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原位红外反射-吸收光谱研究PEG对PHBHx薄膜的热性能影响
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作者 陈玉静 区菊花 +4 位作者 孔振兴 杨锐 戴子林 isao noda Young Mee Jung 《光谱学与光谱分析》 SCIE EI CAS CSCD 北大核心 2020年第S01期39-40,共2页
聚合物薄膜在界面受限效应作用下的成核结晶与其体材料有显著差异,从而导致其形貌,取向和热性能呈现独特性质。最近我们课题组研究分子量为400的聚乙二醇(PEG)对6.9 mol%3-羟基己酸与3-羟基丁酸共聚酯(PHBHx6.9)薄膜的影响,发现与10 wt%... 聚合物薄膜在界面受限效应作用下的成核结晶与其体材料有显著差异,从而导致其形貌,取向和热性能呈现独特性质。最近我们课题组研究分子量为400的聚乙二醇(PEG)对6.9 mol%3-羟基己酸与3-羟基丁酸共聚酯(PHBHx6.9)薄膜的影响,发现与10 wt%的PEG共混后,PHBHx薄膜在Si基底上规整的侧立型结构被破坏。当PEG加入量达到30 wt%时,PHBHx的分子链折叠位于水平和垂直方向之间,这种独特的折叠方式在100℃以下稳定存在。鉴于3-羟基己酸(HHx)单体的摩尔量对PHBHx性质有显著影响,将在前面研究基础拓展PEG对不同HHx含量的PHBHx薄膜性能的影响。利用原位红外-反射吸收光谱(IRRAS)研究PEG对增加3-羟基己酸(HHx)摩尔量至13 mol%后PHBHx的热性能影响。 展开更多
关键词 红外反射-吸收光谱(IRRAS) 界面受限 3-羟基己酸与3-羟基丁酸共聚酯(PHBHx) 聚乙二醇(PEG) 热性能
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Evolution of Two-Dimensional Correlation Spectroscopy
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作者 isao noda 《光谱学与光谱分析》 SCIE EI CAS CSCD 北大核心 2016年第S1期3-4,共2页
A number of useful techniques associated with two-dimensional correlation spectroscopy(2DCOS)to improve its performance and utility have been developed in the last 30years.Evolution of these 2DCOS techniques,including... A number of useful techniques associated with two-dimensional correlation spectroscopy(2DCOS)to improve its performance and utility have been developed in the last 30years.Evolution of these 2DCOS techniques,including some of the very recent developments,is reviewed with examples.Topics include merged or modified asynchronous 2Dcorrelation spectrum,two-dimensional codistribution spectroscopy(2DCDS),Pareto scaling,and null-space projection treatment of spectral dataset. 展开更多
关键词 Two-dimensional correlation spectroscopy 2DCOS 2DCDS Merged 2D Pareto scaling Nullspace projection
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Thermal Behavior and Crystal Transition of Biodegradable Poly(butylenes adipate)Revealed by Two-Dimensional Correlation Spectroscopy
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作者 CHEN Yu-jing isao noda Young Mee Jung 《光谱学与光谱分析》 SCIE EI CAS CSCD 北大核心 2016年第S1期139-140,共2页
In the present study,thermal behavior and crystal transition of pure poly(butylene adipate)(PBA)upon heating process were investigated by FTIR spectroscopy.To gain further insight into the thermal behavior alteration ... In the present study,thermal behavior and crystal transition of pure poly(butylene adipate)(PBA)upon heating process were investigated by FTIR spectroscopy.To gain further insight into the thermal behavior alteration and the phase transition of PBA,we performed two-dimensional(2D)correlation analysis.We found thatβ-form PBA crystal undergoes not only the melting process but also crystal transition upon the heating process. 展开更多
关键词 Poly(butylene adipate) Thermal behavior Crystal transition Two-dimensional correlation spec-troscopy
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