The far-field microdynamic disturbance caused by the excavation of deep mineral resources and underground engineering can induce surrounding rock damage in high-stress conditions and even lead to disasters.However,the...The far-field microdynamic disturbance caused by the excavation of deep mineral resources and underground engineering can induce surrounding rock damage in high-stress conditions and even lead to disasters.However,the mechanical properties and damage/fracture evolution mechanisms of deep rock induced by microdynamic disturbance under three-dimensional stress states are unclear.Therefore,a true triaxial multilevel disturbance test method is proposed,which can completely simulate natural geostress,excavation stress redistribution(such as stress unloading,concentration and rotation),and subsequently the microdynamic disturbance triggering damaged rock failure.Based on a dynamic true triaxial test platform,true triaxial microdynamic disturbance tests under different frequency and amplitudes were carried out on monzogabbro.The results show that increasing amplitude or decreasing frequency diminishes the failure strength of monzogabbro.Deformation modulus gradually decreases during disturbance failure.As frequency and amplitude increase,the degradation rate of deformation modulus decreases slightly,disturbance dissipated energy increases significantly,and disturbance deformation anisotropy strengthens obviously.A damage model has been proposed to quantitatively characterize the disturbance-induced damage evolution at different frequency and amplitude under true triaxial stress.Before disturbance failure,the micro-tensile crack mechanism is dominant,and the micro-shear crack mechanism increases significantly at failure.With the increase of amplitude and frequency,the micro-shear crack mechanism increases.When approaching disturbance failure,the acoustic emission fractal dimension changes from a stable value to local large oscillation,and finally increases sharply to a high value at failure.Finally,the disturbance-induced failure mechanism of surrounding rock in deep engineering is clearly elucidated.展开更多
This study aims to elucidate the dynamic evolution mechanism of the fracturing fracture system during the exploration and development of complex oil and gas reservoirs.By integrating methods of rock mechanical testing...This study aims to elucidate the dynamic evolution mechanism of the fracturing fracture system during the exploration and development of complex oil and gas reservoirs.By integrating methods of rock mechanical testing,logging calculation,and seismic inversion technology,we obtained the current insitu stress characteristics of a single well and rock mechanical parameters.Simultaneously,significant controlling factors of rock mechanical properties were analyzed.Subsequently,by coupling hydraulic fracturing physical experiments with finite element numerical simulation,three different fracturing models were configured:single-cluster,double-cluster,and triple-cluster perforations.Combined with acoustic emission technology,the fracture initiation mode and evolution characteristics during the loading process were determined.The results indicate the following findings:(1)The extension direction and length of the fracture are significantly controlled by the direction of the maximum horizontal principal stress.(2)Areas with poor cementation and compactness exhibit complex fracture morphology,prone to generating network fractures.(3)The interlayer development of fracturing fractures is controlled by the strata occurrence.(4)Increasing the displacement of fracturing fluid enlarges the fracturing fracture length and height.This research provides theoretical support and effective guidance for hydraulic fracturing design in tight oil and gas reservoirs.展开更多
Transition metal chalcogenides(TMCs)are recognized as pre-catalysts,and their(oxy)hydroxides derived from electrochemical reconstruction are the active species in the water oxidation.However,understanding the role of ...Transition metal chalcogenides(TMCs)are recognized as pre-catalysts,and their(oxy)hydroxides derived from electrochemical reconstruction are the active species in the water oxidation.However,understanding the role of the residual chalcogen in the reconstructed layer is lacking in detail,and the corresponding catalytic mechanism remains controversial.Here,taking Cu_(1-x)Co_(x)S as a platform,we explore the regulating effect and existence form of the residual S doped into the reconstructive layer for oxygen evolution reaction(OER),where a dual-path OER mechanism is proposed.First-principles calculations and operando~(18)O isotopic labeling experiments jointly reveal that the residual S in the reconstructive layer of Cu_(1-x)Co_(x)S can wisely balance the adsorbate evolution mechanism(AEM)and lattice oxygen oxidation mechanism(LOM)by activating lattice oxygen and optimizing the adsorption/desorption behaviors at metal active sites,rather than change the reaction mechanism from AEM to LOM.Following such a dual-path OER mechanism,Cu_(0.4)Co_(0.6)S-derived Cu_(0.4)Co_(0.6)OSH not only overcomes the restriction of linear scaling relationship in AEM,but also avoids the structural collapse caused by lattice oxygen migration in LOM,so as to greatly reduce the OER potential and improved stability.展开更多
The time-dependence evolution of the extinction spectra of the silver nanoplates is studied to analyze the underlying physical mechanism of the growth process. As the synthesis cycles increase, the wavelength of the a...The time-dependence evolution of the extinction spectra of the silver nanoplates is studied to analyze the underlying physical mechanism of the growth process. As the synthesis cycles increase, the wavelength of the absorption peak is first blue-shifted and then is followed by the red shift, attributing to the mode alteration of the longitudinal surface plasmon resonance of the silver nanoplates. The capping agents are also optimized for the convenient and speedy growth of the large integrated Ag nanostructure. These observations expand the comprehensive understanding of plasmon resonance of the Ag nanoplates, and give a better manipulation of their applications in the plasmonie nanodevices.展开更多
According to the distribution of abutment stress in a stope,this research established the mechanical model of mining abutment pressure transmission in floor base on the theory of semi-infnite plate body in elasticity....According to the distribution of abutment stress in a stope,this research established the mechanical model of mining abutment pressure transmission in floor base on the theory of semi-infnite plate body in elasticity.This study takes the 762 working face of Haizi Coal Mine as a case in point,and analyzed the dynamic evolution law of seam floor stress during the mining process.With an organic combination of the mining floor stress and surrounding rock stress,the study obtained the change laws of the maximum principle stress and the minimum one for the floor roadway surrounding rock when mining the upper working face.Considering the non-constant pressure force state and the cracks revolution mechanisms of floor roadway surrounding rock,the research built the mechanical model of roadway stress.Simulation results verify the reliability of the above conclusions.Moreover,this model could provide the theoretical basis and technical support for controlling floor roadway surrounding rock.展开更多
Thermal runaway(TR)of lithium-ion(Li-ion)batteries(LIBs)involves multiple forms of hazards,such as gas venting/jetting,fire,or even explosion.Explosion,as the most extreme case,is caused by the generated flammable gas...Thermal runaway(TR)of lithium-ion(Li-ion)batteries(LIBs)involves multiple forms of hazards,such as gas venting/jetting,fire,or even explosion.Explosion,as the most extreme case,is caused by the generated flammable gases,and a deflagration to detonation transition(DDT)may occur in this process.Here,overheat-to-TR tests and the corresponding outgas-induced explosion tests were conducted on 42 Ah Li-ion cells with Li[Ni_(1/3)Co_(1/3)Mn_(1/3)]O2cathode.The sum of CO_(2),H_(2),C_(2)H_(4),CO,and CH4accounted for more than 90%of the gases.Lower/upper explosion limits(LEL/UEL),laminar flame speed,and ideal stable detonation pressure were calculated to interpret the explosion characteristics and boundary.It turned out that shockwave was easily to be compressed and accelerated under higher state of charge(SOC)conditions.Thus,Li-ion cells explosion may evolve into unstable detonation in encapsulated battery pack and its evolution mechanism was explained,which provides a new idea for explosion-proof design of LIBs system.Additionally,a comprehensive assessment method was developed to intuitively characterize TR hazards.Severity of explosion presented an upward trend with the increase of SOC while the sensitivity was not the same.This study provides a further anatomy of TR,which is instructive to the safety of power battery systems.展开更多
In order to investigate the effect of water content on the energy evolution of red sandstone, the axial loading–unloading experiments on dry and water-saturated sandstone samples were conducted, and the distribution ...In order to investigate the effect of water content on the energy evolution of red sandstone, the axial loading–unloading experiments on dry and water-saturated sandstone samples were conducted, and the distribution and evolution of elastic energy and dissipated energy within the rock were measured.The results show that the saturation process from dry to fully-saturated states reduces the strength, rigidity and brittleness of the rock by 30.2%, 25.5% and 16.7%, respectively. The water-saturated sample has larger irreversible deformation in the pre-peak stage and smaller stress drop in the post-peak stage.The saturation process decreases the accumulation energy limit by 38.9%, but increases the dissipated energy and residual elastic energy density, thus greatly reducing the magnitude and rate of energy release. The water-saturated sample has lower conversion efficiency to elastic energy by 3% in the prepeak region; moreover, the elastic energy ratio falls with a smaller range in the post-peak stage.Therefore, saturation process can greatly reduce the risk of dynamic disaster, and heterogeneous water content can lead to dynamic disaster possibly on the other hand.展开更多
To study the mechanical and damage evolution properties of sandstone under triaxial compression, we analyzed the stress strain curve characteristics, deformation and strength properties, and failure process and charac...To study the mechanical and damage evolution properties of sandstone under triaxial compression, we analyzed the stress strain curve characteristics, deformation and strength properties, and failure process and characteristics of sandstone samples under different stress states. The experimental results reveal that peak strength, residual strength, elasticity modulus and deformation modulus increase linearly with confining pressure, and failure models transform from fragile failure under low confining pressure to ductility failure under high confining pressure. Macroscopic failure forms of samples under uniaxial compression were split failure parallel to the axis of samples, while macroscopic failure forms under uniaxial compression were shear failure, the shear failure angle of which decreased linearly with confin- ing pressure. There were significant volume dilatation properties in the loading process of sandstone under different confining pressures, and we analyzed the damage evolution properties of samples based on acoustic emission damage and volumetric dilatation damage, and established damage constitutive model, realizing the real-time Quantitative evaluation of samnles damage state in loading process.展开更多
基金the financial support from the National Natural Science Foundation of China(No.52109119)the Guangxi Natural Science Foundation(No.2021GXNSFBA075030)+2 种基金the Guangxi Science and Technology Project(No.Guike AD20325002)the Chinese Postdoctoral Science Fund Project(No.2022M723408)the Open Research Fund of State Key Laboratory of Simulation and Regulation of Water Cycle in River Basin(China Institute of Water Resources and Hydropower Research)(No.IWHR-SKL-202202)。
文摘The far-field microdynamic disturbance caused by the excavation of deep mineral resources and underground engineering can induce surrounding rock damage in high-stress conditions and even lead to disasters.However,the mechanical properties and damage/fracture evolution mechanisms of deep rock induced by microdynamic disturbance under three-dimensional stress states are unclear.Therefore,a true triaxial multilevel disturbance test method is proposed,which can completely simulate natural geostress,excavation stress redistribution(such as stress unloading,concentration and rotation),and subsequently the microdynamic disturbance triggering damaged rock failure.Based on a dynamic true triaxial test platform,true triaxial microdynamic disturbance tests under different frequency and amplitudes were carried out on monzogabbro.The results show that increasing amplitude or decreasing frequency diminishes the failure strength of monzogabbro.Deformation modulus gradually decreases during disturbance failure.As frequency and amplitude increase,the degradation rate of deformation modulus decreases slightly,disturbance dissipated energy increases significantly,and disturbance deformation anisotropy strengthens obviously.A damage model has been proposed to quantitatively characterize the disturbance-induced damage evolution at different frequency and amplitude under true triaxial stress.Before disturbance failure,the micro-tensile crack mechanism is dominant,and the micro-shear crack mechanism increases significantly at failure.With the increase of amplitude and frequency,the micro-shear crack mechanism increases.When approaching disturbance failure,the acoustic emission fractal dimension changes from a stable value to local large oscillation,and finally increases sharply to a high value at failure.Finally,the disturbance-induced failure mechanism of surrounding rock in deep engineering is clearly elucidated.
基金supported by the Major Scientific and Technological Projects of CNPC under grant ZD2019-183-006the National Science and Technology Major Project of China(2016ZX05014002-006)the National Natural Science Foundation of China(42072234)。
文摘This study aims to elucidate the dynamic evolution mechanism of the fracturing fracture system during the exploration and development of complex oil and gas reservoirs.By integrating methods of rock mechanical testing,logging calculation,and seismic inversion technology,we obtained the current insitu stress characteristics of a single well and rock mechanical parameters.Simultaneously,significant controlling factors of rock mechanical properties were analyzed.Subsequently,by coupling hydraulic fracturing physical experiments with finite element numerical simulation,three different fracturing models were configured:single-cluster,double-cluster,and triple-cluster perforations.Combined with acoustic emission technology,the fracture initiation mode and evolution characteristics during the loading process were determined.The results indicate the following findings:(1)The extension direction and length of the fracture are significantly controlled by the direction of the maximum horizontal principal stress.(2)Areas with poor cementation and compactness exhibit complex fracture morphology,prone to generating network fractures.(3)The interlayer development of fracturing fractures is controlled by the strata occurrence.(4)Increasing the displacement of fracturing fluid enlarges the fracturing fracture length and height.This research provides theoretical support and effective guidance for hydraulic fracturing design in tight oil and gas reservoirs.
基金supported by the Science and Technology Research Program of Chongqing Municipal Education Commission(KJQN202200550)the Natural Science Foundation Joint Fund for Innovation and Development of Chongqing Municipal Education Commission(CSTB2022NSCQ-LZX0077)+4 种基金the National Natural Science Foundation of China(No.52100065)the Science and Technology Research Program of Natural Science Foundation of Chongqing(cstc2021ycjh-bgzxm0037)the Science and Technology Research Program of Chongqing Municipal Education Commission(KJZD-M202200503)the Chongqing Innovation Research Group Project(No.CXQT21015)the Doctor Start/Talent Introduction Program of Chongqing Normal University(No.02060404/2020009000321)。
文摘Transition metal chalcogenides(TMCs)are recognized as pre-catalysts,and their(oxy)hydroxides derived from electrochemical reconstruction are the active species in the water oxidation.However,understanding the role of the residual chalcogen in the reconstructed layer is lacking in detail,and the corresponding catalytic mechanism remains controversial.Here,taking Cu_(1-x)Co_(x)S as a platform,we explore the regulating effect and existence form of the residual S doped into the reconstructive layer for oxygen evolution reaction(OER),where a dual-path OER mechanism is proposed.First-principles calculations and operando~(18)O isotopic labeling experiments jointly reveal that the residual S in the reconstructive layer of Cu_(1-x)Co_(x)S can wisely balance the adsorbate evolution mechanism(AEM)and lattice oxygen oxidation mechanism(LOM)by activating lattice oxygen and optimizing the adsorption/desorption behaviors at metal active sites,rather than change the reaction mechanism from AEM to LOM.Following such a dual-path OER mechanism,Cu_(0.4)Co_(0.6)S-derived Cu_(0.4)Co_(0.6)OSH not only overcomes the restriction of linear scaling relationship in AEM,but also avoids the structural collapse caused by lattice oxygen migration in LOM,so as to greatly reduce the OER potential and improved stability.
基金Supported by the Natural Science Foundation of Hubei Province under Grant No 2014CFB554
文摘The time-dependence evolution of the extinction spectra of the silver nanoplates is studied to analyze the underlying physical mechanism of the growth process. As the synthesis cycles increase, the wavelength of the absorption peak is first blue-shifted and then is followed by the red shift, attributing to the mode alteration of the longitudinal surface plasmon resonance of the silver nanoplates. The capping agents are also optimized for the convenient and speedy growth of the large integrated Ag nanostructure. These observations expand the comprehensive understanding of plasmon resonance of the Ag nanoplates, and give a better manipulation of their applications in the plasmonie nanodevices.
基金supported by the National Natural Science Foundation of China(No.51074004)the Open Project of State Key Laboratory Breeding Base for Mining Disaster Prevention and Control of Shandong University of Science and Technology of China(No.MDPC2012KF06)+1 种基金the Natural Science Foundation of Anhui Province of China(No.11040606M102)Young Teachers Science Foundation of Anhui University of Science&Technology of China(No.2012QNZ14)
文摘According to the distribution of abutment stress in a stope,this research established the mechanical model of mining abutment pressure transmission in floor base on the theory of semi-infnite plate body in elasticity.This study takes the 762 working face of Haizi Coal Mine as a case in point,and analyzed the dynamic evolution law of seam floor stress during the mining process.With an organic combination of the mining floor stress and surrounding rock stress,the study obtained the change laws of the maximum principle stress and the minimum one for the floor roadway surrounding rock when mining the upper working face.Considering the non-constant pressure force state and the cracks revolution mechanisms of floor roadway surrounding rock,the research built the mechanical model of roadway stress.Simulation results verify the reliability of the above conclusions.Moreover,this model could provide the theoretical basis and technical support for controlling floor roadway surrounding rock.
基金sponsored by the China Postdoctoral Science Foundation(China National Postdoctoral Program for Innovative Talents,BX20210362022M710383)the National Natural Science Foundation of China(52072040,U21A20170)。
文摘Thermal runaway(TR)of lithium-ion(Li-ion)batteries(LIBs)involves multiple forms of hazards,such as gas venting/jetting,fire,or even explosion.Explosion,as the most extreme case,is caused by the generated flammable gases,and a deflagration to detonation transition(DDT)may occur in this process.Here,overheat-to-TR tests and the corresponding outgas-induced explosion tests were conducted on 42 Ah Li-ion cells with Li[Ni_(1/3)Co_(1/3)Mn_(1/3)]O2cathode.The sum of CO_(2),H_(2),C_(2)H_(4),CO,and CH4accounted for more than 90%of the gases.Lower/upper explosion limits(LEL/UEL),laminar flame speed,and ideal stable detonation pressure were calculated to interpret the explosion characteristics and boundary.It turned out that shockwave was easily to be compressed and accelerated under higher state of charge(SOC)conditions.Thus,Li-ion cells explosion may evolve into unstable detonation in encapsulated battery pack and its evolution mechanism was explained,which provides a new idea for explosion-proof design of LIBs system.Additionally,a comprehensive assessment method was developed to intuitively characterize TR hazards.Severity of explosion presented an upward trend with the increase of SOC while the sensitivity was not the same.This study provides a further anatomy of TR,which is instructive to the safety of power battery systems.
基金provided by the Fundamental Research Funds for the Central Universities(No.2014QNA80)the Project funded by China Postdoctoral Science Foundation(No.2014M550315)+2 种基金a Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutionsthe National Natural Science Foundation of China(No.11202108)the Natural Science Foundation of Jiangsu Province(No.BK20140189)
文摘In order to investigate the effect of water content on the energy evolution of red sandstone, the axial loading–unloading experiments on dry and water-saturated sandstone samples were conducted, and the distribution and evolution of elastic energy and dissipated energy within the rock were measured.The results show that the saturation process from dry to fully-saturated states reduces the strength, rigidity and brittleness of the rock by 30.2%, 25.5% and 16.7%, respectively. The water-saturated sample has larger irreversible deformation in the pre-peak stage and smaller stress drop in the post-peak stage.The saturation process decreases the accumulation energy limit by 38.9%, but increases the dissipated energy and residual elastic energy density, thus greatly reducing the magnitude and rate of energy release. The water-saturated sample has lower conversion efficiency to elastic energy by 3% in the prepeak region; moreover, the elastic energy ratio falls with a smaller range in the post-peak stage.Therefore, saturation process can greatly reduce the risk of dynamic disaster, and heterogeneous water content can lead to dynamic disaster possibly on the other hand.
基金the National Natural Science Foundation of China (Nos.51323004 and 51574223)the Postdoctoral Science Foundation of China (No.2015M571842)the Open Research Fund of Research Center of Jiangsu Collaborative Innovation Center for Building Energy Saving and Construction Technology (No.SJXTY1502)
文摘To study the mechanical and damage evolution properties of sandstone under triaxial compression, we analyzed the stress strain curve characteristics, deformation and strength properties, and failure process and characteristics of sandstone samples under different stress states. The experimental results reveal that peak strength, residual strength, elasticity modulus and deformation modulus increase linearly with confining pressure, and failure models transform from fragile failure under low confining pressure to ductility failure under high confining pressure. Macroscopic failure forms of samples under uniaxial compression were split failure parallel to the axis of samples, while macroscopic failure forms under uniaxial compression were shear failure, the shear failure angle of which decreased linearly with confin- ing pressure. There were significant volume dilatation properties in the loading process of sandstone under different confining pressures, and we analyzed the damage evolution properties of samples based on acoustic emission damage and volumetric dilatation damage, and established damage constitutive model, realizing the real-time Quantitative evaluation of samnles damage state in loading process.
