The electronic doping effect on both the superconductivity and the nematic order in the FeSe nanoflake are investigated by using the electric-double-layer transistor configuration. The superconductivity can be effecti...The electronic doping effect on both the superconductivity and the nematic order in the FeSe nanoflake are investigated by using the electric-double-layer transistor configuration. The superconductivity can be effectively controlled by electronic doping, and the onset superconducting transition temperature Tc reaches as high as 45 K at a gate voltage Of Vg = 4 V. Meanwhile, the nematic phase is gradually suppressed with the increase of electronic doping (or Vg). The results provide an effective method with variable charge doping for investigation of the rich physics in the FeSe superconductor.展开更多
The structures and stabilization of three crystal surfaces of TCNQ-based charge transfer complexes(CTCs) including PrQ(TCNQ) 2,MPM(TCNQ) 2,and MEM(TCNQ) 2,have been investigated by scanning tunneling microscop...The structures and stabilization of three crystal surfaces of TCNQ-based charge transfer complexes(CTCs) including PrQ(TCNQ) 2,MPM(TCNQ) 2,and MEM(TCNQ) 2,have been investigated by scanning tunneling microscopy(STM).The three bulk-truncated surfaces are all ac-surface,which are terminated with TCNQ molecular arrays.On the ac-surface of PrQ(TCNQ) 2,the TCNQ molecules form a tetramer structure with a wavelike row behavior and a 纬 angle of about 18掳 between adjacent molecules.Moreover,the dimer structures are resolved on both ac-surfaces of MPM(TCNQ) 2 and MEM(TCNQ) 2.In addition,the tetramer structure is the most stable structure,while the dimer structures are unstable and easily subject to the STM tip disturbance,which results in changeable unit cells.The main reasons for the surface stabilization variation among the three ac-surfaces are provided by using the '蟺-atom model'.展开更多
Monolayer MnTe_(2)stabilized as 1 T structure has been theoretically predicted to be a two-dimensional(2 D)ferromagnetic metal and can be tuned via strain engineering.There is no naturally van der Waals(vdW)layered Mn...Monolayer MnTe_(2)stabilized as 1 T structure has been theoretically predicted to be a two-dimensional(2 D)ferromagnetic metal and can be tuned via strain engineering.There is no naturally van der Waals(vdW)layered MnTe_(2)bulk,leaving mechanical exfoliation impossible to prepare monolayer MnTe_(2).Herein,by means of molecular beam epitaxy(MBE),we successfully prepared monolayer hexagonal MnTe_(2)on Si(111)under Te rich condition.Sharp reflection high-energy electron diffraction(RHEED)and low-energy electron diffraction(LEED)patterns suggest the monolayer is atomically flat without surface reconstruction.The valence state of Mn^(4+)and the atom ratio of([Te]:[Mn])further confirm the MnTe_(2)compound.Scanning tunneling spectroscopy(STS)shows the hexagonal MnTe_(2)monolayer is a semiconductor with a large bandgap of~2.78 eV.The valence-band maximum(VBM)locates at theΓpoint,as illustrated by angle-resolved photoemission spectroscopy(ARPES),below which three hole-type bands with parabolic dispersion can be identified.The successful synthesis of monolayer MnTe_(2)film provides a new platform to investigate the 2D magnetism.展开更多
基金Supported by the National Natural Science Foundation of China under Grant Nos 11174294,11174291,11374302,11304319,U1332209,U1432251 and U1532153the China Postdoctoral Science Foundation under Grant No 2015M582020+1 种基金the Program of Users with Excellence,the Hefei Science Center of Chinese Academy of Sciencesthe CAS/SAFEA International Partnership Program for Creative Research Teams of China
文摘The electronic doping effect on both the superconductivity and the nematic order in the FeSe nanoflake are investigated by using the electric-double-layer transistor configuration. The superconductivity can be effectively controlled by electronic doping, and the onset superconducting transition temperature Tc reaches as high as 45 K at a gate voltage Of Vg = 4 V. Meanwhile, the nematic phase is gradually suppressed with the increase of electronic doping (or Vg). The results provide an effective method with variable charge doping for investigation of the rich physics in the FeSe superconductor.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.10804010,50772015,60977015,and 10974019)the National Basic Research Program of China(Grant No.2006CB932301)the Scientific Research Foundation for the Returned Overseas Chinese Scholars of Ministry of Education
文摘The structures and stabilization of three crystal surfaces of TCNQ-based charge transfer complexes(CTCs) including PrQ(TCNQ) 2,MPM(TCNQ) 2,and MEM(TCNQ) 2,have been investigated by scanning tunneling microscopy(STM).The three bulk-truncated surfaces are all ac-surface,which are terminated with TCNQ molecular arrays.On the ac-surface of PrQ(TCNQ) 2,the TCNQ molecules form a tetramer structure with a wavelike row behavior and a 纬 angle of about 18掳 between adjacent molecules.Moreover,the dimer structures are resolved on both ac-surfaces of MPM(TCNQ) 2 and MEM(TCNQ) 2.In addition,the tetramer structure is the most stable structure,while the dimer structures are unstable and easily subject to the STM tip disturbance,which results in changeable unit cells.The main reasons for the surface stabilization variation among the three ac-surfaces are provided by using the '蟺-atom model'.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11604366,11634007,21872099,and 22072102)the National Natural Science Foundation of Jiangsu Province,China(Grant No.BK 20160397)support from the Youth Innovation Promotion Association of Chinese Academy of Sciences(Grant No.2017370)。
文摘Monolayer MnTe_(2)stabilized as 1 T structure has been theoretically predicted to be a two-dimensional(2 D)ferromagnetic metal and can be tuned via strain engineering.There is no naturally van der Waals(vdW)layered MnTe_(2)bulk,leaving mechanical exfoliation impossible to prepare monolayer MnTe_(2).Herein,by means of molecular beam epitaxy(MBE),we successfully prepared monolayer hexagonal MnTe_(2)on Si(111)under Te rich condition.Sharp reflection high-energy electron diffraction(RHEED)and low-energy electron diffraction(LEED)patterns suggest the monolayer is atomically flat without surface reconstruction.The valence state of Mn^(4+)and the atom ratio of([Te]:[Mn])further confirm the MnTe_(2)compound.Scanning tunneling spectroscopy(STS)shows the hexagonal MnTe_(2)monolayer is a semiconductor with a large bandgap of~2.78 eV.The valence-band maximum(VBM)locates at theΓpoint,as illustrated by angle-resolved photoemission spectroscopy(ARPES),below which three hole-type bands with parabolic dispersion can be identified.The successful synthesis of monolayer MnTe_(2)film provides a new platform to investigate the 2D magnetism.