The poor cycling stability of graphite in traditional ester electrolyte limits its applications as anodes for potassium ion batteries(KIBs).Herein,we demonstrate that the introduction of cyclic ether co-solvents into ...The poor cycling stability of graphite in traditional ester electrolyte limits its applications as anodes for potassium ion batteries(KIBs).Herein,we demonstrate that the introduction of cyclic ether co-solvents into ester electrolytes can remarkably enhance the cycling stability of graphite anodes.The graphite anode in ester electrolyte with cyclic ether could achieve a reversible capacity of 196.1 m Ah g^(-1) after 100 cycles at 0.3 C(1 C=280 m A g^(-1)),about three times higher than those in ester electrolytes with or without linear ether.Compared with the SEI formed in ester electrolytes,the addition of tetrahydrofuran promotes the generation of K_(2)CO_(3) and ethylene oxide oligomers(PEO),of which the K_(2)CO_(3) is expected to be more conductive and PEO is mechanically robust.The more uniform,conductive and stable solid electrolyte interphases(SEIs)on graphite in electrolytes with cyclic ethers contribute to the enhancement of the electrochemical performances of graphite.This work provides a novel design of commercialized electrolytes to achieve high-performance anodes for KIBs,which potentially accelerates the development of KIBs.展开更多
基金financially supported by the National Natural Science Foundation of China(U21A2081,22075074,22179014)the Outstanding Young Scientists Research Funds from Hunan Province(2020JJ2004)+2 种基金the Major Science and Technology Program of Hunan Province(2020WK2013)the Natural Science Foundation of Hunan Province(2021JJ40047)the State Key Laboratory of Materials Processing and Die&Mould Technology,Huazhong University of Science and Technology(P2022-020)。
文摘The poor cycling stability of graphite in traditional ester electrolyte limits its applications as anodes for potassium ion batteries(KIBs).Herein,we demonstrate that the introduction of cyclic ether co-solvents into ester electrolytes can remarkably enhance the cycling stability of graphite anodes.The graphite anode in ester electrolyte with cyclic ether could achieve a reversible capacity of 196.1 m Ah g^(-1) after 100 cycles at 0.3 C(1 C=280 m A g^(-1)),about three times higher than those in ester electrolytes with or without linear ether.Compared with the SEI formed in ester electrolytes,the addition of tetrahydrofuran promotes the generation of K_(2)CO_(3) and ethylene oxide oligomers(PEO),of which the K_(2)CO_(3) is expected to be more conductive and PEO is mechanically robust.The more uniform,conductive and stable solid electrolyte interphases(SEIs)on graphite in electrolytes with cyclic ethers contribute to the enhancement of the electrochemical performances of graphite.This work provides a novel design of commercialized electrolytes to achieve high-performance anodes for KIBs,which potentially accelerates the development of KIBs.
