Homogeneous monolith of A1PO4 gel doped with rhodamine 6G (Rh6G) at different dye loadings is prepared by a one-step process with sol-gel method using the precursors A1(lact)3 and H3PO4. The optical properties of ...Homogeneous monolith of A1PO4 gel doped with rhodamine 6G (Rh6G) at different dye loadings is prepared by a one-step process with sol-gel method using the precursors A1(lact)3 and H3PO4. The optical properties of A1PO4 gel doped with Rh6G are characterized by UV-Visible absorption spectra and fluorescence spectra. Rh6G molecular J-dimers and H-dimers even multimers are analyzed by excitation spectra based on exciton theory. The A1PO4 gel doped with Rh6G dye with molar ratio of Rh6G/A1(lact)3 of 1 × 10-4 has excellent optical properties without obvious aggregates.展开更多
基金Supported by the National Natural Science Foundation of China under Grant 50802103.
文摘Homogeneous monolith of A1PO4 gel doped with rhodamine 6G (Rh6G) at different dye loadings is prepared by a one-step process with sol-gel method using the precursors A1(lact)3 and H3PO4. The optical properties of A1PO4 gel doped with Rh6G are characterized by UV-Visible absorption spectra and fluorescence spectra. Rh6G molecular J-dimers and H-dimers even multimers are analyzed by excitation spectra based on exciton theory. The A1PO4 gel doped with Rh6G dye with molar ratio of Rh6G/A1(lact)3 of 1 × 10-4 has excellent optical properties without obvious aggregates.