There is an urgent need for high-quality and high-frequency clock generators for high-energy physics experiments.The transmission data rate exceeds 10 Gbps for a single channel in future readout electronics of silicon...There is an urgent need for high-quality and high-frequency clock generators for high-energy physics experiments.The transmission data rate exceeds 10 Gbps for a single channel in future readout electronics of silicon pixel detectors.Others,such as time measurement detectors,require a high time resolution based on the time-to-digital readout architecture.A phase-locked loop(PLL)is an essential and broadly used circuit in these applications.This study presents an application-specific integrated circuit of a low-jitter,low-power LC-tank that is PLL fabricated using 55-nm CMOS technology.It includes a 3rd-order frequency synthesis loop with a programmable bandwidth,a divide-by-2 pre-scaler,standard low-voltage differential signaling interfaces,and a current mode logic(CML)driver for clock transmissions.All the d-flip-flop dividers and phase-frequency detectors are protected from single-event upsets using the triple modular redundancy technique.The proposed VCO uses low-pass filters to suppress the noise from bias circuits.The tested LC-PLL covers a frequency locking range between 4.74 GHz and 5.92 GHz with two sub-bands.The jitter measurements of the frequency-halved clock(2.56 GHz)are less than 460 fs and 0.8 ps for the random and deterministic jitters,respectively,and a total of 7.5 ps peak-to-peak with a bit error rate of 10^(-12).The random and total jitter values for frequencies of 426 MHz and 20 MHz are less than 1.8 ps and 65 ps,respectively.The LC-PLL consumed 27 mW for the core and 73.8 mW in total.The measured results nearly coincided with the simulations and validated the analyses and tests.展开更多
Atom-level modulation of the coordination environment for single-atom catalysts(SACs)is considered as an effective strategy for elevating the catalytic performance.For the MNxsite,breaking the symmetrical geometry and...Atom-level modulation of the coordination environment for single-atom catalysts(SACs)is considered as an effective strategy for elevating the catalytic performance.For the MNxsite,breaking the symmetrical geometry and charge distribution by introducing relatively weak electronegative atoms into the first/second shell is an efficient way,but it remains challenging for elucidating the underlying mechanism of interaction.Herein,a practical strategy was reported to rationally design single cobalt atoms coordinated with both phosphorus and nitrogen atoms in a hierarchically porous carbon derived from metal-organic frameworks.X-ray absorption spectrum reveals that atomically dispersed Co sites are coordinated with four N atoms in the first shell and varying numbers of P atoms in the second shell(denoted as Co-N/P-C).The prepared catalyst exhibits excellent oxygen reduction reaction(ORR)activity as well as zinc-air battery performance.The introduction of P atoms in the Co-SACs weakens the interaction between Co and N,significantly promoting the adsorption process of ^(*)OOH,resulting in the acceleration of reaction kinetics and reduction of thermodynamic barrier,responsible for the increased intrinsic activity.Our discovery provides insights into an ultimate design of single-atom catalysts with adjustable electrocatalytic activities for efficient electrochemical energy conversion.展开更多
The GECAM series of satellites utilizes LaBr_(3)(Ce),LaBr_(3)(Ce,Sr),and NaI(Tl)crystals as sensitive materials for gamma-ray detectors(GRDs).To investigate the nonlinearity in the detection of low-energy gamma rays a...The GECAM series of satellites utilizes LaBr_(3)(Ce),LaBr_(3)(Ce,Sr),and NaI(Tl)crystals as sensitive materials for gamma-ray detectors(GRDs).To investigate the nonlinearity in the detection of low-energy gamma rays and address the errors in the calibration of the E-C relationship,comprehensive tests and comparative studies of the three aforementioned crystals were conducted using Compton electrons,radioactive sources,and mono-energetic X-rays.The nonlinearity test results of the Compton electrons and X-rays demonstrated substantial differences,with all three crystals presenting a higher nonlinearity for X/-rays than for Compton electrons.Despite the LaBr_(3)(Ce)and LaBr_(3)(Ce,Sr)crystals having higher absolute light yields,they exhibited a noticeable nonlinear decrease in the light yield,especially at energies below 400 keV.The NaI(Tl)crystal demonstrated an"excess"light output in the 6-200 keV range,reaching a maximum"excess"of 9.2%at 30 keV in the X-ray testing and up to 15.5%at 14 keV during Compton electron testing,indicating a significant advantage in the detection of low-energy gamma rays.Furthermore,we explored the underlying causes of the observed nonlinearity in these crystals.This study not only elucidates the detector responses of GECAM,but also initiates a comprehensive investigation of the nonlinearity of domestically produced lanthanum bromide and sodium iodide crystals.展开更多
The efficacy of the oxygen reduction reaction(ORR) in fuel cells can be significantly enhanced by optimizing cobalt-based catalysts,which provide a more stable alternative to iron-based catalysts.However,their perform...The efficacy of the oxygen reduction reaction(ORR) in fuel cells can be significantly enhanced by optimizing cobalt-based catalysts,which provide a more stable alternative to iron-based catalysts.However,their performance is often impeded by weak adsorption of oxygen species,leading to a 2e^(-)pathway that negatively affects fuel cell discharge efficiency.Here,we engineered a high-density cobalt active center catalyst,coordinated with nitrogen and sulfur atoms on a porous carbon substrate.Both experimental and theoretical analyses highlighted the role of sulfur atoms as electron donors,disrupting the charge symmetry of the original Co active center and promoting enhanced interaction with Co 3d orbitals.This modification improves the adsorption of oxygen and reaction intermediates during ORR,significantly reducing the production of hydrogen peroxide(H_(2)O_(2)).Remarkably,the optimized catalyst demonstrated superior fuel cell performance,with peak power densities of 1.32 W cm^(-2) in oxygen and 0.61 W cm^(-2) in air environments,respectively.A significant decrease in H_(2)O_(2) by-product accumulation was observed during the reaction process,reducing catalyst and membrane damage and consequently improving fuel cell durability.This study emphasizes the critical role of coordination symmetry in Co/N/C catalysts and proposes an effective strategy to enhance fuel cell performance.展开更多
Neutron-sensitive microchannel plates(nMCPs)have applications in neutron detection,including energy spectrum measurements,neutron-induced cross sections,and neutron imaging.10B-doped MCPs(B-MCPs)have attracted signifi...Neutron-sensitive microchannel plates(nMCPs)have applications in neutron detection,including energy spectrum measurements,neutron-induced cross sections,and neutron imaging.10B-doped MCPs(B-MCPs)have attracted significant attention owing to their potential for exhibiting a high neutron detection efficiency over a large neutron energy range.Good spatial and temporal resolutions are useful for neutron energy-resolved imaging.However,their practical applications still face many technical challenges.In this study,a B-MCP with 10 mol%10B was tested for its response to wide-energy neutrons from eV to MeV at the Back-n white neutron source at the China Spallation Neutron Source.The neutron detection efficiency was calibrated at 1 eV,which is approximately 300 times that of an ordinary MCP and indicates the success of 10 B doping.The factors that caused the reduction in the detection efficiency were simulated and discussed.The neutron energy spectrum obtained using B-MCP was compared with that obtained by other measurement methods,and showed very good consistency for neutron energies below tens of keV.The response is more complicated at higher neutron energy,at which point the elastic and nonelastic reactions of all nuclides of B-MCP gradually become dominant.This is beneficial for the detection of neutrons,as it compensates for the detection efficiency of B-MCP for high-energy neutrons.展开更多
Surface-enhanced Raman Spectroscopy(SERS)is a nondestructive technique for rapid detection of analytes even at the single-molecule level.However,highly sensitive and reliable SERS substrates are mostly fabricated with...Surface-enhanced Raman Spectroscopy(SERS)is a nondestructive technique for rapid detection of analytes even at the single-molecule level.However,highly sensitive and reliable SERS substrates are mostly fabricated with complex nanofabrication techniques,greatly restricting their practical applications.A convenient electrochemical method for transforming the surface of commercial gold wires/foils into silver-alloyed nanostructures is demonstrated in this report.Au substrates are treated with repetitive anodic and cathodic bias in an electrolyte of thiourea,in a one-pot one-step manner.X-rays absorption fine structure(XAFS)spectroscopy confirms that the AuAg alloy is induced at the surface.The unique AuAg alloyed surface nanostructures are particularly advantageous when served as SERS substrates,enabling a remarkably sensitive detection of Rhodamine B(a detection limit of 10^(-14)M,and uniform strong response throughout the substrates at 10^(-12)M).展开更多
Zeolite-encapsulated metal nanoclusters are at the heart of bifunctional catalysts,which hold great potential for petrochemical conversion and the emerging sustainable biorefineries.Nevertheless,efficient encapsulatio...Zeolite-encapsulated metal nanoclusters are at the heart of bifunctional catalysts,which hold great potential for petrochemical conversion and the emerging sustainable biorefineries.Nevertheless,efficient encapsulation of metal nanoclusters into a high-silica zeolite Y in particular with good structural integrity still remains a significant challenge.Herein,we have constructed Ru nanoclusters(~1 nm)encapsulated inside a high-silica zeolite Y(SY)with a SiO_(2)/Al_(2)O_(3) ratio(SAR)of 10 via a cooperative strategy for direct zeolite synthesis and a consecutive impregnation for metal encapsulation.Compared with the benchmark Ru/H-USY and other analogues,the as-prepared Ru/H-SY markedly boosts the yields of pentanoic biofuels and stability in the direct hydrodeoxygenation of biomass-derived levulinate even at a mild temperature of 180℃,which are attributed to the notable stabilization of transition states by the enhanced acid accessibility and properly sized constraints of zeolite cavities owing to the good structural integrity.展开更多
A gridded thermionic cathode electron gun was developed for the linear accelerator of the High Energy Photon Source(HEPS).An electron gun should provide a large maximum bunch charge with a wide adjustable range.To sat...A gridded thermionic cathode electron gun was developed for the linear accelerator of the High Energy Photon Source(HEPS).An electron gun should provide a large maximum bunch charge with a wide adjustable range.To satisfy these requirements,the shape of the electrode was optimized using a multi-objective genetic algorithm.A large bunch charge with an adjustable range was achieved using the grid-limited gun,the flow of which was analyzed using 3-D simulations.The electron gun has been manufactured and tested,and the measured data of the grid-limited current and simulation results are compared and discussed in this study.展开更多
Flexible wearable optoelectronic devices fabricated fromorganic–inorganic hybrid perovskites significantly accelerate the developmentof portable energy,biomedicine,and sensing fields,but their poor thermal stabilityh...Flexible wearable optoelectronic devices fabricated fromorganic–inorganic hybrid perovskites significantly accelerate the developmentof portable energy,biomedicine,and sensing fields,but their poor thermal stabilityhinders further applications.Conversely,all-inorganic perovskites possessexcellent thermal stability,but black-phase all-inorganic perovskite filmusually requires high-temperature annealing steps,which increases energy consumptionand is not conducive to the fabrication of flexible wearable devices.In this work,an unprecedented low-temperature fabrication of stable blackphaseCsPbI3perovskite films is demonstrated by the in situ hydrolysis reactionof diphenylphosphinic chloride additive.The released diphenyl phosphateand chloride ions during the hydrolysis reaction significantly lower the phasetransition temperature and effectively passivate the defects in the perovskitefilms,yielding high-performance photodetectors with a responsivity of 42.1 AW−1 and a detectivity of 1.3×10^(14)Jones.Furthermore,high-fidelity imageand photoplethysmography sensors are demonstrated based on the fabricated flexible wearable photodetectors.This work provides a newperspective for the low-temperature fabrication of large-area all-inorganic perovskite flexible optoelectronic devices.展开更多
Thermal quenching(TQ)at elevated temperature is a major factor affecting the luminescent intensity and efficiency of phosphors.Improving the thermal stability of phosphors and weakening the TQ effect are of significan...Thermal quenching(TQ)at elevated temperature is a major factor affecting the luminescent intensity and efficiency of phosphors.Improving the thermal stability of phosphors and weakening the TQ effect are of significance for the high-quality illumination of phosphor-converted WLEDs.Here,a novel red-emitting phosphor K_(2)Zn(PO_(3))_(4)∶Mn^(2+)is synthesized by standard high temperature solid state reaction in ambient atmosphere,which is a new member of self-reduction system.An effective synthesis strategy is proposed to optimize its photoluminescent performances.Combined with X-ray photoelectron spectroscopy and X-ray absorption fine structure spectroscopy,oxygen vacancy defects introduced by Mn doping are proved to play an important role in the transition of Mn^(4+)→Mn^(2+).Thermoluminescence analysis reveals that the distribution of trap levels,especially the deep ones,is effectively regulated by the controllable crystallization and significantly affect the thermal stability of phosphors.Then a defect-assisted model is proposed to address the inner mechanism of the phenomenon.The carriers trapped by deep trap levels can be released under the high-temperature stimulus,which return back to the luminescent centers and participate in the radiative recombination to improve thermal stability.This study provides a new crystallographic idea and theoretical support for obtaining luminescent materials with high thermal stability.展开更多
The rapidity distribution of multiparticle production at the ISR and SppS collider energies are studied,and the data reveal a new empirical scaling behaviour in rapidity distributions in terms of the reduced variable....The rapidity distribution of multiparticle production at the ISR and SppS collider energies are studied,and the data reveal a new empirical scaling behaviour in rapidity distributions in terms of the reduced variable.Some relevant problems on the inclusive distribution of multiparticle productions are discussed.展开更多
The dependence of long range correlation in high energy hadron-hadron collisions on the width of rapidity gap is studied,It is shown that the result from a model with only one particle source does not fit the experime...The dependence of long range correlation in high energy hadron-hadron collisions on the width of rapidity gap is studied,It is shown that the result from a model with only one particle source does not fit the experimental data.In order to get the experimental dependence of long range correlation on the width of rapidity gap at least three particle sources are needed.展开更多
Two 650 MHz single-cell superconducting radio-frequency(SRF)cavities used for the Circular Electron Positron Collider(CEPC)were studied to achieve a high accelerating gradient(E_(acc))and high intrinsic quality factor...Two 650 MHz single-cell superconducting radio-frequency(SRF)cavities used for the Circular Electron Positron Collider(CEPC)were studied to achieve a high accelerating gradient(E_(acc))and high intrinsic quality factor(Q_(0)).The 650 MHz single-cell cavities were subjected to a combination of buffered chemical polishing(BCP)and electropolishing(EP),and their E_(acc) exceeded40 MV/m.Such a high E_(acc) may result from the cold EP with more uniform removal.BCP is easy,cheap,and rough,whereas EP is complicated,expensive,and precise Therefore,the combination of BCP and EP investigated in this study is suitable for surface treatments of mass SRF cavities.Medium temperature(mid-T)furnace baking was also conducted,which demonstrated an ultrahigh Q_(0) of 8×10^(10) at 22 MV/m for both cavities,and an extremely low BCS resistance(R_(BCS))of~1.0 nΩwas achieved a2.0 K.展开更多
To reduce the energy demand and operation cost for circular electron positron collider(CEPC), the high efficiency klystrons are being developed at Institute of High Energy Physics, Chinese Academy of Sciences. A 800-k...To reduce the energy demand and operation cost for circular electron positron collider(CEPC), the high efficiency klystrons are being developed at Institute of High Energy Physics, Chinese Academy of Sciences. A 800-k W continuous wave(CW) klystron operating at frequency of 650-MHz has been designed. The results of beam–wave interaction simulation with several different codes are presented. The efficiency is optimized to be 65% with a second harmonic cavity in three-dimensional(3D) particle-in-cell code CST. The effect of cavity frequency error and mismatch load on efficiency of klystron have been investigated. The design and cold test of reentrant cavities are described, which meet the requirements of RF section design. So far, the manufacturing and high-power test of the first klystron prototype have been completed.When the gun operated at DC voltage of 80 k V and current of 15.4 A, the klystron peak power reached 804 k W with output efficiency of about 65.3% at 40% duty cycle. The 1-d B bandwidth is ±0.8 MHZ. Due to the crack of ceramic window, the CW power achieved about 700 kW. The high-power test results are in good agreement with 3D simulation.展开更多
In recent years,a new generation of storage ring-based light sources,known as diffraction-limited storage rings(DLSRs),whose emittance approaches the diffraction limit for the range of X-ray wavelengths of interest to...In recent years,a new generation of storage ring-based light sources,known as diffraction-limited storage rings(DLSRs),whose emittance approaches the diffraction limit for the range of X-ray wavelengths of interest to the scientific community,has garnered significant attention worldwide.Researchers have begun to design and build DLSRs.Among various DLSR proposals,the hybrid multibend achromat(H-MBA)lattice enables sextupole strengths to be maintained at a reasonable level when minimizing the emittance;hence,it has been adopted in many DLSR designs.Based on the H-7BA lattice,the design of the Advanced Photon Source Upgrade Project(APS-U)can effectively reduce emittance by replacing six quadrupoles with anti-bends.Herein,we discuss the feasibility of designing an APS-U-type H-MBA lattice for the Southern Advanced Photon Source,a mid-energy DLSR light source with ultralow emittance that has been proposed to be built adjacent to the China Spallation Neutron Source.Both linear and nonlinear dynamics are optimized to obtain a detailed design of this type of lattice.The emittance is minimized,while a sufficiently large dynamic aperture(DA)and momentum acceptance(MA)are maintained.A design comprising 36 APS-U type H-7BAs,with an energy of 3 GeV and a circumference of 972 m,is achieved.The horizontal natural emittance is 20 pm·rad,with a horizontal DA of 5.8 mm,a vertical DA of 4.5 mm,and an MA of 4%,as well as a long longitudinal damping time of 120 ms.Subsequently,a few modifications are performed based on the APS-U-type lattice to reduce the maximum value of damping time from 120 to 44 ms while maintaining other performance parameters at the same level.展开更多
The science analysis of the data from the High Energy X-ray Telescope(HE) on the Hard X-ray Modulation Telescope(HXMT) satellite is organized in three stages:calibration,screening and extraction of high-level scientif...The science analysis of the data from the High Energy X-ray Telescope(HE) on the Hard X-ray Modulation Telescope(HXMT) satellite is organized in three stages:calibration,screening and extraction of high-level scientific products.At the first stage,the raw PHA value of each event is converted to PI value accounting for temporal changes in gain and energy offset.At the second stage,the calibrated events are screened by applying cleaning criteria.At the third stage,scientific products,i.e.spectra,light curves and redistribution matrix files,are extracted.This work will introduce the three stages as well as the screening criteria and the data combining method.展开更多
A waterproof nanocrystalline soft magnetic alloy core with a size of O.D.850 mm×I.D.316 mm×H.25 mm for radio frequency acceleration was successfully developed by winding 18μm 1k107b MA ribbons.Theμ'_(p...A waterproof nanocrystalline soft magnetic alloy core with a size of O.D.850 mm×I.D.316 mm×H.25 mm for radio frequency acceleration was successfully developed by winding 18μm 1k107b MA ribbons.Theμ'_(p)Qf products reached 7.5,10,and 12 GHz at 1,3,and 5 MHz,respectively.Theμ'_(p)Qf products of the MA core(O.D.250 mm×I.D.100 mm×H.25 mm)manufactured using a 13μm MA ribbon further increased by 30%.Detailed improvements on the MA core manufacture process are discussed herein.Continuous high-power tests on the new MA cores demonstrated its good performance of waterproofness,particularly its stability of highμ'_(p)Qf products.The MA core with highμ'pQf product and large size can operate under a high average RF power,high electric field,and in deionized water,which will be used in the China Spallation Neutron Source PhaseⅡ(CSNS-Ⅱ).展开更多
A transmission grating coupled with an X-ray charge coupled device （CCD） is used to quantitatively measure the proportion of high-order harmonics of the soft-X-ray source of beam line 4B7B. The results show that the...A transmission grating coupled with an X-ray charge coupled device （CCD） is used to quantitatively measure the proportion of high-order harmonics of the soft-X-ray source of beam line 4B7B. The results show that the monochromatic X-ray has third-order and second-order harmonics. The proportion of second-order harmonic of 4B7B is less than 9.0% and the third- order harmonic is below 0.7% when no suppressing method is applied. When suppression methods are used, the proportion of second-order harmonic is less than 1.7% and the third-order harmonic is ignorable.展开更多
In-situ angle-dispersive x-ray diffraction measurements on three samples of Gr14An84,Gr34An64 and Gr63An34 were performed by using a diamond anvil cell instrument with synchrotron radiation at the Beijing Synchrotron ...In-situ angle-dispersive x-ray diffraction measurements on three samples of Gr14An84,Gr34An64 and Gr63An34 were performed by using a diamond anvil cell instrument with synchrotron radiation at the Beijing Synchrotron Radiation Facility at up to 13.7 GPa.A least−square fit of the pressure-volume to the Birch–Murnaghan equation of state,when fixed K'0=4.0 yields bulk modulus values of K0=166±2,168±3,173±2 GPa for Gr_(14)An_(84),Gr_(34)An_(64 )and Gr_(63)An_(34),respectively.The bulk modulus increases from 166±2 GPa for Gr_(14)An_(84) and to 173±2 GPa for Gr_(63)An_(34) with the increasing An content.Furthermore,by linear interpolation,the bulk modulus of the Gr−An binary system as a function of An content can be expressed as K0(GPa)=176.9(9)−0.12(1)XAn(R^(2)=0.987).展开更多
As a widely used pressure calibrator, the structural phase transitions of bismuth from phase I, to phase II, to phase III,and then to phase V with increasing pressure at 300 K have been widely confirmed. However, ther...As a widely used pressure calibrator, the structural phase transitions of bismuth from phase I, to phase II, to phase III,and then to phase V with increasing pressure at 300 K have been widely confirmed. However, there are different structural versions for phase III, most of which are determined by x-ray diffraction(XRD) technology. Using x-ray absorption fine structure(XAFS) measurements combined with ab initio calculations, we show that the proposed incommensurate composite structure of bismuth of the three configurations is the best option. An abnormal continuous increase of the nearest-neighbor distance of phase III with elevated pressure is also observed. The electronic structure transformation from semimetal to metal is responsible for the complex behavior of structure transformation.展开更多
基金supported in part by the National Natural Science Foundation of China(Nos.12005245,12075100,and 11775244)by the Scientific and Technological Innovation Project(No.2020000165)from the Institute of High Energy Physics,Chinese Academy of Sciences+1 种基金partially funded by the Scientific Instrument Development Project of the Chinese Academy of Sciences(No.ZDKYYQ20200007)Youth Innovation Promotion Association of the Chinese Academy of Sciences(No.Y201905).
文摘There is an urgent need for high-quality and high-frequency clock generators for high-energy physics experiments.The transmission data rate exceeds 10 Gbps for a single channel in future readout electronics of silicon pixel detectors.Others,such as time measurement detectors,require a high time resolution based on the time-to-digital readout architecture.A phase-locked loop(PLL)is an essential and broadly used circuit in these applications.This study presents an application-specific integrated circuit of a low-jitter,low-power LC-tank that is PLL fabricated using 55-nm CMOS technology.It includes a 3rd-order frequency synthesis loop with a programmable bandwidth,a divide-by-2 pre-scaler,standard low-voltage differential signaling interfaces,and a current mode logic(CML)driver for clock transmissions.All the d-flip-flop dividers and phase-frequency detectors are protected from single-event upsets using the triple modular redundancy technique.The proposed VCO uses low-pass filters to suppress the noise from bias circuits.The tested LC-PLL covers a frequency locking range between 4.74 GHz and 5.92 GHz with two sub-bands.The jitter measurements of the frequency-halved clock(2.56 GHz)are less than 460 fs and 0.8 ps for the random and deterministic jitters,respectively,and a total of 7.5 ps peak-to-peak with a bit error rate of 10^(-12).The random and total jitter values for frequencies of 426 MHz and 20 MHz are less than 1.8 ps and 65 ps,respectively.The LC-PLL consumed 27 mW for the core and 73.8 mW in total.The measured results nearly coincided with the simulations and validated the analyses and tests.
基金supported by the National Natural Science Foundation of China(51872115,12234018 and 52101256)Beijing Synchrotron Radiation Facility(BSRF,4B9A)。
文摘Atom-level modulation of the coordination environment for single-atom catalysts(SACs)is considered as an effective strategy for elevating the catalytic performance.For the MNxsite,breaking the symmetrical geometry and charge distribution by introducing relatively weak electronegative atoms into the first/second shell is an efficient way,but it remains challenging for elucidating the underlying mechanism of interaction.Herein,a practical strategy was reported to rationally design single cobalt atoms coordinated with both phosphorus and nitrogen atoms in a hierarchically porous carbon derived from metal-organic frameworks.X-ray absorption spectrum reveals that atomically dispersed Co sites are coordinated with four N atoms in the first shell and varying numbers of P atoms in the second shell(denoted as Co-N/P-C).The prepared catalyst exhibits excellent oxygen reduction reaction(ORR)activity as well as zinc-air battery performance.The introduction of P atoms in the Co-SACs weakens the interaction between Co and N,significantly promoting the adsorption process of ^(*)OOH,resulting in the acceleration of reaction kinetics and reduction of thermodynamic barrier,responsible for the increased intrinsic activity.Our discovery provides insights into an ultimate design of single-atom catalysts with adjustable electrocatalytic activities for efficient electrochemical energy conversion.
基金This work was supported by the National Key Research and Development Program(Nos.2022YFB3503600 and 2021YFA0718500)Strategic Priority Research Program of the Chinese Academy of Sciences(Nos.XDA15360102)National Natural Science Foundation of China(Nos.12273042 and 12075258).
文摘The GECAM series of satellites utilizes LaBr_(3)(Ce),LaBr_(3)(Ce,Sr),and NaI(Tl)crystals as sensitive materials for gamma-ray detectors(GRDs).To investigate the nonlinearity in the detection of low-energy gamma rays and address the errors in the calibration of the E-C relationship,comprehensive tests and comparative studies of the three aforementioned crystals were conducted using Compton electrons,radioactive sources,and mono-energetic X-rays.The nonlinearity test results of the Compton electrons and X-rays demonstrated substantial differences,with all three crystals presenting a higher nonlinearity for X/-rays than for Compton electrons.Despite the LaBr_(3)(Ce)and LaBr_(3)(Ce,Sr)crystals having higher absolute light yields,they exhibited a noticeable nonlinear decrease in the light yield,especially at energies below 400 keV.The NaI(Tl)crystal demonstrated an"excess"light output in the 6-200 keV range,reaching a maximum"excess"of 9.2%at 30 keV in the X-ray testing and up to 15.5%at 14 keV during Compton electron testing,indicating a significant advantage in the detection of low-energy gamma rays.Furthermore,we explored the underlying causes of the observed nonlinearity in these crystals.This study not only elucidates the detector responses of GECAM,but also initiates a comprehensive investigation of the nonlinearity of domestically produced lanthanum bromide and sodium iodide crystals.
基金financially National Natural Science Foundation of China (22288102, 22172134, U1932201, U2032202)Science and Technology Planning Project of Fujian Province (2022H0002)support from the EPSRC (EP/W03784X/1)。
文摘The efficacy of the oxygen reduction reaction(ORR) in fuel cells can be significantly enhanced by optimizing cobalt-based catalysts,which provide a more stable alternative to iron-based catalysts.However,their performance is often impeded by weak adsorption of oxygen species,leading to a 2e^(-)pathway that negatively affects fuel cell discharge efficiency.Here,we engineered a high-density cobalt active center catalyst,coordinated with nitrogen and sulfur atoms on a porous carbon substrate.Both experimental and theoretical analyses highlighted the role of sulfur atoms as electron donors,disrupting the charge symmetry of the original Co active center and promoting enhanced interaction with Co 3d orbitals.This modification improves the adsorption of oxygen and reaction intermediates during ORR,significantly reducing the production of hydrogen peroxide(H_(2)O_(2)).Remarkably,the optimized catalyst demonstrated superior fuel cell performance,with peak power densities of 1.32 W cm^(-2) in oxygen and 0.61 W cm^(-2) in air environments,respectively.A significant decrease in H_(2)O_(2) by-product accumulation was observed during the reaction process,reducing catalyst and membrane damage and consequently improving fuel cell durability.This study emphasizes the critical role of coordination symmetry in Co/N/C catalysts and proposes an effective strategy to enhance fuel cell performance.
基金supported by the Guangdong Basic and Applied Basic Research Foundation(No.2023A1515030074)the National Natural Science Foundation of China(No.12035017)。
文摘Neutron-sensitive microchannel plates(nMCPs)have applications in neutron detection,including energy spectrum measurements,neutron-induced cross sections,and neutron imaging.10B-doped MCPs(B-MCPs)have attracted significant attention owing to their potential for exhibiting a high neutron detection efficiency over a large neutron energy range.Good spatial and temporal resolutions are useful for neutron energy-resolved imaging.However,their practical applications still face many technical challenges.In this study,a B-MCP with 10 mol%10B was tested for its response to wide-energy neutrons from eV to MeV at the Back-n white neutron source at the China Spallation Neutron Source.The neutron detection efficiency was calibrated at 1 eV,which is approximately 300 times that of an ordinary MCP and indicates the success of 10 B doping.The factors that caused the reduction in the detection efficiency were simulated and discussed.The neutron energy spectrum obtained using B-MCP was compared with that obtained by other measurement methods,and showed very good consistency for neutron energies below tens of keV.The response is more complicated at higher neutron energy,at which point the elastic and nonelastic reactions of all nuclides of B-MCP gradually become dominant.This is beneficial for the detection of neutrons,as it compensates for the detection efficiency of B-MCP for high-energy neutrons.
基金supported by Shenzhen-Hong Kong Science and Technology Innovation Cooperation Zone Shenzhen Park (Project HZQBKCZYB-2020030)National Key R&D Program of China (Project 2017YFA0204403)+2 种基金the National Natural Science Foundation of China (Project 51590892)the Major Program of Changsha Science and Technology (Project kh2003023)the Innovation and Technology Commission of HKSAR through Hong Kong Branch of National Precious Metals Material Engineering Research Centre,and the City University of Hong Kong (Project 9667207)。
文摘Surface-enhanced Raman Spectroscopy(SERS)is a nondestructive technique for rapid detection of analytes even at the single-molecule level.However,highly sensitive and reliable SERS substrates are mostly fabricated with complex nanofabrication techniques,greatly restricting their practical applications.A convenient electrochemical method for transforming the surface of commercial gold wires/foils into silver-alloyed nanostructures is demonstrated in this report.Au substrates are treated with repetitive anodic and cathodic bias in an electrolyte of thiourea,in a one-pot one-step manner.X-rays absorption fine structure(XAFS)spectroscopy confirms that the AuAg alloy is induced at the surface.The unique AuAg alloyed surface nanostructures are particularly advantageous when served as SERS substrates,enabling a remarkably sensitive detection of Rhodamine B(a detection limit of 10^(-14)M,and uniform strong response throughout the substrates at 10^(-12)M).
基金supported by the National Natural Science Foundation of China (22288101,21991090,21991091,22078316,22272171 and 22109167)the Sino-French International Research Network (Zeolites)+2 种基金the BL01B1 beamline of SPring-8 and the 1W1B station of Beijing Synchrotron Radiation Facility (BSRF)for the support of XAS measurementsthe Division of Energy Research Resources of Dalian Institute of Chemical Physics for the support of iDPC-STEM measurementsthe support of the Alexander von Humboldt Foundation (CHN 1220532 HFST-P)。
文摘Zeolite-encapsulated metal nanoclusters are at the heart of bifunctional catalysts,which hold great potential for petrochemical conversion and the emerging sustainable biorefineries.Nevertheless,efficient encapsulation of metal nanoclusters into a high-silica zeolite Y in particular with good structural integrity still remains a significant challenge.Herein,we have constructed Ru nanoclusters(~1 nm)encapsulated inside a high-silica zeolite Y(SY)with a SiO_(2)/Al_(2)O_(3) ratio(SAR)of 10 via a cooperative strategy for direct zeolite synthesis and a consecutive impregnation for metal encapsulation.Compared with the benchmark Ru/H-USY and other analogues,the as-prepared Ru/H-SY markedly boosts the yields of pentanoic biofuels and stability in the direct hydrodeoxygenation of biomass-derived levulinate even at a mild temperature of 180℃,which are attributed to the notable stabilization of transition states by the enhanced acid accessibility and properly sized constraints of zeolite cavities owing to the good structural integrity.
文摘A gridded thermionic cathode electron gun was developed for the linear accelerator of the High Energy Photon Source(HEPS).An electron gun should provide a large maximum bunch charge with a wide adjustable range.To satisfy these requirements,the shape of the electrode was optimized using a multi-objective genetic algorithm.A large bunch charge with an adjustable range was achieved using the grid-limited gun,the flow of which was analyzed using 3-D simulations.The electron gun has been manufactured and tested,and the measured data of the grid-limited current and simulation results are compared and discussed in this study.
基金supported by the National Natural Science Foundation of China(52303257,52321006,T2394480,and T2394484)the National Key R&D Program of China(Grant No.2023YFE0111500)+3 种基金Key Research&Development and Promotion of Special Project(Scientific Problem Tackling)of Henan Province(242102211090)the China Postdoctoral Science Foundation(2023TQ0300,and 2023M743171)the Postdoctoral Fellowship Program(Grade B)of China Postdoctoral Science Foundation(GZB20230666)College Student Innovation and Entrepreneurship Training Program of Zhengzhou University(202410459200)。
文摘Flexible wearable optoelectronic devices fabricated fromorganic–inorganic hybrid perovskites significantly accelerate the developmentof portable energy,biomedicine,and sensing fields,but their poor thermal stabilityhinders further applications.Conversely,all-inorganic perovskites possessexcellent thermal stability,but black-phase all-inorganic perovskite filmusually requires high-temperature annealing steps,which increases energy consumptionand is not conducive to the fabrication of flexible wearable devices.In this work,an unprecedented low-temperature fabrication of stable blackphaseCsPbI3perovskite films is demonstrated by the in situ hydrolysis reactionof diphenylphosphinic chloride additive.The released diphenyl phosphateand chloride ions during the hydrolysis reaction significantly lower the phasetransition temperature and effectively passivate the defects in the perovskitefilms,yielding high-performance photodetectors with a responsivity of 42.1 AW−1 and a detectivity of 1.3×10^(14)Jones.Furthermore,high-fidelity imageand photoplethysmography sensors are demonstrated based on the fabricated flexible wearable photodetectors.This work provides a newperspective for the low-temperature fabrication of large-area all-inorganic perovskite flexible optoelectronic devices.
文摘Thermal quenching(TQ)at elevated temperature is a major factor affecting the luminescent intensity and efficiency of phosphors.Improving the thermal stability of phosphors and weakening the TQ effect are of significance for the high-quality illumination of phosphor-converted WLEDs.Here,a novel red-emitting phosphor K_(2)Zn(PO_(3))_(4)∶Mn^(2+)is synthesized by standard high temperature solid state reaction in ambient atmosphere,which is a new member of self-reduction system.An effective synthesis strategy is proposed to optimize its photoluminescent performances.Combined with X-ray photoelectron spectroscopy and X-ray absorption fine structure spectroscopy,oxygen vacancy defects introduced by Mn doping are proved to play an important role in the transition of Mn^(4+)→Mn^(2+).Thermoluminescence analysis reveals that the distribution of trap levels,especially the deep ones,is effectively regulated by the controllable crystallization and significantly affect the thermal stability of phosphors.Then a defect-assisted model is proposed to address the inner mechanism of the phenomenon.The carriers trapped by deep trap levels can be released under the high-temperature stimulus,which return back to the luminescent centers and participate in the radiative recombination to improve thermal stability.This study provides a new crystallographic idea and theoretical support for obtaining luminescent materials with high thermal stability.
文摘The rapidity distribution of multiparticle production at the ISR and SppS collider energies are studied,and the data reveal a new empirical scaling behaviour in rapidity distributions in terms of the reduced variable.Some relevant problems on the inclusive distribution of multiparticle productions are discussed.
基金Supported in part by the National Natural Science Foundation of China.
文摘The dependence of long range correlation in high energy hadron-hadron collisions on the width of rapidity gap is studied,It is shown that the result from a model with only one particle source does not fit the experimental data.In order to get the experimental dependence of long range correlation on the width of rapidity gap at least three particle sources are needed.
基金supported by the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDB25000000)the National Natural Science Foundation of China(No.12075270)the Platform of Advanced Photon Source Technology R&D。
文摘Two 650 MHz single-cell superconducting radio-frequency(SRF)cavities used for the Circular Electron Positron Collider(CEPC)were studied to achieve a high accelerating gradient(E_(acc))and high intrinsic quality factor(Q_(0)).The 650 MHz single-cell cavities were subjected to a combination of buffered chemical polishing(BCP)and electropolishing(EP),and their E_(acc) exceeded40 MV/m.Such a high E_(acc) may result from the cold EP with more uniform removal.BCP is easy,cheap,and rough,whereas EP is complicated,expensive,and precise Therefore,the combination of BCP and EP investigated in this study is suitable for surface treatments of mass SRF cavities.Medium temperature(mid-T)furnace baking was also conducted,which demonstrated an ultrahigh Q_(0) of 8×10^(10) at 22 MV/m for both cavities,and an extremely low BCS resistance(R_(BCS))of~1.0 nΩwas achieved a2.0 K.
基金Project supported by Yifang Wang’s Science Studio of the Ten Thousand Talents Project。
文摘To reduce the energy demand and operation cost for circular electron positron collider(CEPC), the high efficiency klystrons are being developed at Institute of High Energy Physics, Chinese Academy of Sciences. A 800-k W continuous wave(CW) klystron operating at frequency of 650-MHz has been designed. The results of beam–wave interaction simulation with several different codes are presented. The efficiency is optimized to be 65% with a second harmonic cavity in three-dimensional(3D) particle-in-cell code CST. The effect of cavity frequency error and mismatch load on efficiency of klystron have been investigated. The design and cold test of reentrant cavities are described, which meet the requirements of RF section design. So far, the manufacturing and high-power test of the first klystron prototype have been completed.When the gun operated at DC voltage of 80 k V and current of 15.4 A, the klystron peak power reached 804 k W with output efficiency of about 65.3% at 40% duty cycle. The 1-d B bandwidth is ±0.8 MHZ. Due to the crack of ceramic window, the CW power achieved about 700 kW. The high-power test results are in good agreement with 3D simulation.
基金This work was supported by the National Natural Science Foundation of China(No.11922512)the Youth Innovation Promotion Association of Chinese Academy of Sciences(No.Y201904)the Guangdong Basic and Applied Basic Research Foundation—Guangdong Dongguan Joint Foundation(No.2019B1515120069).
文摘In recent years,a new generation of storage ring-based light sources,known as diffraction-limited storage rings(DLSRs),whose emittance approaches the diffraction limit for the range of X-ray wavelengths of interest to the scientific community,has garnered significant attention worldwide.Researchers have begun to design and build DLSRs.Among various DLSR proposals,the hybrid multibend achromat(H-MBA)lattice enables sextupole strengths to be maintained at a reasonable level when minimizing the emittance;hence,it has been adopted in many DLSR designs.Based on the H-7BA lattice,the design of the Advanced Photon Source Upgrade Project(APS-U)can effectively reduce emittance by replacing six quadrupoles with anti-bends.Herein,we discuss the feasibility of designing an APS-U-type H-MBA lattice for the Southern Advanced Photon Source,a mid-energy DLSR light source with ultralow emittance that has been proposed to be built adjacent to the China Spallation Neutron Source.Both linear and nonlinear dynamics are optimized to obtain a detailed design of this type of lattice.The emittance is minimized,while a sufficiently large dynamic aperture(DA)and momentum acceptance(MA)are maintained.A design comprising 36 APS-U type H-7BAs,with an energy of 3 GeV and a circumference of 972 m,is achieved.The horizontal natural emittance is 20 pm·rad,with a horizontal DA of 5.8 mm,a vertical DA of 4.5 mm,and an MA of 4%,as well as a long longitudinal damping time of 120 ms.Subsequently,a few modifications are performed based on the APS-U-type lattice to reduce the maximum value of damping time from 120 to 44 ms while maintaining other performance parameters at the same level.
基金Supported by the National Natural Science Foundation of China(11303027,11503029)the Strategic Priority Research Program on Space Science of the Chinese Academy of Sciences(XDA04010300)
文摘The science analysis of the data from the High Energy X-ray Telescope(HE) on the Hard X-ray Modulation Telescope(HXMT) satellite is organized in three stages:calibration,screening and extraction of high-level scientific products.At the first stage,the raw PHA value of each event is converted to PI value accounting for temporal changes in gain and energy offset.At the second stage,the calibrated events are screened by applying cleaning criteria.At the third stage,scientific products,i.e.spectra,light curves and redistribution matrix files,are extracted.This work will introduce the three stages as well as the screening criteria and the data combining method.
基金supported by the funds of the National Natural Science Foundation of China (Nos. 11175194, 11875270, and U1832210)Youth Innovation Promotion Association CAS (No. 2018015)Guangdong Basic and Applied Basic Research Foundation (No.2019B1515120046)
文摘A waterproof nanocrystalline soft magnetic alloy core with a size of O.D.850 mm×I.D.316 mm×H.25 mm for radio frequency acceleration was successfully developed by winding 18μm 1k107b MA ribbons.Theμ'_(p)Qf products reached 7.5,10,and 12 GHz at 1,3,and 5 MHz,respectively.Theμ'_(p)Qf products of the MA core(O.D.250 mm×I.D.100 mm×H.25 mm)manufactured using a 13μm MA ribbon further increased by 30%.Detailed improvements on the MA core manufacture process are discussed herein.Continuous high-power tests on the new MA cores demonstrated its good performance of waterproofness,particularly its stability of highμ'_(p)Qf products.The MA core with highμ'pQf product and large size can operate under a high average RF power,high electric field,and in deionized water,which will be used in the China Spallation Neutron Source PhaseⅡ(CSNS-Ⅱ).
文摘A transmission grating coupled with an X-ray charge coupled device （CCD） is used to quantitatively measure the proportion of high-order harmonics of the soft-X-ray source of beam line 4B7B. The results show that the monochromatic X-ray has third-order and second-order harmonics. The proportion of second-order harmonic of 4B7B is less than 9.0% and the third- order harmonic is below 0.7% when no suppressing method is applied. When suppression methods are used, the proportion of second-order harmonic is less than 1.7% and the third-order harmonic is ignorable.
基金by the Founds for Huge Scientific Equipment of the National Natural Science Foundation of China and Chinese Academy of Sciences under Grant No 10979053the National Natural Science Foundation of China under Grant Nos 41004035 and 40873052+2 种基金the Guizhou Foundation for Science and Technology under Grant No[2010]2231The experiment was performed at the 4W2 High Pressure Station,Beijing Synchrotron Radiation Facility(BSRF)The High Pressure Station is supported by the Chinese Academy of Sciences under Grant Nos KJCX2-SW-N20 and KJCX2-SW-N03.
文摘In-situ angle-dispersive x-ray diffraction measurements on three samples of Gr14An84,Gr34An64 and Gr63An34 were performed by using a diamond anvil cell instrument with synchrotron radiation at the Beijing Synchrotron Radiation Facility at up to 13.7 GPa.A least−square fit of the pressure-volume to the Birch–Murnaghan equation of state,when fixed K'0=4.0 yields bulk modulus values of K0=166±2,168±3,173±2 GPa for Gr_(14)An_(84),Gr_(34)An_(64 )and Gr_(63)An_(34),respectively.The bulk modulus increases from 166±2 GPa for Gr_(14)An_(84) and to 173±2 GPa for Gr_(63)An_(34) with the increasing An content.Furthermore,by linear interpolation,the bulk modulus of the Gr−An binary system as a function of An content can be expressed as K0(GPa)=176.9(9)−0.12(1)XAn(R^(2)=0.987).
基金supported by the National Natural Science Foundation of China(Grant Nos.10904133,11304294,11274281,11404006,and U1230201)the Development Foundation of China Academy of Engineering Physics(Grant Nos.2015B0101004,2013B0401062,and 2012A0101001)the Research Foundation of the Laboratory of Shock Wave and Detonation,China(Grant No.9140C670201140C67282)
文摘As a widely used pressure calibrator, the structural phase transitions of bismuth from phase I, to phase II, to phase III,and then to phase V with increasing pressure at 300 K have been widely confirmed. However, there are different structural versions for phase III, most of which are determined by x-ray diffraction(XRD) technology. Using x-ray absorption fine structure(XAFS) measurements combined with ab initio calculations, we show that the proposed incommensurate composite structure of bismuth of the three configurations is the best option. An abnormal continuous increase of the nearest-neighbor distance of phase III with elevated pressure is also observed. The electronic structure transformation from semimetal to metal is responsible for the complex behavior of structure transformation.
