A experimental study of characteristics of NO reduction by a simulating production gas of biomass gasification was performed in a ceramic flow reactor heated by an electric furnace.The gas was composed of CO,CO2,CH4,H...A experimental study of characteristics of NO reduction by a simulating production gas of biomass gasification was performed in a ceramic flow reactor heated by an electric furnace.The gas was composed of CO,CO2,CH4,H2 and N2,and the temperature used in the experiments ranged from 1 000 ℃ to 1 400 ℃.The influence of the inlet concentration of oxygen(0%～5%),the local equivalence ratio,φ(0.5～2.28),and the reactor temperatures was studied to analyse the characteristics of biomass gasification-reburning.The results indicate that more consumption of reducting agent is needed to increase the NO reduction efficiency in pyrolysis condition.The suitable values of the local equivalence ratio,φ,could make the NO reduction efficiency in oxidation condition higher than that in pyrolysis condition.The local equivalence ratio is an important parameter for NO reduction,and higher NO reduction efficiency can be obtained when φ varies between 0.8 and 1.1.The reduction of NO is favored at high temperatures.展开更多
针对生物质气化再燃技术路线中焦油的价值及利用开展研究。通过热重-质谱联用仪分析典型农业废弃物在热解、气化过程中焦油组分的析出情况,并在管式流动实验台上研究焦油在生物质气化气还原NO中的作用以及焦油还原NO受当量比、温度等因...针对生物质气化再燃技术路线中焦油的价值及利用开展研究。通过热重-质谱联用仪分析典型农业废弃物在热解、气化过程中焦油组分的析出情况,并在管式流动实验台上研究焦油在生物质气化气还原NO中的作用以及焦油还原NO受当量比、温度等因素的影响规律,最后建立了甲苯还原NO的机制模型,并以停流动实验台的实验结果进行了验证。结果表明:苯、甲苯、苯乙烯和苯酚是具有代表性的焦油组分;焦油对生物质气化气还原NO有积极的作用;焦油组分还原NO存在最佳的当量比,并要求合适的温度窗口,需要关注聚合反应;甲苯还原NO机制(NO reduction by toluene,NRT)模型与实验结果拟合良好,模型的生成速率和消耗速率分析显示HCCO和C2H在焦油还原NO中具有重要作用。展开更多
文摘A experimental study of characteristics of NO reduction by a simulating production gas of biomass gasification was performed in a ceramic flow reactor heated by an electric furnace.The gas was composed of CO,CO2,CH4,H2 and N2,and the temperature used in the experiments ranged from 1 000 ℃ to 1 400 ℃.The influence of the inlet concentration of oxygen(0%～5%),the local equivalence ratio,φ(0.5～2.28),and the reactor temperatures was studied to analyse the characteristics of biomass gasification-reburning.The results indicate that more consumption of reducting agent is needed to increase the NO reduction efficiency in pyrolysis condition.The suitable values of the local equivalence ratio,φ,could make the NO reduction efficiency in oxidation condition higher than that in pyrolysis condition.The local equivalence ratio is an important parameter for NO reduction,and higher NO reduction efficiency can be obtained when φ varies between 0.8 and 1.1.The reduction of NO is favored at high temperatures.
文摘针对生物质气化再燃技术路线中焦油的价值及利用开展研究。通过热重-质谱联用仪分析典型农业废弃物在热解、气化过程中焦油组分的析出情况,并在管式流动实验台上研究焦油在生物质气化气还原NO中的作用以及焦油还原NO受当量比、温度等因素的影响规律,最后建立了甲苯还原NO的机制模型,并以停流动实验台的实验结果进行了验证。结果表明:苯、甲苯、苯乙烯和苯酚是具有代表性的焦油组分;焦油对生物质气化气还原NO有积极的作用;焦油组分还原NO存在最佳的当量比,并要求合适的温度窗口,需要关注聚合反应;甲苯还原NO机制(NO reduction by toluene,NRT)模型与实验结果拟合良好,模型的生成速率和消耗速率分析显示HCCO和C2H在焦油还原NO中具有重要作用。
