The weak interlayer van der Waals(vdW) interactions in two-dimensional(2D) vdW materials enable sliding ferroelectricity as an effective strategy for modulating their intrinsic properties. In this work, we systematica...The weak interlayer van der Waals(vdW) interactions in two-dimensional(2D) vdW materials enable sliding ferroelectricity as an effective strategy for modulating their intrinsic properties. In this work, we systematically investigate the influence of interlayer sliding on the electronic behavior of PtSe_(2) using density functional theory(DFT) calculations. Our results demonstrate that interlayer sliding induces a pronounced photocurrent spanning the short-wavelength infrared to visible spectral ranges. Remarkably, under an applied gate voltage, the sliding ferroelectric PtSe_(2) exhibits anomalously enhanced photovoltaic performance and an ultrahigh extinction ratio.Transmission spectral analysis reveals that this phenomenon originates from band structure modifications driven by energy-level transitions. Furthermore, the observed photocurrent enhancement via sliding ferroelectricity demonstrates universality across diverse platinum-based optoelectronic devices. This study introduces a novel paradigm for tailoring the intrinsic characteristics of 2D vdW semiconductors, expanding the design space for next-generation ferroelectric materials in advanced optoelectronic applications.展开更多
The yearly growing quantities of dataflow create a desired requirement for advanced data storage methods.Luminescent materials,which possess adjustable parameters such as intensity,emission center,lifetime,polarizatio...The yearly growing quantities of dataflow create a desired requirement for advanced data storage methods.Luminescent materials,which possess adjustable parameters such as intensity,emission center,lifetime,polarization,etc.,can be used to enable multi-dimensional optical data storage(ODS)with higher capacity,longer lifetime and lower energy consumption.Multiplexed storage based on luminescent materials can be easily manipulated by lasers,and has been considered as a feasible option to break through the limits of ODS density.Substantial progresses in laser-modified luminescence based ODS have been made during the past decade.In this review,we recapitulated recent advancements in laser-modified luminescence based ODS,focusing on the defect-related regulation,nucleation,dissociation,photoreduction,ablation,etc.We conclude by discussing the current challenges in laser-modified luminescence based ODS and proposing the perspectives for future development.展开更多
基金supported by the National Key Research and Development Program of China (Grant No. 2024YFB3211701)the National Natural Science Foundation of China (Grant Nos. T2222011, 62174026, and 12274234)+1 种基金the National Key Research and Development Program of China (Grant Nos. 2023YFB3611400 and 2019YFA0308000)the Fundamental Research Funds for the Central Universities (Grant No. 242023k30027)。
文摘The weak interlayer van der Waals(vdW) interactions in two-dimensional(2D) vdW materials enable sliding ferroelectricity as an effective strategy for modulating their intrinsic properties. In this work, we systematically investigate the influence of interlayer sliding on the electronic behavior of PtSe_(2) using density functional theory(DFT) calculations. Our results demonstrate that interlayer sliding induces a pronounced photocurrent spanning the short-wavelength infrared to visible spectral ranges. Remarkably, under an applied gate voltage, the sliding ferroelectric PtSe_(2) exhibits anomalously enhanced photovoltaic performance and an ultrahigh extinction ratio.Transmission spectral analysis reveals that this phenomenon originates from band structure modifications driven by energy-level transitions. Furthermore, the observed photocurrent enhancement via sliding ferroelectricity demonstrates universality across diverse platinum-based optoelectronic devices. This study introduces a novel paradigm for tailoring the intrinsic characteristics of 2D vdW semiconductors, expanding the design space for next-generation ferroelectric materials in advanced optoelectronic applications.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.61774034 and 12104090)。
文摘The yearly growing quantities of dataflow create a desired requirement for advanced data storage methods.Luminescent materials,which possess adjustable parameters such as intensity,emission center,lifetime,polarization,etc.,can be used to enable multi-dimensional optical data storage(ODS)with higher capacity,longer lifetime and lower energy consumption.Multiplexed storage based on luminescent materials can be easily manipulated by lasers,and has been considered as a feasible option to break through the limits of ODS density.Substantial progresses in laser-modified luminescence based ODS have been made during the past decade.In this review,we recapitulated recent advancements in laser-modified luminescence based ODS,focusing on the defect-related regulation,nucleation,dissociation,photoreduction,ablation,etc.We conclude by discussing the current challenges in laser-modified luminescence based ODS and proposing the perspectives for future development.
