Scrap metals are typically covered with surface contaminants,such as paint,dust,and rust,which can significantly affect the emission spectrum during laser-induced breakdown spectroscopy(LIBS)based sorting.In this stud...Scrap metals are typically covered with surface contaminants,such as paint,dust,and rust,which can significantly affect the emission spectrum during laser-induced breakdown spectroscopy(LIBS)based sorting.In this study,the effects of paint layers on metal surfaces during LIBS classification were investigated.LIBS spectra were collected from metal surfaces painted with black and white paints by ablation with a nanosecond pulsed laser(wavelength=1064 nm,pulse width=7 ns).For the black-painted samples,the LIBS spectra showed a broad background emission,emission lines unrelated to the target metals,large shot-to-shot variation,and a relatively low signal intensity of the target metal,causing poor classification accuracy even at high shot numbers.Cleaning the black paint layer by ablating over a wide area prior to LIBS analysis resulted in high classification accuracy with fewer shot numbers.A method to determine the number of cleaning shots necessary to obtain high classification accuracy and high throughput is proposed on the basis of the change in LIBS signal intensity during cleaning shots.For the white-painted samples,the paint peeled off the metal surface after the first shot,and strong LIBS signals were measured after the following shot,which were attributed to the nanoparticles generated by the ablation of the paint,allowing an accurate classification after only two shots.The results demonstrate that different approaches must be employed depending on the paint color to achieve high classification accuracy with fewer shot numbers.展开更多
Laser-structuring is an effective method to promote ion diffusion and improve the performance of lithium-ion battery(LIB)electrodes.In this work,the effects of laser structuring parameters(groove pitch and depth)on th...Laser-structuring is an effective method to promote ion diffusion and improve the performance of lithium-ion battery(LIB)electrodes.In this work,the effects of laser structuring parameters(groove pitch and depth)on the fundamental characteristics of LIB electrode,such as interfacial area,internal resistances,material loss and electrochemical performance,are investigated,LiNi_(0.5)Co_(0.2)Mn_(0.3)O_(2) cathodes were structured by a femtosecond laser by varying groove depth and pitch,which resulted in a material loss of 5%-14%and an increase of 140%-260%in the in terfacial area between electrode surface and electrolyte.It is shown that the importance of groove depth and pitch on the electrochemical performance(specific capacity and areal discharge capacity)of laser-structured electrode varies with current rates.Groove pitch is more im porta nt at low current rate but groove depth is at high curre nt rate.From the mapping of lithium concentration within the electrodes of varying groove depth and pitch by laser-induced breakdown spectroscopy,it is verified that the groove functions as a diffusion path for lithium ions.The ionic,electronic,and charge transfer resistances measured with symmetric and half cells showed that these internal resistances are differently affected by laser structuring parameters and the changes in porosity,ionic diffusion and electronic pathways.It is demonstrated that the laser structuring parameters for maximum electrode performance and minimum capacity loss should be determined in consideration of the main operating conditions of LIBs.展开更多
基金supported by the R&D Center for Valuable Recycling (Global-Top R&D Program)of the Ministry of Environment (No.2016002250003)。
文摘Scrap metals are typically covered with surface contaminants,such as paint,dust,and rust,which can significantly affect the emission spectrum during laser-induced breakdown spectroscopy(LIBS)based sorting.In this study,the effects of paint layers on metal surfaces during LIBS classification were investigated.LIBS spectra were collected from metal surfaces painted with black and white paints by ablation with a nanosecond pulsed laser(wavelength=1064 nm,pulse width=7 ns).For the black-painted samples,the LIBS spectra showed a broad background emission,emission lines unrelated to the target metals,large shot-to-shot variation,and a relatively low signal intensity of the target metal,causing poor classification accuracy even at high shot numbers.Cleaning the black paint layer by ablating over a wide area prior to LIBS analysis resulted in high classification accuracy with fewer shot numbers.A method to determine the number of cleaning shots necessary to obtain high classification accuracy and high throughput is proposed on the basis of the change in LIBS signal intensity during cleaning shots.For the white-painted samples,the paint peeled off the metal surface after the first shot,and strong LIBS signals were measured after the following shot,which were attributed to the nanoparticles generated by the ablation of the paint,allowing an accurate classification after only two shots.The results demonstrate that different approaches must be employed depending on the paint color to achieve high classification accuracy with fewer shot numbers.
基金supported by a GIST Research Institute(GRI)grant funded by the GIST in 2021supported by the Korea In stitute for Advancement of Tech no logy(KIAT)grant funded by the Korea Government(MOTIE).(P0008763,The Competency Development Program for Industry Specialist.)。
文摘Laser-structuring is an effective method to promote ion diffusion and improve the performance of lithium-ion battery(LIB)electrodes.In this work,the effects of laser structuring parameters(groove pitch and depth)on the fundamental characteristics of LIB electrode,such as interfacial area,internal resistances,material loss and electrochemical performance,are investigated,LiNi_(0.5)Co_(0.2)Mn_(0.3)O_(2) cathodes were structured by a femtosecond laser by varying groove depth and pitch,which resulted in a material loss of 5%-14%and an increase of 140%-260%in the in terfacial area between electrode surface and electrolyte.It is shown that the importance of groove depth and pitch on the electrochemical performance(specific capacity and areal discharge capacity)of laser-structured electrode varies with current rates.Groove pitch is more im porta nt at low current rate but groove depth is at high curre nt rate.From the mapping of lithium concentration within the electrodes of varying groove depth and pitch by laser-induced breakdown spectroscopy,it is verified that the groove functions as a diffusion path for lithium ions.The ionic,electronic,and charge transfer resistances measured with symmetric and half cells showed that these internal resistances are differently affected by laser structuring parameters and the changes in porosity,ionic diffusion and electronic pathways.It is demonstrated that the laser structuring parameters for maximum electrode performance and minimum capacity loss should be determined in consideration of the main operating conditions of LIBs.
