We report an external cavity quantum cascade laser （EC-QCL） operating near 6.9μm using the Littman Metcalf configuration. The EC-QCL works in a pulsed mode and can be tuned continuously from 1340 to 1640cm^-1 by on...We report an external cavity quantum cascade laser （EC-QCL） operating near 6.9μm using the Littman Metcalf configuration. The EC-QCL works in a pulsed mode and can be tuned continuously from 1340 to 1640cm^-1 by only tilting the tuning mirror. The fine tuning ability of the EC-QCL is demonstrated by measuring the absorption spectrum of water in the ambient air with a lock-in amplifier.展开更多
The rovibrational spectrum of O2–N2O van der Waals complex is measured in the ν1 symmetric stretch region of N2 O monomer using a tunable diode laser spectrometer. The complex is generated by a slit-pulsed supersoni...The rovibrational spectrum of O2–N2O van der Waals complex is measured in the ν1 symmetric stretch region of N2 O monomer using a tunable diode laser spectrometer. The complex is generated by a slit-pulsed supersonic expansion with gas mixtures of O2, N2 O, and He. Both a- and b-type transitions are observed. The effective Hamiltonian for an open-shell complex consisting of a diatomic molecule in a ^3Σ electronic state and a closed-shell partner is used to analyze the observed spectrum. Molecular constants in the vibrationally excited state are determined accurately. The band-origin of the spectrum is determined to be 1284.7504（25） cm^-1, red-shifted from that of the N2 O monomer by ～ 0.1529 cm^-1.展开更多
This paper reports that the absorption spectra of H2O^＋ have been measured by tunable mid-infrared diode laser spectroscopy in the spectral range of 1100-1380 cm^-1. The H2O＋ ions are generated in an AC glow dischar...This paper reports that the absorption spectra of H2O^＋ have been measured by tunable mid-infrared diode laser spectroscopy in the spectral range of 1100-1380 cm^-1. The H2O＋ ions are generated in an AC glow discharge of the gaseous mixtures of H2O/He and detected with the velocity modulation technique. Forty new lines are assigned to the ν2 fundamental band of H2O^＋ （X^2B1）. The observed lines together with other data published previously are fitted to the standard effective Hamiltonian of an asymmetric top, yielding a set of improved rotational constants, spin-rotation constants and their quartic and sextic centrifugal distortion constants for the ν2=1 vibrational state of H2O＋.展开更多
An intracavity CO laser magnetic resonance spectrometer with homogeneous dc electric field applied via a pair of parallel Stark plates in the absorption cell is used to measure the electric dipole moments of free radi...An intracavity CO laser magnetic resonance spectrometer with homogeneous dc electric field applied via a pair of parallel Stark plates in the absorption cell is used to measure the electric dipole moments of free radicals.Taking advantage of high sensitivity and high resolution of this technique and the Stark effect,highly-resolved saturated absorption spectra of v=1-0 transition of ^(15)N^(16)O in the ground state X^(2)II_(3/2) have been successfully observed in the presence of a low electric field.The electric dipole moment of NO in the electronic ground state is determined asμ=0.1566±14 D(Debye)from the analysis of the observed spectra,confirming that,combined with the Stark field,the laser magnetic resonance technique can be an effective and reliable approach for the precise measurement of electric dipole moments of free radicals,especially the unstable ones.展开更多
Twenty-five new R-branch lines of the v2（1^-← 0^＋） band of H3O^＋ are measured using diode laser velocity modulation spectroscopy between 1070 and 1230 cm^-1. The H3O^＋ ions are produced in a high voltage ac disc...Twenty-five new R-branch lines of the v2（1^-← 0^＋） band of H3O^＋ are measured using diode laser velocity modulation spectroscopy between 1070 and 1230 cm^-1. The H3O^＋ ions are produced in a high voltage ac discharge with water diluted in helium. The observed lines together with all the previously published measurements are fit to the standard vibration-rotational Hamiltonian of an oblate symmetric top, yielding a set of improved molecular constants. All the sextic centrifugal distortion constants for both 0^＋ and 1^- states are determined precisely. The observed R（13, 0） transition is shifted about -0.129 cm^-1 from its calculated value, indicating that a near degeneracy exists between the （13, 0）^＋ and （13, 3）^- ground-state rotation-inversion levels.展开更多
基金Supported by the National Natural Science Foundation of China under Grant Nos 11174098 and 11574107the SelfDetermined Research Funds of Central China Normal University under Grant No CCNU15A02034
文摘We report an external cavity quantum cascade laser （EC-QCL） operating near 6.9μm using the Littman Metcalf configuration. The EC-QCL works in a pulsed mode and can be tuned continuously from 1340 to 1640cm^-1 by only tilting the tuning mirror. The fine tuning ability of the EC-QCL is demonstrated by measuring the absorption spectrum of water in the ambient air with a lock-in amplifier.
基金Project supported by the National Natural Science Foundation of China(Grants Nos.11174098,11304023,and 11304095)
文摘The rovibrational spectrum of O2–N2O van der Waals complex is measured in the ν1 symmetric stretch region of N2 O monomer using a tunable diode laser spectrometer. The complex is generated by a slit-pulsed supersonic expansion with gas mixtures of O2, N2 O, and He. Both a- and b-type transitions are observed. The effective Hamiltonian for an open-shell complex consisting of a diatomic molecule in a ^3Σ electronic state and a closed-shell partner is used to analyze the observed spectrum. Molecular constants in the vibrationally excited state are determined accurately. The band-origin of the spectrum is determined to be 1284.7504（25） cm^-1, red-shifted from that of the N2 O monomer by ～ 0.1529 cm^-1.
基金Project supported by the National Natural Science Foundation of China (Grant Nos 10544002 and 10604019)
文摘This paper reports that the absorption spectra of H2O^＋ have been measured by tunable mid-infrared diode laser spectroscopy in the spectral range of 1100-1380 cm^-1. The H2O＋ ions are generated in an AC glow discharge of the gaseous mixtures of H2O/He and detected with the velocity modulation technique. Forty new lines are assigned to the ν2 fundamental band of H2O^＋ （X^2B1）. The observed lines together with other data published previously are fitted to the standard effective Hamiltonian of an asymmetric top, yielding a set of improved rotational constants, spin-rotation constants and their quartic and sextic centrifugal distortion constants for the ν2=1 vibrational state of H2O＋.
基金Supported by the National Natural Science Foundation of China under Grant No.19874072.
文摘An intracavity CO laser magnetic resonance spectrometer with homogeneous dc electric field applied via a pair of parallel Stark plates in the absorption cell is used to measure the electric dipole moments of free radicals.Taking advantage of high sensitivity and high resolution of this technique and the Stark effect,highly-resolved saturated absorption spectra of v=1-0 transition of ^(15)N^(16)O in the ground state X^(2)II_(3/2) have been successfully observed in the presence of a low electric field.The electric dipole moment of NO in the electronic ground state is determined asμ=0.1566±14 D(Debye)from the analysis of the observed spectra,confirming that,combined with the Stark field,the laser magnetic resonance technique can be an effective and reliable approach for the precise measurement of electric dipole moments of free radicals,especially the unstable ones.
基金Supported by the National Natural Science Foundation of China under Grant Nos 10604019 and 10474027, and Natural Science Foundation of Hubei Province under Grant No 2006ABA176.
文摘Twenty-five new R-branch lines of the v2（1^-← 0^＋） band of H3O^＋ are measured using diode laser velocity modulation spectroscopy between 1070 and 1230 cm^-1. The H3O^＋ ions are produced in a high voltage ac discharge with water diluted in helium. The observed lines together with all the previously published measurements are fit to the standard vibration-rotational Hamiltonian of an oblate symmetric top, yielding a set of improved molecular constants. All the sextic centrifugal distortion constants for both 0^＋ and 1^- states are determined precisely. The observed R（13, 0） transition is shifted about -0.129 cm^-1 from its calculated value, indicating that a near degeneracy exists between the （13, 0）^＋ and （13, 3）^- ground-state rotation-inversion levels.
