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氢气辅助镁还原-烧结制备Zr-2.5Nb合金 被引量:1
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作者 董朝望 赵金龙 +2 位作者 夏阳 郭学益 刘汉宁 《中国有色金属学报》 EI CAS CSCD 北大核心 2022年第11期3306-3314,共9页
传统的克劳尔方法制备锆铌合金存在工艺流程长、易被杂质元素污染等问题。本文提出一种利用氢气辅助镁还原-压制烧结直接制备锆铌合金的新工艺。以Zr-2.5Nb为目标合金,在氢气气氛下利用镁粉还原金属氧化物Zr O2和Nb2O5的混合物,成功制... 传统的克劳尔方法制备锆铌合金存在工艺流程长、易被杂质元素污染等问题。本文提出一种利用氢气辅助镁还原-压制烧结直接制备锆铌合金的新工艺。以Zr-2.5Nb为目标合金,在氢气气氛下利用镁粉还原金属氧化物Zr O2和Nb2O5的混合物,成功制备出氧质量分数低至0.038%的Zr-2.5Nb氢化合金粉末,之后对制备出的合金粉末进行冷等静压-烧结,制备Zr-2.5Nb合金。对制备出的合金粉末的元素含量、形貌及粒度进行了分析,探究了烧结温度对合金性能的影响。结果表明:合金粉末中Nb质量分数为2.29%,平均粒度为61.88μm。当烧结温度为1400℃时,合金产品致密度和硬度分别达到最大,分别为95.36%和250.3 HV,合金的压缩强度在1300℃时达到最高值1059 MPa。制备出的合金硬度和压缩性能均满足美国工业核级锆合金标准。 展开更多
关键词 还原 Zr-Nb合金 粉末 烧结
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Towards a circular metal additive manufacturing through recycling of materials: A mini review 被引量:8
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作者 XIA Yang dong zhao-wang +2 位作者 GUO Xue-yi TIAN Qing-hua LIU Yong 《Journal of Central South University》 SCIE EI CAS CSCD 2020年第4期1134-1145,共12页
Additive manufacturing is a new emerging technology which is ideal for low-to-zero waste production, and it is considered to be a green and clean process that has the potential to lower the cost and energy consumption... Additive manufacturing is a new emerging technology which is ideal for low-to-zero waste production, and it is considered to be a green and clean process that has the potential to lower the cost and energy consumption of production. However, the cost of the feedstock for additive manufacturing and the additive manufactured parts is usually very high, which hinders the further application of additive manufacturing, especially for the metal additive manufacturing. The concept of circular metal additive manufacturing involves the recycling of the metal feedstock and the additive manufactured parts leading to the truly zero waste production and the most energy saving. This paper reviews the technologies that help the formation of a circular metal additive manufacturing through recycling of the feedstocks and the damaged metal parts. Reactive metals, such as titanium, tend to be contaminated easily during handling and production. Recycling of the titanium for achieving a circular titanium additive manufacturing is reviewed in detail. 展开更多
关键词 RECYCLING additive manufacturing TITANIUM POWDER
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Preparing low-oxygen Ti-6Al-4V alloy powder through direct reduction of oxides and its synergistic reaction mechanism 被引量:3
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作者 dong zhao-wang XIA Yang +2 位作者 GUO Xue-yi LIU Han-ning LIU Pei-dong 《Journal of Central South University》 SCIE EI CAS CSCD 2022年第6期1811-1822,共12页
Ti-6Al-4V alloy powder was prepared through a two-step reduction of a mixture of TiO_(2),V_(2)O_(5) and Al_(2)O_(3) in this study.The oxide mixture was first reduced by Mg in MgCl_(2) at 750℃ in argon,where oxygen wa... Ti-6Al-4V alloy powder was prepared through a two-step reduction of a mixture of TiO_(2),V_(2)O_(5) and Al_(2)O_(3) in this study.The oxide mixture was first reduced by Mg in MgCl_(2) at 750℃ in argon,where oxygen was reduced to 2.47 wt%from 40.02 wt%.The oxygen content in the final powder was eventually reduced to an extremely low level(0.055 wt%)using calcium at 900℃ in argon,and the final powder had the composition of 90.12 wt%Ti,5.57 wt%Al,and 3.87 wt%V,which meets the standard specification of Ti-6Al-4V(ASTM F1108-09).Between the two reductions,a heat treatment step was designed to help controlling the specific surface area and particle size.The effect of the heat treatment temperature on the morphology,and composition uniformity of the powder was investigated in detail.Heat treatment above 1300℃ attributed to a dense powder with a controlled specific surface area.Thermodynamic modeling and experimental results indicated that onlyα-Ti enriched with Al andβ-Ti enriched with V exist in the final powder,and other possible phases including Al-Mg and Al-V were excluded.This study also offers a triple-step thermochemical process for producing high-purity Ti-based alloy powder. 展开更多
关键词 titanium powder titanium alloy oxide direct reduction synergistic reaction mechanism two-step reduction
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氢气辅助镁还原制备低氧氢化锆粉 被引量:3
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作者 董朝望 段良洪 +2 位作者 刘汉宁 郭学益 夏阳 《Journal of Central South University》 SCIE EI CAS CSCD 2023年第5期1512-1522,共11页
锆金属在核工业及能源领域发挥着重要的作用,但锆氧之间具有很强的亲和力,使锆金属难以经济有效地生产,粉末冶金方法制备锆金属可以实现锆金属的近净成形制备,锆粉可通过氢化锆粉脱氧制备而成。本文提出了一种在氢气辅助下镁还原制备高... 锆金属在核工业及能源领域发挥着重要的作用,但锆氧之间具有很强的亲和力,使锆金属难以经济有效地生产,粉末冶金方法制备锆金属可以实现锆金属的近净成形制备,锆粉可通过氢化锆粉脱氧制备而成。本文提出了一种在氢气辅助下镁还原制备高纯ZrH_(2)粉末的新工艺,并分析了氢元素的强化脱氧作用。在750℃、240 min条件下Ar和H_(2)气氛中镁还原制备的ZrH_(2)粉末氧含量分别为3.05 wt%和1.03 wt%。对氢还原后的粉末进行脱氧,获得平均粒度为89.01μm、氧含量为0.0047 wt%的氢化锆粉末。透射电镜测试结果表明,与氩气气氛还原粉末相比,氢气条件下的粉末表面钝化层厚度从8.51nm减小到2.76 nm。热力学计算表明,H元素可以使Zr金属发生相变,降低Zr-O固溶体的稳定性,提高镁的脱氧能力。 展开更多
关键词 镁还原 粉末
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