N-dodecanethiol capped zinc sulfide（Zn S） nanocrystals were synthesized by the one-pot approach and blended with poly（N-vinylcarbazole）（PVK） to fabricate electrical bistable devices. The corresponding devices di...N-dodecanethiol capped zinc sulfide（Zn S） nanocrystals were synthesized by the one-pot approach and blended with poly（N-vinylcarbazole）（PVK） to fabricate electrical bistable devices. The corresponding devices did exhibit electrical bistability and negative differential resistance（NDR） effects. A large ON/OFF current ratio of 104 at negative voltages was obtained by applying different amplitudes of sweeping voltage. The observed conductance switching and the negative differential resistance are attributed to the electric-field-induced charge transfer between the nanocrystals and the polymer,and the charge trapping/detrapping in the nanocrystals.展开更多
The improvement of the acetone-soaking treatment to the performance of polymer solar cells based on the P3HT/PCBM bulk heterojunction is reported. Undergoing acetone-soaking, the PCBM does not distribute uniformly in ...The improvement of the acetone-soaking treatment to the performance of polymer solar cells based on the P3HT/PCBM bulk heterojunction is reported. Undergoing acetone-soaking, the PCBM does not distribute uniformly in the vertical direction, a PCBM enrichment layer forms on the top of the active layer, which is beneficial to the collec- tion of the carriers and blocking the inverting diffusion carriers. X-ray photoelectron spectroscopy （XPS） analysis reveals that the PCBM weight ratio on the top of the active layer increases by 20% after the acetone-soaking treatment. Due to the nonuniform distribution of PCBM, the short-circuit current density, the open-circuit voltage, and the fill factor are enhanced significantly. Finally, the power conversion efficiency of the acetone-soaking device increases by 31% compared with the control device.展开更多
基金supported by the National Natural Science Foundation of China(Grant No.61377028)the Natural Science Funds for Distinguished Young Scholar,China(Grant No.61125505)the Fundamental Research Funds for the Central Universities,China(Grant No.2014JBZ009)
文摘N-dodecanethiol capped zinc sulfide（Zn S） nanocrystals were synthesized by the one-pot approach and blended with poly（N-vinylcarbazole）（PVK） to fabricate electrical bistable devices. The corresponding devices did exhibit electrical bistability and negative differential resistance（NDR） effects. A large ON/OFF current ratio of 104 at negative voltages was obtained by applying different amplitudes of sweeping voltage. The observed conductance switching and the negative differential resistance are attributed to the electric-field-induced charge transfer between the nanocrystals and the polymer,and the charge trapping/detrapping in the nanocrystals.
基金supported by the National Natural Science Foundation of China(Grant Nos.61275175,61177017,and 61377028)the National Natural Science Foundation of China for Distinguished Yong Scholars(Grant No.61125505)
文摘The improvement of the acetone-soaking treatment to the performance of polymer solar cells based on the P3HT/PCBM bulk heterojunction is reported. Undergoing acetone-soaking, the PCBM does not distribute uniformly in the vertical direction, a PCBM enrichment layer forms on the top of the active layer, which is beneficial to the collec- tion of the carriers and blocking the inverting diffusion carriers. X-ray photoelectron spectroscopy （XPS） analysis reveals that the PCBM weight ratio on the top of the active layer increases by 20% after the acetone-soaking treatment. Due to the nonuniform distribution of PCBM, the short-circuit current density, the open-circuit voltage, and the fill factor are enhanced significantly. Finally, the power conversion efficiency of the acetone-soaking device increases by 31% compared with the control device.
