The spreading behavior of new type of chiral and achiral rigid cyclic oligomer on the water surface was investigated by measuring the surface pressure(π) area( A ) isotherms, with the aim of comparison of new type LB...The spreading behavior of new type of chiral and achiral rigid cyclic oligomer on the water surface was investigated by measuring the surface pressure(π) area( A ) isotherms, with the aim of comparison of new type LB films of chiral and achiral rigid cyclic oligomers. Molecular resolution atomic force microscope images of the Langmuir Blodgett(LB) film was observed and the structure of their two dimensional crystals on the basal plane of mica was studied.展开更多
High-quality Fe-doped TiO_(2) films are epitaxially grown on MgF_(2) substrates by pulsed laser deposition.The x-ray diffraction and Raman spectra prove that they are of pure rutile phase.High-resolution transmission ...High-quality Fe-doped TiO_(2) films are epitaxially grown on MgF_(2) substrates by pulsed laser deposition.The x-ray diffraction and Raman spectra prove that they are of pure rutile phase.High-resolution transmission electron microscopy(TEM)further demonstrates that the epitaxial relationship between rutile-phased TiO_(2) and MgF_(2) substrates is 110 TiO_(2)||110 MgF_(2).The room temperature ferromagnetism is detected by alternative gradient magnetometer.By increasing the ambient oxygen pressure,magnetization shows that it decreases monotonically while absorption edge shows a red shift.The transport property measurement demonstrates a strong correlation between magnetization and carrier concentration.The influence of ambient oxygen pressure on magnetization can be well explained by a modified bound magnetization polarization model.展开更多
Topological magnetotransport in non-collinear antiferromagnets has attracted extensive attention due to the exotic phenomena such as large anomalous Hall effect(AHE),magnetic spin Hall effect,and chiral anomaly.The ma...Topological magnetotransport in non-collinear antiferromagnets has attracted extensive attention due to the exotic phenomena such as large anomalous Hall effect(AHE),magnetic spin Hall effect,and chiral anomaly.The materials exhibiting topological antiferromagnetic physics are typically limited in special Mn_3X family such as Mn_3Sn and Mn_3Ge.Exploring the topological magnetotransport in common antiferromagnetic materials widely used in spintronics will not only enrich the platforms for investigating the non-collinear antiferromagnetic physics,but also have great importance for driving the nontrivial topological properties towards practical applications.Here,we report remarkable AHE,anisotropic and negative parallel magnetoresistance in the magnetron-sputtered Ir_(20)Mn_(80)antiferromagnet,which is one of the most widely used antiferromagnetic materials in industrial spintronics.The ab initio calculations suggest that the Ir_4Mn_(16)(IrMn_4)or Mn_3Ir nanocrystals hold nontrivial electronic band structures,which may contribute to the observed intriguing magnetotransport properties in the Ir_(20)Mn_(80).Further,we demonstrate the spin–orbit torque switching of the antiferromagnetic Ir_(20)Mn_(80)by the spin Hall current of Pt.The presented results highlight a great potential of the magnetron-sputtered Ir_(20)Mn_(80)film for exploring the topological antiferromagnet-based physics and spintronics applications.展开更多
As promising materials,alloy-type anode materials have been intensively investigated in both academia and industry.To release huge volume expansion during alloying/dealloying process,they are usually doped with transi...As promising materials,alloy-type anode materials have been intensively investigated in both academia and industry.To release huge volume expansion during alloying/dealloying process,they are usually doped with transition metals.However,the electrochemical role of transition metals has not been fully understood.Here,pure Sn_(3)Fe films were deposited by sputtering,and the electrochemical mechanism was systematically investigated by operando magnetometry.We confirmed that Fe particles liberated by Li insertion recombine partially with Sn during the delithiation,while the stepwise increase in magnetization with the cycles demonstrates growth of Fe nanoparticles.In addition,we also found an unconventional increase of magnetization in the charging process,which can be attributed to the space charge storage at the interface of Fe/Li_(x)Sn.These critical findings pave the way for the mechanism understanding and development of high-performance Sn based alloy electrode materials.展开更多
文摘The spreading behavior of new type of chiral and achiral rigid cyclic oligomer on the water surface was investigated by measuring the surface pressure(π) area( A ) isotherms, with the aim of comparison of new type LB films of chiral and achiral rigid cyclic oligomers. Molecular resolution atomic force microscope images of the Langmuir Blodgett(LB) film was observed and the structure of their two dimensional crystals on the basal plane of mica was studied.
基金Project supported by the National Natural Science Foundation of China(Grant No.11504192)the Natural Science Foundation of Shandong Province,China(Grant Nos.ZR201910230017 and BSB2014010).
文摘High-quality Fe-doped TiO_(2) films are epitaxially grown on MgF_(2) substrates by pulsed laser deposition.The x-ray diffraction and Raman spectra prove that they are of pure rutile phase.High-resolution transmission electron microscopy(TEM)further demonstrates that the epitaxial relationship between rutile-phased TiO_(2) and MgF_(2) substrates is 110 TiO_(2)||110 MgF_(2).The room temperature ferromagnetism is detected by alternative gradient magnetometer.By increasing the ambient oxygen pressure,magnetization shows that it decreases monotonically while absorption edge shows a red shift.The transport property measurement demonstrates a strong correlation between magnetization and carrier concentration.The influence of ambient oxygen pressure on magnetization can be well explained by a modified bound magnetization polarization model.
基金the Tencent Foundation through the XPLORER PRIZEthe National Key Research and Development Program of China(Grant Nos.2018YFB0407602 and 2021YFB3601303)the National Natural Science Foundation of China(Grant Nos.61627813,11904017,92164206,and 61571023)。
文摘Topological magnetotransport in non-collinear antiferromagnets has attracted extensive attention due to the exotic phenomena such as large anomalous Hall effect(AHE),magnetic spin Hall effect,and chiral anomaly.The materials exhibiting topological antiferromagnetic physics are typically limited in special Mn_3X family such as Mn_3Sn and Mn_3Ge.Exploring the topological magnetotransport in common antiferromagnetic materials widely used in spintronics will not only enrich the platforms for investigating the non-collinear antiferromagnetic physics,but also have great importance for driving the nontrivial topological properties towards practical applications.Here,we report remarkable AHE,anisotropic and negative parallel magnetoresistance in the magnetron-sputtered Ir_(20)Mn_(80)antiferromagnet,which is one of the most widely used antiferromagnetic materials in industrial spintronics.The ab initio calculations suggest that the Ir_4Mn_(16)(IrMn_4)or Mn_3Ir nanocrystals hold nontrivial electronic band structures,which may contribute to the observed intriguing magnetotransport properties in the Ir_(20)Mn_(80).Further,we demonstrate the spin–orbit torque switching of the antiferromagnetic Ir_(20)Mn_(80)by the spin Hall current of Pt.The presented results highlight a great potential of the magnetron-sputtered Ir_(20)Mn_(80)film for exploring the topological antiferromagnet-based physics and spintronics applications.
基金supported by the National Natural Science Foundation of China(Grant Nos.22179066 and 11504192)the Natural Science Foundation of Shandong Province(Grant No.ZR2020MA073)。
文摘As promising materials,alloy-type anode materials have been intensively investigated in both academia and industry.To release huge volume expansion during alloying/dealloying process,they are usually doped with transition metals.However,the electrochemical role of transition metals has not been fully understood.Here,pure Sn_(3)Fe films were deposited by sputtering,and the electrochemical mechanism was systematically investigated by operando magnetometry.We confirmed that Fe particles liberated by Li insertion recombine partially with Sn during the delithiation,while the stepwise increase in magnetization with the cycles demonstrates growth of Fe nanoparticles.In addition,we also found an unconventional increase of magnetization in the charging process,which can be attributed to the space charge storage at the interface of Fe/Li_(x)Sn.These critical findings pave the way for the mechanism understanding and development of high-performance Sn based alloy electrode materials.
