Extensive usage of highly conductive carbon materials with large specific surface area(e.g.,carbon nanotubes,CNTs)in lithium ion batteries(LIBs),especially as current collector of anodes,suffers from low initial coulo...Extensive usage of highly conductive carbon materials with large specific surface area(e.g.,carbon nanotubes,CNTs)in lithium ion batteries(LIBs),especially as current collector of anodes,suffers from low initial coulombic efficiency(ICE),large interfacial resistance,and severe embrittlement,as the large specific surface area often results in severe interfacial decomposition of the electrolyte and the formation of thick and fluffy solid electrolyte interphase(SEI)during cycling of LIBs.Herein,we demonstrate that when the CNT-based current collector and Na foil(which are being stacked intimately upon each other)are being placed in Na+-based organic electrolyte,local redox reaction between the Na foil and the electrolyte would occur spontaneously,generating a thin and homogeneous NaF-based passivating layer on the CNTs.More importantly,we found that owing to the weak solvation behaviors of Na+in the organic electrolyte,the resulting passivation layer,which is rich in NaF,is thin and dense;when used as the anode current collector in LIBs,the pre-existing passivating layer can function effectively in isolating the anode from the solvated Li+,thus suppressing the formation of bulky SEI and the destructive intercalation of solvated Li+.The relevant half-cell(graphite as anode)exhibits a high ICE of 92.1%;the relevant pouch cell with thus passivated CNT film as current collectors for both electrodes(LiCoO_(2)as cathode,graphite as anode)displays a high energy density of 255 Wh kg^(-1),spelling an increase of 50%compared with that using the conventional metal current collectors.展开更多
Feedforward symbol timing recovery techniques are particularly important for initial acquisition in burst modems. However, these techniques either have large calculation burden or sensitive to frequency offsets. In th...Feedforward symbol timing recovery techniques are particularly important for initial acquisition in burst modems. However, these techniques either have large calculation burden or sensitive to frequency offsets. In this paper, we proposed an efficient symbol timing recovery algorithm of MPSK signals named OMQ(Ordered Maximum power using Quadratic approximation partially) algorithm which is based on the Quadratic Approximation(QA) algorithm. We used ordered statistic sorting method to reduce the computational complexity further, meanwhile maximum mean power principle was used to decrease frequency offset sensitivity. The proposed algorithm adopts estimation-down sampling structure which is suitable for small packet size transmission. The results show that, while comparing with the QA algorithm, the computational complexity is reduced by 75% at most when 8 samples per symbol are used. The proposed algorithm shows better performance in terms of the jitter variance and sensitivity to frequency offsets.展开更多
基金financially supported by the National Key Research and Development Program of China(2022YFB4002103)the National Natural Science Foundation of China(22279107)。
文摘Extensive usage of highly conductive carbon materials with large specific surface area(e.g.,carbon nanotubes,CNTs)in lithium ion batteries(LIBs),especially as current collector of anodes,suffers from low initial coulombic efficiency(ICE),large interfacial resistance,and severe embrittlement,as the large specific surface area often results in severe interfacial decomposition of the electrolyte and the formation of thick and fluffy solid electrolyte interphase(SEI)during cycling of LIBs.Herein,we demonstrate that when the CNT-based current collector and Na foil(which are being stacked intimately upon each other)are being placed in Na+-based organic electrolyte,local redox reaction between the Na foil and the electrolyte would occur spontaneously,generating a thin and homogeneous NaF-based passivating layer on the CNTs.More importantly,we found that owing to the weak solvation behaviors of Na+in the organic electrolyte,the resulting passivation layer,which is rich in NaF,is thin and dense;when used as the anode current collector in LIBs,the pre-existing passivating layer can function effectively in isolating the anode from the solvated Li+,thus suppressing the formation of bulky SEI and the destructive intercalation of solvated Li+.The relevant half-cell(graphite as anode)exhibits a high ICE of 92.1%;the relevant pouch cell with thus passivated CNT film as current collectors for both electrodes(LiCoO_(2)as cathode,graphite as anode)displays a high energy density of 255 Wh kg^(-1),spelling an increase of 50%compared with that using the conventional metal current collectors.
基金supported by the National Natural Science Foundation of China(NSFC.NO.61303253)
文摘Feedforward symbol timing recovery techniques are particularly important for initial acquisition in burst modems. However, these techniques either have large calculation burden or sensitive to frequency offsets. In this paper, we proposed an efficient symbol timing recovery algorithm of MPSK signals named OMQ(Ordered Maximum power using Quadratic approximation partially) algorithm which is based on the Quadratic Approximation(QA) algorithm. We used ordered statistic sorting method to reduce the computational complexity further, meanwhile maximum mean power principle was used to decrease frequency offset sensitivity. The proposed algorithm adopts estimation-down sampling structure which is suitable for small packet size transmission. The results show that, while comparing with the QA algorithm, the computational complexity is reduced by 75% at most when 8 samples per symbol are used. The proposed algorithm shows better performance in terms of the jitter variance and sensitivity to frequency offsets.
