利石对赖氨酸的吸附主要在矿物表面进行;FTIR和TG结果表明赖氨酸主要取代粘土矿物层间吸附水,以氢键的形式与Si-O-Si(^(IV)Al)键合。实验结果将有助于进一步探明环境中粘土矿物对有机质的吸附机理。 展开更多
关键词 皂石 高岭石 蒙脱石 绿泥石 伊利石 赖氨酸 吸附
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Model-driven full system dynamics estimation of PMSM-driven chain shell magazine 被引量:2
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作者 kai wei Longmiao Chen Quan Zou 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第9期147-156,共10页
Based on the system dynamic model, a full system dynamics estimation method is proposed for a chain shell magazine driven by a permanent magnet synchronous motor(PMSM). An adaptive extended state observer(AESO) is pro... Based on the system dynamic model, a full system dynamics estimation method is proposed for a chain shell magazine driven by a permanent magnet synchronous motor(PMSM). An adaptive extended state observer(AESO) is proposed to estimate the unmeasured states and disturbance, in which the model parameters are adjusted in real time. Theoretical analysis shows that the estimation errors of the disturbances and unmeasured states converge exponentially to zero, and the parameter estimation error can be obtained from the extended state. Then, based on the extended state of the AESO, a novel parameter estimation law is designed. Due to the convergence of AESO, the novel parameter estimation law is insensitive to controllers and excitation signal. Under persistent excitation(PE) condition, the estimated parameters will converge to a compact set around the actual parameter value. Without PE signal, the estimated parameters will converge to zero for the extended state. Simulation and experimental results show that the proposed method can accurately estimate the unmeasured states and disturbance of the chain shell magazine, and the estimated parameters will converge to the actual value without strictly continuous PE signals. 展开更多
关键词 Chain shell magazine Full system dynamics estimation Disturbance estimation Parameter estimation Adaptive extended state observer
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