Au is considered as one of the most promising catalysts for nitrogen reduction reaction(NRR),however maximizing the activity utilization rate of Au and understanding the synergistic effects between Au and carriers pos...Au is considered as one of the most promising catalysts for nitrogen reduction reaction(NRR),however maximizing the activity utilization rate of Au and understanding the synergistic effects between Au and carriers pose ongoing challenges.Herein,we systematically explore the synergistic catalytic effect of incorporating Au with boron clusters for accelerating NRR kinetics.An in-situ abinitio strategy is employed to construct B-doped Au nanoparticles(2-6 nm in diameter)loaded on BO_(x) substrates(AuBO_(x)),in which B not only modulates the surface electronic structure of Au but also forms strong coupling interactions to stabilize the nanoparticles.The electrochemical results show that Au-BO_(x) possesses excellent NRR activity(NH_(3) yield of 48.52μg h^(-1)mg_(cat)^(-1),Faraday efficiency of 56.18%),and exhibits high stability and reproducibility throughout the electrocatalytic NRR process.Theoretical calculations reveal that the introduction of B induces the formation of both Au dangling bond and Au-B coupling bond.which considerably facilitates the hydrogenation of~*N_(2)^(-)~*NH_(3).The present work provides a new avenue for the preparation of metal-boron materials achieved by one-step reduction and doping process,utilizing boron clusters as reducing and stabilizing agents.展开更多
In response to the rapid increase in world population and subsequent demands for food,edible insects represent an alternative food source for humans that is rich in proteins,amino acids and minerals.Entomophagy is a t...In response to the rapid increase in world population and subsequent demands for food,edible insects represent an alternative food source for humans that is rich in proteins,amino acids and minerals.Entomophagy is a tradition in many countries including China and Thailand,and edible insects have attracted a lot of attention in Western World due to their suitable nutrient composition,high mineral content(e.g.,Fe,Zn,Ca,Mg)and potential use as a supplement in human diet.In this study,we surveyed mineral content in seven insect orders and 67 species of mass produced and wild-harvested edible insects.The total content of essential elements in edible insects was very high in Tenebrio molitor,Bombyx mori,and Zonocerus variegatus.The heavy metal content(summarized for eight species)was below the maximum limit allowed for safe consumption.Sustainable supply of minerals derived from insect biomass is complicated due to the high variations of mineral content in insects and the potential of its change due to processing.展开更多
As an important application scenario of 5G, the vehicular network has a huge amount of computing data, which brings challenges to the scarce network resources. Mobile edge computing(MEC) sinks cloud services to the ed...As an important application scenario of 5G, the vehicular network has a huge amount of computing data, which brings challenges to the scarce network resources. Mobile edge computing(MEC) sinks cloud services to the edge of network, which reduces the delay jitter caused by remote cloud computing. Software-defined networking(SDN) is an emerging network paradigm with the features of logic centralized control and programmability. In this paper, we construct an SDN-assisted MEC network architecture for the vehicular network. By introducing SDN controller, the efficiency and flexibility of vehicular network are improved, and the network state can be perceived from the global perspective. To further reduce the system overhead, the problem of vehicle to everything(V2X) offloading and resource allocation is proposed, where the optimal offloading decision, transmission power control, subchannels assignment, and computing resource allocation scheme are given. The optimization problem is transformed into three stages because of the heterogeneity of the offloaded tasks and the NP-hard property of the problem. Firstly, the analytic hierarchy process is used to select initial offloading node, then stateless Q-learning is adopted to allocate transmission power, subchannels and computing resources. In addition, the offloading decision is modeled as a potential game, and the Nash equilibrium is proved by the potential function construction. Finally, the numerical results show that the proposed mechanism can effectively reduce the system overhead and achieve better results compared with others’ algorithms.展开更多
The biggest challenge is to develop a low cost and readily available catalyst to replace expensive commercial Pt/C for efficient electrochemical oxygen reduction reaction(ORR).In this research,closo-[B_(12)H_(12)]^(2−...The biggest challenge is to develop a low cost and readily available catalyst to replace expensive commercial Pt/C for efficient electrochemical oxygen reduction reaction(ORR).In this research,closo-[B_(12)H_(12)]^(2−)and 1,10-phenanthroline-iron complexes were introduced into the porous metal-organic framework by impregnation method,and further annealing treatment achieved the successful anchoring of single-atom-Fe in B-doped CN Matrix(FeN4CB).The ORR activity of FeN4CB is comparable to the widely used commercial 20 wt%Pt/C.Where the half-wave potential(E_(1/2))in alkaline medium up to 0.84 V,and even in the face of challenging ORR in acidic medium,the E_(1/2)of ORR driven by FeN4CB is still as high as 0.81 V.When FeN4CB was used as air cathode,the open circuit voltage of Zn-air battery reaches 1.435 V,and the power density and specific capacity are as high as 177 mW cm^(−2)and 800 mAh g_(Zn)^(−1)(theoretical value:820 mAh g_(Zn)^(−1)),respectively.The dazzling point of FeN4CB also appears in the high ORR stability,whether in alkaline or acidic media,E_(1/2)and limiting current density are still close to the initial value after 5000 times cycles.After continuously running the charge-discharge test for 220 h,the charge voltage and discharge voltage of the rechargeable zinc-air battery with FeN4CB as the air cathode maintained the initial state.Density functional theory calculations reveals that introducing B atom to Fe–N4–C can adjust the electronic structure to easily break O=O bond and significantly reduce the energy barrier of the rate-determining step resulting in an improved ORR activity.展开更多
In this study,a real-time rotor temperature monitoring system for large turbogenerators using SmartMesh IP wireless network communication technology was designed and tested.The system is capable of providing comprehen...In this study,a real-time rotor temperature monitoring system for large turbogenerators using SmartMesh IP wireless network communication technology was designed and tested.The system is capable of providing comprehensive,accurate,continuous,and reliable real-time temperature monitoring for turbogenerators.Additionally,it has demonstrated satisfactory results in a real-time monitoring test of the rotor temperature of various famous large-scale turbogenerators and giant nuclear power half-speed turbogenerators designed and manufactured in China.The development and application of this wireless temperature measurement system would aid in improving the intelligent operation quality,safety,and stability of China’s large turbine generators and even the entire power system.展开更多
We investigate systematically the effects of the inter-particle attraction on the structure and dynamical behaviors of glass-forming liquids via molecular dynamics simulations.We find that the inter-particle attractio...We investigate systematically the effects of the inter-particle attraction on the structure and dynamical behaviors of glass-forming liquids via molecular dynamics simulations.We find that the inter-particle attraction does not influence the structure,but greatly affects the dynamics and dynamical heterogeneity of the system.After the system changes from a purely repulsive glass-forming liquid to an attractive one,the dynamics slows down and the dynamical heterogeneity becomes greater,which is found interestingly to be associated with larger cooperative rearrangement regions(CRRs).Additionally,the structures of CRRs are observed to be compact in attractive glass-forming liquids but string-like in purely repulsive ones.Our findings constitute an important contribution to the ongoing study of the role of attractions in properties of glasses and glass-forming liquids.展开更多
基金supported by the National Natural Science Foundation of China(22075133,62288102,22375091,21971114,and 21701086)the Jiangsu Provincial Funds(BX2022013)。
文摘Au is considered as one of the most promising catalysts for nitrogen reduction reaction(NRR),however maximizing the activity utilization rate of Au and understanding the synergistic effects between Au and carriers pose ongoing challenges.Herein,we systematically explore the synergistic catalytic effect of incorporating Au with boron clusters for accelerating NRR kinetics.An in-situ abinitio strategy is employed to construct B-doped Au nanoparticles(2-6 nm in diameter)loaded on BO_(x) substrates(AuBO_(x)),in which B not only modulates the surface electronic structure of Au but also forms strong coupling interactions to stabilize the nanoparticles.The electrochemical results show that Au-BO_(x) possesses excellent NRR activity(NH_(3) yield of 48.52μg h^(-1)mg_(cat)^(-1),Faraday efficiency of 56.18%),and exhibits high stability and reproducibility throughout the electrocatalytic NRR process.Theoretical calculations reveal that the introduction of B induces the formation of both Au dangling bond and Au-B coupling bond.which considerably facilitates the hydrogenation of~*N_(2)^(-)~*NH_(3).The present work provides a new avenue for the preparation of metal-boron materials achieved by one-step reduction and doping process,utilizing boron clusters as reducing and stabilizing agents.
基金founded by Jiangsu Agricultural Science and Technology Innovation Fund(CX(20)3179)Dongminghuanghetan Ecological Agriculture Co.,Ltd(204032897)+1 种基金partially funded funding from the European Union’s Horizon 2020 research and innovation programme under grant agreement no.861976,project SUSINCHAINthe German Federal Ministry of Education and Research(BMBF),in the frame of FACCE-SURPLUS/FACCE-JPI project UpWaste,grant number 031B0934A。
文摘In response to the rapid increase in world population and subsequent demands for food,edible insects represent an alternative food source for humans that is rich in proteins,amino acids and minerals.Entomophagy is a tradition in many countries including China and Thailand,and edible insects have attracted a lot of attention in Western World due to their suitable nutrient composition,high mineral content(e.g.,Fe,Zn,Ca,Mg)and potential use as a supplement in human diet.In this study,we surveyed mineral content in seven insect orders and 67 species of mass produced and wild-harvested edible insects.The total content of essential elements in edible insects was very high in Tenebrio molitor,Bombyx mori,and Zonocerus variegatus.The heavy metal content(summarized for eight species)was below the maximum limit allowed for safe consumption.Sustainable supply of minerals derived from insect biomass is complicated due to the high variations of mineral content in insects and the potential of its change due to processing.
基金the National Nature Science Foundation of China (61801065, 61601071)Program for Changjiang Scholars and Innovative Research Team in University of Ministry of Education of China (IRT16R72)General project on foundation and cutting-edge research plan of Chongqing (No. cstc2018jcyjAX0463)
文摘As an important application scenario of 5G, the vehicular network has a huge amount of computing data, which brings challenges to the scarce network resources. Mobile edge computing(MEC) sinks cloud services to the edge of network, which reduces the delay jitter caused by remote cloud computing. Software-defined networking(SDN) is an emerging network paradigm with the features of logic centralized control and programmability. In this paper, we construct an SDN-assisted MEC network architecture for the vehicular network. By introducing SDN controller, the efficiency and flexibility of vehicular network are improved, and the network state can be perceived from the global perspective. To further reduce the system overhead, the problem of vehicle to everything(V2X) offloading and resource allocation is proposed, where the optimal offloading decision, transmission power control, subchannels assignment, and computing resource allocation scheme are given. The optimization problem is transformed into three stages because of the heterogeneity of the offloaded tasks and the NP-hard property of the problem. Firstly, the analytic hierarchy process is used to select initial offloading node, then stateless Q-learning is adopted to allocate transmission power, subchannels and computing resources. In addition, the offloading decision is modeled as a potential game, and the Nash equilibrium is proved by the potential function construction. Finally, the numerical results show that the proposed mechanism can effectively reduce the system overhead and achieve better results compared with others’ algorithms.
基金financially supported by the NSFC-Yunnan Joint Foundation(U2002213)the Double Tops Joint Fund of the Yunnan Science and Technology Bureau and Yunnan University(2019FY003025)the‘Double-First Class’University Construction Project(C176220100042 and CZ21623201)。
文摘The biggest challenge is to develop a low cost and readily available catalyst to replace expensive commercial Pt/C for efficient electrochemical oxygen reduction reaction(ORR).In this research,closo-[B_(12)H_(12)]^(2−)and 1,10-phenanthroline-iron complexes were introduced into the porous metal-organic framework by impregnation method,and further annealing treatment achieved the successful anchoring of single-atom-Fe in B-doped CN Matrix(FeN4CB).The ORR activity of FeN4CB is comparable to the widely used commercial 20 wt%Pt/C.Where the half-wave potential(E_(1/2))in alkaline medium up to 0.84 V,and even in the face of challenging ORR in acidic medium,the E_(1/2)of ORR driven by FeN4CB is still as high as 0.81 V.When FeN4CB was used as air cathode,the open circuit voltage of Zn-air battery reaches 1.435 V,and the power density and specific capacity are as high as 177 mW cm^(−2)and 800 mAh g_(Zn)^(−1)(theoretical value:820 mAh g_(Zn)^(−1)),respectively.The dazzling point of FeN4CB also appears in the high ORR stability,whether in alkaline or acidic media,E_(1/2)and limiting current density are still close to the initial value after 5000 times cycles.After continuously running the charge-discharge test for 220 h,the charge voltage and discharge voltage of the rechargeable zinc-air battery with FeN4CB as the air cathode maintained the initial state.Density functional theory calculations reveals that introducing B atom to Fe–N4–C can adjust the electronic structure to easily break O=O bond and significantly reduce the energy barrier of the rate-determining step resulting in an improved ORR activity.
基金supported by the National Natura Science Foundation of China (NSFC), No.51607146China National Major Science and Technology Projects 2010ZX06004-013-04-02 and 2012ZX06002-017-02-01+1 种基金Sichuan Science and Technology Program,No.2018GZ0391Sichuan Hydropower Energy and power equipment technology Engineering Research Center, Xihua university, Chengdu 610039, China,No.SDNY2020-001
文摘In this study,a real-time rotor temperature monitoring system for large turbogenerators using SmartMesh IP wireless network communication technology was designed and tested.The system is capable of providing comprehensive,accurate,continuous,and reliable real-time temperature monitoring for turbogenerators.Additionally,it has demonstrated satisfactory results in a real-time monitoring test of the rotor temperature of various famous large-scale turbogenerators and giant nuclear power half-speed turbogenerators designed and manufactured in China.The development and application of this wireless temperature measurement system would aid in improving the intelligent operation quality,safety,and stability of China’s large turbine generators and even the entire power system.
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 11704270,12074275,and 11574222)Jiangsu Planned Projects for Postdoctoral Research Funds+1 种基金the PAPD Program of Jiangsu Higher Education Institutionsthe Start-up Fund from Anhui University (Grant No. S020318001/02)
文摘We investigate systematically the effects of the inter-particle attraction on the structure and dynamical behaviors of glass-forming liquids via molecular dynamics simulations.We find that the inter-particle attraction does not influence the structure,but greatly affects the dynamics and dynamical heterogeneity of the system.After the system changes from a purely repulsive glass-forming liquid to an attractive one,the dynamics slows down and the dynamical heterogeneity becomes greater,which is found interestingly to be associated with larger cooperative rearrangement regions(CRRs).Additionally,the structures of CRRs are observed to be compact in attractive glass-forming liquids but string-like in purely repulsive ones.Our findings constitute an important contribution to the ongoing study of the role of attractions in properties of glasses and glass-forming liquids.
