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EXAFS研究合成甲醇催化剂Cu/ZnO/M_xO_y 被引量:3
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作者 沈百荣 韩继红 +3 位作者 孙琦 范康年 顾昌鑫 邓景发 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 1997年第12期2038-2040,共3页
The effect of the ternary component on the structure and catalytic behavior ofCu/ZnO/MxOy catalysts for methanol synthesis from hydrogenation and carbon di0xide hasbeen studied by EXAFS. The results show that there is... The effect of the ternary component on the structure and catalytic behavior ofCu/ZnO/MxOy catalysts for methanol synthesis from hydrogenation and carbon di0xide hasbeen studied by EXAFS. The results show that there is a relationship among the catalyticactivity, the acidity of the ternary component and the dispersity of Cu respectively. It meansthat the active site of the catalyst of this reaction should be Cu or Cu+. 展开更多
关键词 EXAFS 二氧化碳 加氢 甲醇 催化剂
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Mo-Ni-γ-Al_2O_3体系中Mo、Ni近邻结构的EXAFS研究 被引量:2
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作者 韩继红 徐卫 +5 位作者 顾昌鑫 华中一 牛国兴 朱崇业 陈海鹰 李全芝 《物理化学学报》 SCIE CAS CSCD 北大核心 1997年第12期1108-1114,共7页
运用EXAFS技术对加入P2O5或TiO2的MO-Ni-γ-Al2O3体系中Mo、Ni的K吸收边进行了分析,获得了体系中金属组分原子周围的微观结构信息,从而进一步证实P或Ti的加入有助于含量较高的Mo、Ni在载体表面的高度分散,样品中适量的P有助于形成较... 运用EXAFS技术对加入P2O5或TiO2的MO-Ni-γ-Al2O3体系中Mo、Ni的K吸收边进行了分析,获得了体系中金属组分原子周围的微观结构信息,从而进一步证实P或Ti的加入有助于含量较高的Mo、Ni在载体表面的高度分散,样品中适量的P有助于形成较多的八面体结构,所有含P的样品中八面体结构含量均高于含Ti的样品,八面体结构Mo-O键上的氧在加氢脱硫反应中较易被硫取代,因而提高反应活性,这是含八面体结构较多的MoNiP样品的加氢脱硫活性优于MoNiTi样品的一个重要原因. 展开更多
关键词 石油炼制 双金属体系 加氢脱硫 催化剂
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Simulation Studies of Rib Structure Effect on Discharge Characteristics of Plasma Display Panel 被引量:1
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作者 丁可 邓斌 +2 位作者 单莉英 孙琦 顾昌鑫 《Plasma Science and Technology》 SCIE EI CAS CSCD 2007年第1期80-88,共9页
To investigate the effect of the rib structure on the discharge characteristics of the plasma display panel, the potential distribution, particles density distribution and ions incident angle distribution were examine... To investigate the effect of the rib structure on the discharge characteristics of the plasma display panel, the potential distribution, particles density distribution and ions incident angle distribution were examined by simulation of a two-dimensional particle-in-cell/Monte Carlo collision, with two kinds of rib structure: the stripe rib structure and the Waffle rib structure. The results showed that the distribution of electric potential at the corner of the discharge cell was almost the same for these two rib structures while in the centre there was a difference between these two rib structures. The striation phenomenon could be observed in both cases. The distribution of density also indicated that the striation phenomenon was accompanied by the firing of discharge, and the Waffle rib structure might reduce the density humps. In the cell with a stripe rib structure, the profiles of the surface charge density along the sustained dielectric layer presented a better fluctuating distribution than that in the cell with a Waffle rib structure. The spatial potential and particle density in the discharge bulk showed that the Waffle ribs could weaken the striation phenomenon, which could be explained by the decrease in the particle numbers in the discharge cell. The simulation results of the ion incident angle showed that most ions impacted the sustained dielectric layer in the normal stripe rib cell with an incident angle in the range of 6° to 19° while with the Waffle rib structure the incident angle of most ions was in the range of 4° to 19°. The Waffle rib structure did not affect the angle distribution of incident ions significantly. 展开更多
关键词 discharge characteristics surface charge ion angle distribution plasma display panel
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Ion-Sputter-Induced Nanodots on Si(110): Ion Energy Dependence
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作者 李维卿 凌立 +4 位作者 漆乐俊 杨新菊 范文彬 顾昌鑫 陆明 《Chinese Physics Letters》 SCIE CAS CSCD 2005年第4期919-922,共4页
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Surface morphology evolution of Si(110) by ion sputtering as a function of sample temperature
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作者 漆乐俊 凌立 +3 位作者 李维卿 杨新菊 顾昌鑫 陆明 《Chinese Physics B》 SCIE EI CAS CSCD 2005年第8期1626-1630,共5页
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