Serving as a promising alternative to liquid electrolyte in the application of portable and wearable devices,gel polymer electrolytes(GPEs)are expected to obtain more preferable properties rather than just be satisfie...Serving as a promising alternative to liquid electrolyte in the application of portable and wearable devices,gel polymer electrolytes(GPEs)are expected to obtain more preferable properties rather than just be satisfied with the merits of high safety and deformability.Here,an easy-operated method is employed to fabricate cross-linked composite polymer membranes used for GPEs assisted by UV irradiation,in which N-doped carbon quantum dots(N-CQDs)and TiO2are introduced as photocatalysts and additives to improve the performances of GPEs.Specifically,N-CQDs participate as a cross-linker to construct the inner porous structure,and TiO2nanoparticles serve as a stabilizer to improve the electrochemical stability of GPEs under high voltage(3.5 V).The excellent thermal and mechanical stability of the membrane fabricated in this work guarantee the safety of the supercapacitors(SCs).This GPE based SC not only exhibits prominent rate performance(105%capacitance retention at the current density of 40A g^(-1))and cyclic stability(85%at 1 A g^(-1)under 3.5 V after 20,000 cycles),but also displays remarkable energy density(42.88 Wh kg^(-1))with high power density(19.3 k W kg^(-1)).Moreover,the superior rate and cycling performances of the as-prepared GPE based flexible SCs under flat and bending state confirm the feasibility of its application in flexible energy storage devices.展开更多
Lithium(Li)metal batteries(LMBs)are widely regarded as the ultimate choice for the next generation of high-energy–density batteries.However,the uncontrollable growth of Li dendrites formed by inhomogeneous deposition...Lithium(Li)metal batteries(LMBs)are widely regarded as the ultimate choice for the next generation of high-energy–density batteries.However,the uncontrollable growth of Li dendrites formed by inhomogeneous deposition seriously hinders its commercialization.Although many studies have achieved significant results in inhibiting the formation of Li dendrites,it is still impossible to eradicate them completely.Therefore,regulating the deposition behavior,such as the growth direction of unevenly deposited Li,is preferable to unilaterally suppressing them in some cases.Here we report a structured anode that can confine the deposited Li within holes and tune it to become vertical-up/horizontal-centripetal mixed growth mode by optimizing the electric field/Li^(+)concentration gradient.The Li^(+) adsorbed by the poly(amic acid)(PAA)insulating layer coated on the anode surface can form the Li^(+)concentration gradient pointing to the center of the hole.Combined with the special electric field formed by the hole structure,it is favorable for the Li^(+)to move into the vertically arrayed holes and simultaneously deposit on the bottom and walls.Furthermore,both in-situ and ex-situ observations confirm that the growth mode is changed and the Li deposition morphology is denser,which can greatly delay capacity fading and prolong cycle life in both liquid and quasi-solid-state LMBs.All the results show that the novel anode provides a new perspective for deep research into solid-state LMBs.展开更多
In this paper,a trusted multi-task distribution mechanism for Internet of Vehicles based on smart contract is proposed to improve the security and efficiency for the task distribution in Internet of Vehicles.Firstly,a...In this paper,a trusted multi-task distribution mechanism for Internet of Vehicles based on smart contract is proposed to improve the security and efficiency for the task distribution in Internet of Vehicles.Firstly,a three-tier trusted multi-task distribution framework is presented based on smart contract.The smart contract will be triggered by the task request.As the important part of the smart contract,the task distribution algorithm is stored on the blockchain and run automatically.In the process of the task distribution,the cost of the task distribution and the system stability play a critical role.Therefore,the task distribution problem is formulated to minimize the cost of the task distribution whilst maintaining the stability of the system based on Lyapunov theorem.Unfortunately,this problem is a mixed integer nonlinear programming problem with NP-hard characteristics.To tackle this,the optimization problem is decomposed into two sub problems of computing resource allocation and task distribution decision,and an effective task distribution algorithm is proposed.Simulation results show that the proposed algorithm can effectively improves system performance.展开更多
基金funding supports from the Natural Science Basis Research Plan in Shaanxi Province of China(2019JLZ-10)the Independent Research Project of National Key Laboratory of Electrical Insulation and Power Equipment(EIPE19111)。
文摘Serving as a promising alternative to liquid electrolyte in the application of portable and wearable devices,gel polymer electrolytes(GPEs)are expected to obtain more preferable properties rather than just be satisfied with the merits of high safety and deformability.Here,an easy-operated method is employed to fabricate cross-linked composite polymer membranes used for GPEs assisted by UV irradiation,in which N-doped carbon quantum dots(N-CQDs)and TiO2are introduced as photocatalysts and additives to improve the performances of GPEs.Specifically,N-CQDs participate as a cross-linker to construct the inner porous structure,and TiO2nanoparticles serve as a stabilizer to improve the electrochemical stability of GPEs under high voltage(3.5 V).The excellent thermal and mechanical stability of the membrane fabricated in this work guarantee the safety of the supercapacitors(SCs).This GPE based SC not only exhibits prominent rate performance(105%capacitance retention at the current density of 40A g^(-1))and cyclic stability(85%at 1 A g^(-1)under 3.5 V after 20,000 cycles),but also displays remarkable energy density(42.88 Wh kg^(-1))with high power density(19.3 k W kg^(-1)).Moreover,the superior rate and cycling performances of the as-prepared GPE based flexible SCs under flat and bending state confirm the feasibility of its application in flexible energy storage devices.
基金supported by the National Key R&D Program of China(Grant No.2020YFA0710500)the basic scientific research business expenses Program of Xi’an Jiaotong University(Grant No.xzy022022053)the Independent Research Project of the State Key Laboratory of Electrical Insulation and Power Equipment(Grant No.EIPE23303)for financial support。
文摘Lithium(Li)metal batteries(LMBs)are widely regarded as the ultimate choice for the next generation of high-energy–density batteries.However,the uncontrollable growth of Li dendrites formed by inhomogeneous deposition seriously hinders its commercialization.Although many studies have achieved significant results in inhibiting the formation of Li dendrites,it is still impossible to eradicate them completely.Therefore,regulating the deposition behavior,such as the growth direction of unevenly deposited Li,is preferable to unilaterally suppressing them in some cases.Here we report a structured anode that can confine the deposited Li within holes and tune it to become vertical-up/horizontal-centripetal mixed growth mode by optimizing the electric field/Li^(+)concentration gradient.The Li^(+) adsorbed by the poly(amic acid)(PAA)insulating layer coated on the anode surface can form the Li^(+)concentration gradient pointing to the center of the hole.Combined with the special electric field formed by the hole structure,it is favorable for the Li^(+)to move into the vertically arrayed holes and simultaneously deposit on the bottom and walls.Furthermore,both in-situ and ex-situ observations confirm that the growth mode is changed and the Li deposition morphology is denser,which can greatly delay capacity fading and prolong cycle life in both liquid and quasi-solid-state LMBs.All the results show that the novel anode provides a new perspective for deep research into solid-state LMBs.
基金supported in part by Open Foundation of State key Laboratory of Networking and Switching Technology(Beijing University of Posts and Telecommunications)(SKLNST-2022-1-15)in part by the Future Network Scientific Research Fund Project under Grant FNSRFP-2021-YB-7+5 种基金in part by the Provincial Water Science and Technology Program of Jiangsu under Grant 2020028in part by Social and People's Livelihood Technology in Nantong City under Grant MS22021042in part by the Fundamental Research Funds for the Central Universities under Grant B200205007in part by the Provincial Key Research and Development Program of Jiangsu under Grant BE2019017in part by the Open Research Fund Key Laboratory of Wireless Sensor Network and Communication,Chinese Academy of Sciences,under Grant 20190914in part by the Project of National Natural Science Foundation of China 62271190。
文摘In this paper,a trusted multi-task distribution mechanism for Internet of Vehicles based on smart contract is proposed to improve the security and efficiency for the task distribution in Internet of Vehicles.Firstly,a three-tier trusted multi-task distribution framework is presented based on smart contract.The smart contract will be triggered by the task request.As the important part of the smart contract,the task distribution algorithm is stored on the blockchain and run automatically.In the process of the task distribution,the cost of the task distribution and the system stability play a critical role.Therefore,the task distribution problem is formulated to minimize the cost of the task distribution whilst maintaining the stability of the system based on Lyapunov theorem.Unfortunately,this problem is a mixed integer nonlinear programming problem with NP-hard characteristics.To tackle this,the optimization problem is decomposed into two sub problems of computing resource allocation and task distribution decision,and an effective task distribution algorithm is proposed.Simulation results show that the proposed algorithm can effectively improves system performance.
