By using the combination of solvothermal and microemulsion methods, hierarchical cobalt nanorods with 70 nm width and 39 mm length have been prepared under mild conditions. The nanorods are composed of a bundle of 20 ...By using the combination of solvothermal and microemulsion methods, hierarchical cobalt nanorods with 70 nm width and 39 mm length have been prepared under mild conditions. The nanorods are composed of a bundle of 20 nm wide whiskers, which are composed of spherical nanoparticles（\{5 nm\}）. It is suggested that the co-operation of the reduction of Co 2+ and the transition from spherical \{micelles\} into hexagonal rod-like micelles lead to the formation of the nanostructured cobalt filaments.展开更多
A novel three dimensional fluorinated gallium phosphate has been hydrothermally synthesized by using diethylenetriamine as an organic structure directing agent. X ray single crystal structure analysis indicates this c...A novel three dimensional fluorinated gallium phosphate has been hydrothermally synthesized by using diethylenetriamine as an organic structure directing agent. X ray single crystal structure analysis indicates this compound crystallizes in the orthorhombic space group Pbca, a =1.605 6(7) nm, b = 1 011 4 (4) nm, c =1.854 6(5) nm, V =3.011 6(19) nm 3, Z =4. The three dimensional framework based on linkage of corner sharing polyhedron PO 4, GaO 4F and GaO 4F 2 delimit ten ring channels along b axis in which the triply protonated amines are located serving as charge compensating guests and supporters.展开更多
文摘By using the combination of solvothermal and microemulsion methods, hierarchical cobalt nanorods with 70 nm width and 39 mm length have been prepared under mild conditions. The nanorods are composed of a bundle of 20 nm wide whiskers, which are composed of spherical nanoparticles（\{5 nm\}）. It is suggested that the co-operation of the reduction of Co 2+ and the transition from spherical \{micelles\} into hexagonal rod-like micelles lead to the formation of the nanostructured cobalt filaments.
文摘A novel three dimensional fluorinated gallium phosphate has been hydrothermally synthesized by using diethylenetriamine as an organic structure directing agent. X ray single crystal structure analysis indicates this compound crystallizes in the orthorhombic space group Pbca, a =1.605 6(7) nm, b = 1 011 4 (4) nm, c =1.854 6(5) nm, V =3.011 6(19) nm 3, Z =4. The three dimensional framework based on linkage of corner sharing polyhedron PO 4, GaO 4F and GaO 4F 2 delimit ten ring channels along b axis in which the triply protonated amines are located serving as charge compensating guests and supporters.
文摘以仲钼酸铵和四氯化锡为原料,采用水热法制备了不同Sn掺杂比例的MoO_3;利用X射线衍射(XRD),扫描电子显微镜(SEM)和Brunauer-Emmett Teller(BET)测试等手段对材料进行了物相、形貌结构和孔径表征;测试了其对乙醇、二氯甲烷、甲醇、甲醛、甲酸、四氯化碳、氨气和丙酮等气体的传感性能.结果表明,Sn掺杂未改变MoO_3的结构;290℃为气体传感测试的最佳测试温度;掺杂后的MoO_3对乙醇气体的灵敏度和响应时间均优于纯相MoO_3,Sn掺杂摩尔比为5%时效果最好,500 mg/m^3测试条件下对乙醇的灵敏度为19.64,响应时间为1.1 s.
