A building unit(defined as SBU) synthesized from 1,2,4,5-benzene tetracarboxylic acid and 4-hydroxy pyridine was used as the gelator with low molecular weight to form supramolecular hydrogels at various concentrations...A building unit(defined as SBU) synthesized from 1,2,4,5-benzene tetracarboxylic acid and 4-hydroxy pyridine was used as the gelator with low molecular weight to form supramolecular hydrogels at various concentrations.The dried hydrogels(xerogels) were observed by scanning electron microscope(SEM).The results indicate that the xerogels possess network structures composing of intertwined fibers and the dimension of the fibers can be regulated by the concentration of SBU.Powder X-ray diffraction(XRD) analysis indicates that the fibers are connected by SBU building units.The reversible sol-gel transition of the supramolecular system with the change of temperature was also noticed.展开更多
文摘A building unit(defined as SBU) synthesized from 1,2,4,5-benzene tetracarboxylic acid and 4-hydroxy pyridine was used as the gelator with low molecular weight to form supramolecular hydrogels at various concentrations.The dried hydrogels(xerogels) were observed by scanning electron microscope(SEM).The results indicate that the xerogels possess network structures composing of intertwined fibers and the dimension of the fibers can be regulated by the concentration of SBU.Powder X-ray diffraction(XRD) analysis indicates that the fibers are connected by SBU building units.The reversible sol-gel transition of the supramolecular system with the change of temperature was also noticed.
