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Fe_(2)O_(3)对ZrTiO_(4)载体NH_(3)-SCR催化性能的影响
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作者 袁龙腾 胡平 +4 位作者 胡卜亮 韩嘉彧 马升捷 杨帆 alex a.volinsky 《燃料化学学报(中英文)》 EI CAS CSCD 北大核心 2023年第12期1843-1855,共13页
NH_(3)-SCR催化剂主要用于工业生产和汽车尾气清洁,本研究采用“共沉淀-浸渍法”制备了新型α%Fe_(2)O_(3)/ZrTiO_(4)(α=0、8、12、15)催化剂。结果表明,α%Fe_(2)O_(3)/ZrTiO_(4)催化剂的最佳成分配比的12%Fe_(2)O_(3)/ZrTiO_(4)催化... NH_(3)-SCR催化剂主要用于工业生产和汽车尾气清洁,本研究采用“共沉淀-浸渍法”制备了新型α%Fe_(2)O_(3)/ZrTiO_(4)(α=0、8、12、15)催化剂。结果表明,α%Fe_(2)O_(3)/ZrTiO_(4)催化剂的最佳成分配比的12%Fe_(2)O_(3)/ZrTiO_(4)催化剂在250−400℃条件下NO_(x)转化率大于80%,在300℃时NO_(x)转化率接近100%,并且N2选择性在200−450℃大于90%。在ZrTiO_(4)表面负载Fe_(2)O_(3)后,催化剂的氧化还原性能、表面酸度和Oβ/(Oα+Oβ)比例都有所提高,这不仅归因于α%Fe_(2)O_(3)/ZrTiO_(4)催化剂具有多孔结构,还归因于活性组分Fe_(2)O_(3)和载体ZrTiO_(4)之间的电子相互作用。此外,原位DRIFTs反应表明,12%Fe_(2)O_(3)/ZrTiO_(4)催化剂的NH_(3)-SCR反应遵循Eley-Rideal机制。明确的反应机制有利于更深入了解SCR过程中NO_(x)转化的反应过程。这项工作为未来Fe基SCR催化剂在中温范围内替代V基催化剂提供了可行的策略。 展开更多
关键词 Fe_(2)O_(3)/ZrTiO_(4)催化剂 NH_(3)-SCR 多孔 反应机制
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Effects of laser pulse energy on surface microstructure and mechanical properties of high carbon steel 被引量:2
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作者 熊毅 贺甜甜 +3 位作者 李鹏燕 陈路飞 任凤章 alex a.volinsky 《Journal of Central South University》 SCIE EI CAS CSCD 2015年第12期4515-4520,共6页
Surface microstructure and mechanical properties of pearlitic Fe–0.8%C(mass fraction) steel after laser shock processing(LSP) with different laser pulse energies were investigated by scanning electron microscopy(SEM)... Surface microstructure and mechanical properties of pearlitic Fe–0.8%C(mass fraction) steel after laser shock processing(LSP) with different laser pulse energies were investigated by scanning electron microscopy(SEM),transmission electron microscopy(TEM),X-ray diffraction(XRD) and microhardness measurements.After LSP,the cementite lamellae were bent,kinked and broken into particles.Fragmentation and dissolution of the cementite lamellae were enhanced by increasing the laser pulse energy.Due to the dissolution of carbon atoms in the ferritic matrix,the lattice parameter of α-Fe increased.The grain size of the surface ferrite was refined,and the microstructure changed from lamellae to ultrafine micro-duplex structure(ferrite(α)+cementite(θ)) with higher laser pulse energy,accompanied by the residual stress and microhardness increase. 展开更多
关键词 pearlitic steel laser shock processing MICROSTRUCTURE MICROHARDNESS residual stress
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