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超临界二氧化碳辅助挤出制备微孔醋酸纤维素 被引量:3
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作者 熊奥 阮建 +1 位作者 丁亚军 应三九 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2021年第3期24-31,共8页
为了连续化制备泡孔结构良好的微孔二醋酸纤维素(CDA)材料,采用超临界二氧化碳(SC-CO_(2))辅助CDA挤出发泡,通过扫描电镜对微孔CDA材料断面形貌进行了观测,研究了CO_(2)注气量、螺杆转速和溶剂比对CDA泡孔形貌的影响,结果显示,随着CO_(2... 为了连续化制备泡孔结构良好的微孔二醋酸纤维素(CDA)材料,采用超临界二氧化碳(SC-CO_(2))辅助CDA挤出发泡,通过扫描电镜对微孔CDA材料断面形貌进行了观测,研究了CO_(2)注气量、螺杆转速和溶剂比对CDA泡孔形貌的影响,结果显示,随着CO_(2)注气量增加,泡孔密度从9.3×10^(7)cm^(-3)增加至1.04×10^(11)cm^(-3),平均泡孔直径从10.06μm减小至1.16μm;随着螺杆转速的提高,压降速率显著增加,泡孔密度从6.6×10^(7)cm^(-3)增加到了9.12×10^(10) cm^(-3),泡孔直径从28.1μm减小到了0.88μm;随着醇酮溶剂用量的增加,泡孔密度降低,并出现了泡孔合并现象。采用SC-CO_(2)辅助挤出发泡技术可以制备出含有致密泡孔结构的微孔CDA材料。 展开更多
关键词 二醋酸纤维素 超临界二氧化碳 挤出发泡 微孔结构
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Thermal hazard assessment of TKX-50-based melt-cast explosive 被引量:4
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作者 Jun-feng Wang Shu-sen Chen +5 位作者 Shao-hua Jin Qing-hai Shu Feng-lei Huang jian ruan Xiao Ma Kun Chen 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2022年第9期1546-1551,共6页
In the present study, thermal hazards of TNT and DNAN used as the molten binder in TKX-50-based meltcast explosives were comparatively studied through accelerating rate calorimeter(ARC) and Cook-off experiments. Two k... In the present study, thermal hazards of TNT and DNAN used as the molten binder in TKX-50-based meltcast explosives were comparatively studied through accelerating rate calorimeter(ARC) and Cook-off experiments. Two kinds of ARC operation modes were performed to investigate the thermal safety performance under adiabatic conditions(HWS mode) and constant heating(CHR mode). The obtained results demonstrated that at both heating modes, DNAN/TKX-50 outperformed TNT/TKX-50 from the thermal safety point of view. However, the sensitivity to heat of the samples was reverse because of the different heating modes. In addition, the results of thermal hazard assessment obtained from the cookoff experiment complied with ARC analysis which indicated the molten binder TNT replaced by DNAN would reduce the hazard of the TKX-50 melt cast explosive. Furthermore, the results of cook-off experiments also showed that DNAN/TKX-50 outperformed TNT/TKX-50 from the aspect of thermal stability, which was consistent with the result of CHR mode because of the similar heating process. 展开更多
关键词 Dihydroxylammonium 5 5’-bistetrazole-1 1’-diolate(TKX-50) 2 4-Dinitroanisole(DNAN) Thermal safety performance Accelerating rate calorimeter(ARC) Cook-off
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A specialized code for operation transient analysis and its application in fluoride salt-cooled high-temperature reactors 被引量:1
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作者 jian ruan Bo Xu +3 位作者 Ming-Hai Li Yang Yang Yang Zou Hong-Jie Xu 《Nuclear Science and Techniques》 SCIE CAS CSCD 2017年第8期133-145,共13页
Fluoride salt-cooled high-temperature reactors(FHRs) include many attractive features, such as high temperature, large heat capacity, low pressure and strong inherent safety. Transient characteristics of FHR are parti... Fluoride salt-cooled high-temperature reactors(FHRs) include many attractive features, such as high temperature, large heat capacity, low pressure and strong inherent safety. Transient characteristics of FHR are particularly important for evaluating its operation performance. Thus, a specialized code OCFHR(operation and control analysis code of FHR) issued to study an experimental FHR's operation behaviors. The geometric modeling of OCFHR is based on one-dimensional lumped parameter method, and some simplifications are taken into consideration during simulation due to the existence of complex structures such as pebble bed, intermediate heat exchanger(IHX), air radiator(AR) and multiply channels.A point neutron kinetics model is developed, and neutron physics calculation is needed to provide some key inputs including axial power density distribution, reactivity coefficients and parameters about delayed neutron precursors. For analyzing the operational performance, five disturbed transients are simulated, involving reactivity step insertion, variations of coolant mass flow rate of primary loop and intermediate loop, adjustment of air inlet temperature and mass flow rate of air cooling system.Simulation results indicate that inherent self-stability of FHR restrains severe consequences under above transients,and some dynamic features are observed, such as large negative temperature feedbacks, remarkable thermal inertia and high response delay. 展开更多
关键词 操作行为 高温堆 冷却剂 氟化盐 代码 瞬态分析 应用 中间热交换器
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