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Dual‑Donor‑Induced Crystallinity Modulation Enables 19.23% Efficiency Organic Solar Cells
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作者 Anhai Liang Yuqing Sun +9 位作者 Sein Chung Jiyeong Shin Kangbo Sun Chaofeng Zhu Jingjing Zhao Zhenmin Zhao Yufei Zhong Guangye Zhang Kilwon Cho Zhipeng Kan 《Nano-Micro Letters》 SCIE EI CAS 2025年第3期376-388,共13页
Trap-assisted charge recombination is one of the primary limitationsof restricting the performance of organic solar cells. However, effectivelyreducing the presence of traps in the photoactive layer remains challengin... Trap-assisted charge recombination is one of the primary limitationsof restricting the performance of organic solar cells. However, effectivelyreducing the presence of traps in the photoactive layer remains challenging.Herein, wide bandgap polymer donor PTzBI-dF is demonstrated as an effectivemodulator for enhancing the crystallinity of the bulk heterojunction active layerscomposed of D18 derivatives blended with Y6, leading to dense and orderedmolecular packings, and thus, improves photoluminescence quenching properties.As a result, the photovoltaic devices exhibit reduced trap-assisted charge recombinationlosses, achieving an optimized power conversion efficiency of over 19%.Besides the efficiency enhancement, the devices comprised of PTzBI-dF as athird component simultaneously attain decreased current leakage, improved chargecarrier mobilities, and suppressed bimolecular charge recombination, leading toreduced energy losses. The advanced crystalline structures induced by PTzBI-dFand its characteristics, such as well-aligned energy level, and complementaryabsorption spectra, are ascribed to the promising performance improvements.Our findings suggest that donor phase engineering is a feasible approach to tuning the molecular packings in the active layer, providingguidelines for designing effective morphology modulators for high-performance organic solar cells. 展开更多
关键词 Trap-assisted charge recombination PHOTOLUMINESCENCE MISCIBILITY Current leakage Power conversion efficiency
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Quantitative Description of the Effects of Sweep Efficiency and Displacement Efficiency during Chemical Flooding on a Heterogeneous Reservoir 被引量:6
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作者 沈平平 袁士义 +2 位作者 邓宝荣 宋杰 沈奎友 《Petroleum Science》 SCIE CAS CSCD 2004年第3期41-48,77,共9页
The processes of flooding—water flooding, polymer flooding and ternary combination flooding—were simulated respectively on a 2-D positive rhythm profile geological model by using the ASP numerical modeling softw... The processes of flooding—water flooding, polymer flooding and ternary combination flooding—were simulated respectively on a 2-D positive rhythm profile geological model by using the ASP numerical modeling software developed by RIPED (Yuan, et al. 1995). The recovery coefficient, remaining oil saturation, sweep efficiency and displacement efficiency were calculated and correlated layer by layer. The results show that the sweep efficiency and displacement efficiency work different effects on different layers in the severely heterogeneous reservoir. The study shows that the displacement efficiency and sweep efficiency play different roles in different layers for severely heterogeneous reservoirs. The displacement efficiency contributes mainly to the high permeability zones, the sweep efficiency to the low permeability zones, both of which contribute to the middle permeable zones. To improve the sweep efficiency in the low permeability zones is of significance for enhancing the whole recovery of the reservoir. It is an important path for improving the effectiveness of chemical flooding in the severely heterogeneous reservoirs to inject ternary combination slug after profile control. 展开更多
关键词 Chemical flooding displacement efficiency sweep efficiency recovery efficiency heterogenous reservoir
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Understanding Bridging Sites and Accelerating Quantum Efficiency for Photocatalytic CO_(2) Reduction 被引量:2
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作者 Kangwang Wang Zhuofeng Hu +8 位作者 Peifeng Yu Alina M.Balu Kuan Li Longfu Li Lingyong Zeng Chao Zhang Rafael Luque Kai Yan Huixia Luo 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第1期68-84,共17页
We report a novel double-shelled nanoboxes photocatalyst architecture with tailored interfaces that accelerate quantum efficiency for photocatalytic CO_(2) reduction reaction(CO_(2)RR)via Mo–S bridging bonds sites in... We report a novel double-shelled nanoboxes photocatalyst architecture with tailored interfaces that accelerate quantum efficiency for photocatalytic CO_(2) reduction reaction(CO_(2)RR)via Mo–S bridging bonds sites in S_(v)–In_(2)S_(3)@2H–MoTe_(2).The X-ray absorption near-edge structure shows that the formation of S_(v)–In_(2)S_(3)@2H–MoTe_(2) adjusts the coordination environment via interface engineering and forms Mo–S polarized sites at the interface.The interfacial dynamics and catalytic behavior are clearly revealed by ultrafast femtosecond transient absorption,time-resolved,and in situ diffuse reflectance–Infrared Fourier transform spectroscopy.A tunable electronic structure through steric interaction of Mo–S bridging bonds induces a 1.7-fold enhancement in S_(v)–In_(2)S_(3)@2H–MoTe_(2)(5)photogenerated carrier concentration relative to pristine S_(v)–In_(2)S_(3).Benefiting from lower carrier transport activation energy,an internal quantum efficiency of 94.01%at 380 nm was used for photocatalytic CO_(2)RR.This study proposes a new strategy to design photocatalyst through bridging sites to adjust the selectivity of photocatalytic CO_(2)RR. 展开更多
关键词 Quantum efficiency Electronic structure Steric interaction Bridging sites CO_(2)reduction
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Elucidating the enhancement of kaolinite flotation by iron content through density functional theory: A study on sodium oleate adsorption efficiency 被引量:1
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作者 Lingyun Liu Chuilei Kong +1 位作者 Hongyu Zhao Fangqin Lu 《International Journal of Mining Science and Technology》 SCIE EI CAS CSCD 2024年第6期855-866,共12页
This study delves into the intricate relationship between iron(Fe)content in kaolinite and its impact on the adsorption behavior of sodium oleate.The effects of different iron concentrations on adsorption energy,hydro... This study delves into the intricate relationship between iron(Fe)content in kaolinite and its impact on the adsorption behavior of sodium oleate.The effects of different iron concentrations on adsorption energy,hydrogen bond kinetics and adsorption efficiency were studied through simulation and experimental verification.The results show that the presence of iron in the kaolinite structure significantly improves the adsorption capacity of sodium oleate.Kaolinite samples with high iron content have better adsorption properties,lower adsorption energy levels and shorter and stronger hydrogen bonds than pure kaolinite.The optimal concentration of oleic acid ions for achieving maximum adsorption efficiency was identified as 1.2 mmol/L across different kaolinite samples.At this concentration,the adsorption rates and capacities reach their peak,with Fe-enriched kaolinite samples exhibiting notably higher flotation recovery rates.This optimal concentration represents a balance between sufficient oleic acid ion availability for surface interactions and the prevention of self-aggregation phenomena that could hinder adsorption.This study offers promising avenues for optimizing the flotation process in mineral processing applications. 展开更多
关键词 Iron Influence Sodium Oleate Adsorption Kaolinite Surfaces Molecular Interaction Analysis Flotation efficiency Optimization
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Energy Efficiency Maximization for Cooperative NOMA with Hardware Impairments 被引量:1
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作者 Wang Zhengqiang Chang Ruifei +2 位作者 Wan Xiaoyu Fan Zifu Duo Bin 《China Communications》 SCIE CSCD 2024年第12期80-91,共12页
The massive connectivity and limited energy pose significant challenges to deploy the enormous devices in energy-efficient and environmentally friendly in the Internet of Things(IoT).Motivated by these challenges,this... The massive connectivity and limited energy pose significant challenges to deploy the enormous devices in energy-efficient and environmentally friendly in the Internet of Things(IoT).Motivated by these challenges,this paper investigates the energy efficiency(EE)maximization problem for downlink cooperative non-orthogonal multiple access(C-NOMA)systems with hardware impairments(HIs).The base station(BS)communicates with several users via a half-duplex(HD)amplified-and-forward(AF)relay.First,we formulate the EE maximization problem of the system under HIs by jointly optimizing transmit power and power allocated coefficient(PAC)at BS,and transmit power at the relay.The original EE maximization problem is a non-convex problem,which is challenging to give the optimal solution directly.First,we use fractional programming to convert the EE maximization problem as a series of subtraction form subproblems.Then,variable substitution and block coordinate descent(BCD)method are used to handle the sub-problems.Next,a resource allocation algorithm is proposed to maximize the EE of the systems.Finally,simulation results show that the proposed algorithm outperforms the downlink cooperative orthogonal multiple access(C-OMA)scheme. 展开更多
关键词 block coordinate descent cooperative non-orthogonal multiple access energy efficiency hardware impairments resource allocation
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Research on a TOPSIS energy efficiency evaluation system for crude oil gathering and transportation systems based on a GA-BP neural network 被引量:1
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作者 Xue-Qiang Zhang Qing-Lin Cheng +2 位作者 Wei Sun Yi Zhao Zhi-Min Li 《Petroleum Science》 SCIE EI CAS CSCD 2024年第1期621-640,共20页
As the main link of ground engineering,crude oil gathering and transportation systems require huge energy consumption and complex structures.It is necessary to establish an energy efficiency evaluation system for crud... As the main link of ground engineering,crude oil gathering and transportation systems require huge energy consumption and complex structures.It is necessary to establish an energy efficiency evaluation system for crude oil gathering and transportation systems and identify the energy efficiency gaps.In this paper,the energy efficiency evaluation system of the crude oil gathering and transportation system in an oilfield in western China is established.Combined with the big data analysis method,the GA-BP neural network is used to establish the energy efficiency index prediction model for crude oil gathering and transportation systems.The comprehensive energy consumption,gas consumption,power consumption,energy utilization rate,heat utilization rate,and power utilization rate of crude oil gathering and transportation systems are predicted.Considering the efficiency and unit consumption index of the crude oil gathering and transportation system,the energy efficiency evaluation system of the crude oil gathering and transportation system is established based on a game theory combined weighting method and TOPSIS evaluation method,and the subjective weight is determined by the triangular fuzzy analytic hierarchy process.The entropy weight method determines the objective weight,and the combined weight of game theory combines subjectivity with objectivity to comprehensively evaluate the comprehensive energy efficiency of crude oil gathering and transportation systems and their subsystems.Finally,the weak links in energy utilization are identified,and energy conservation and consumption reduction are improved.The above research provides technical support for the green,efficient and intelligent development of crude oil gathering and transportation systems. 展开更多
关键词 Crude oil gathering and transportation system GA-BP neural network Energy efficiency evaluation TOPSIS evaluation method Energy saving and consumption reduction
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Machine learning optimization strategy of shaped charge liner structure based on jet penetration efficiency
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作者 Ziqi Zhao Tong Li +6 位作者 Donglin Sheng Jian Chen Amin Yan Yan Chen Haiying Wang Xiaowei Chen Lanhong Dai 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第9期23-41,共19页
Shaped charge liner(SCL)has been extensively applied in oil recovery and defense industries.Achieving superior penetration capability through optimizing SCL structures presents a substantial challenge due to intricate... Shaped charge liner(SCL)has been extensively applied in oil recovery and defense industries.Achieving superior penetration capability through optimizing SCL structures presents a substantial challenge due to intricate rate-dependent processes involving detonation-driven liner collapse,high-speed jet stretching,and penetration.This study introduces an innovative optimization strategy for SCL structures that employs jet penetration efficiency as the primary objective function.The strategy combines experimentally validated finite element method with machine learning(FEM-ML).We propose a novel jet penetration efficiency index derived from enhanced cutoff velocity and shape characteristics of the jet via machine learning.This index effectively evaluates the jet penetration performance.Furthermore,a multi-model fusion based on a machine learning optimization method,called XGBOOST-MFO,is put forward to optimize SCL structure over a large input space.The strategy's feasibility is demonstrated through the optimization of copper SCL implemented via the FEM-ML strategy.Finally,this strategy is extended to optimize the structure of the recently emerging CrMnFeCoNi high-entropy alloy conical liners and hemispherical copper liners.Therefore,the strategy can provide helpful guidance for the engineering design of SCL. 展开更多
关键词 Jet penetration efficiency Shaped charge liner FEM-ML XGBOOST MFO High-entropy alloy
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Effects of thinning and understory removal on water use efficiency of Pinus massoniana:evidence from photosynthetic capacity and stable carbon isotope analyses
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作者 Ting Wang Qing Xu +4 位作者 Beibei Zhang Deqiang Gao Ying Zhang Jing Jiang Haijun Zuo 《Journal of Forestry Research》 SCIE EI CAS CSCD 2024年第2期42-53,共12页
Understanding the relationship between forest management and water use efficiency(WUE)is important for evaluating forest adaptability to climate change.However,the effects of thinning and understory removal on WUE and... Understanding the relationship between forest management and water use efficiency(WUE)is important for evaluating forest adaptability to climate change.However,the effects of thinning and understory removal on WUE and its key controlling processes are not well understood,which limits our comprehension of the physiological mechanisms of various management practices.In this study,four forest management measures(no thinning:NT;understory removal:UR;light thinning:LT;and heavy thinning:HT)were carried out in Pinus massoniana plantations in a subtropical region of China.Photosynthetic capacity and needle stable carbon isotope composition(δ^(13)C)were measured to assess instantaneous water use efficiency(WUE_(inst))and long-term water use efficiency(WUE_(i)).Multiple regression models and structural equation modelling(SEM)identified the effects of soil properties and physiological performances on WUE_(inst)and WUE_(i).The results show that WUE_(inst)values among the four treatments were insignificant.However,compared with the NT stand(35.8μmol·mol^(-1)),WUE_(i)values significantly increased to 41.7μmol·mol^(-1)in the UR,50.1μmol·mol^(-1)in the LT and 46.6μmol·mol^(-1)in HT treatments,largely explained by photosynthetic capacity and soil water content.Understory removal did not change physiological performance(needle water potential and photosynthetic capacity).Thinning increased the net photosynthetic rate(A_n)but not stomatal conductance(g_s)or predawn needle water potential(ψ_(pd)),implying that the improvement in water use efficiency for thinned stands was largely driven by radiation interception than by soil water availability.In general,thinning may be an appropriate management measure to promote P.massoniana WUE to cope with seasonal droughts under future extreme climates. 展开更多
关键词 Stable carbon isotope Water use efficiency THINNING Understory removal Photosynthetic capacity Needle water potential
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Multifunctional interfacial molecular bridge enabled by an aggregation-induced emission strategy for enhancing efficiency and UV stability of perovskite solar cells
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作者 Shuhang Bian Yuqi Wang +13 位作者 Fancong Zeng Zhongqi Liu Bin Liu Yanjie Wu Long Shao Yongzhi Shao Huan Zhang Shuainan Liu Jin Liang Xue Bai Lin Xu Donglei Zhou Biao Dong Hongwei Song 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第8期588-595,I0013,共9页
The interface defects between the electron transport layer(ETL)and the perovskite layer,as well as the low ultraviolet(UV)light utilization rate of the perovskite absorption layer,pose significant challenges for the c... The interface defects between the electron transport layer(ETL)and the perovskite layer,as well as the low ultraviolet(UV)light utilization rate of the perovskite absorption layer,pose significant challenges for the commercialization of perovskite solar cells(PSCs).To address this issue,this paper proposes an innovative multifunctional interface modulation strategy by introducing aggregation-induced emission(AIE)molecule 5-[4-[1,2,2-tri[4-(3,5-dicarboxyphenyl)phenyl]ethylene]phenyl]benzene-1,3-dicarboxylic acid(H_(8)ETTB)at the SnO_(2)ETL/perovskite interface.Firstly,the interaction of H_(8)ETTB with the SnO_(2)surface,facilitated by its carboxyl groups,is effective in passivating surface defects caused by noncoord inated Sn and O vacancies.This interaction enhances the conductivity of the SnO_(2)film and adjusts energy levels,leading to enhanced charge carrier transport.Simultaneously,H_(8)ETTB can passivate noncoord inated Pb^(2+)ions at the perovskite interface,promoting perovskite crystallization and reducing the interface energy barrier,resulting in a perovskite film with low defects and high crystalline quality.More importantly,the H_(8)ETTB molecule,can convert UV light into light absorbable by the perovskite,thereby reducing damage caused by UV light and improving the device's utilization of UV.Consequently,the champion PSC based on SnO_(2)-H_(8)ETTB achieves an impressing efficiency of 23.32%and significantly improved photostability compared with the control device after continuous exposure to intense UV radiation.In addition,the Cs_(0.05)(FA_(0.95)MA_(0.05))_(0.95)Pb(I_(0.95)Br_(0.05))_(3)based device can achieve maximum efficiency of 24.01%,demonstrating the effectiveness and universality of this strategy.Overall,this innovative interface bridging strategy effectively tackles interface defects and low UV light utilization in PSCs,presenting a promising approach for achieving highly efficient and stable PSCs. 展开更多
关键词 Perovskite solar cells Aggregation-induced emission Defect passivation efficiency UV stability
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Enhancing the crystallinity and stability of perovskite solar cells with 4-tert-butylpyridine induction for efficiency exceeding 24%
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作者 You Liu Lishuang Zheng +15 位作者 Kuanxiang Zhang Kun Xu Weicheng Xie Jue Zhang Yulu Tian Tianyuan Liu Hanzhong Xu Ruoming Ma Wei Huang Jiahui Chen Jusheng Bao Chen Chen Yongsheng Zhou Xuchun Wang Junming Chen Jungan Wang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第6期1-7,I0001,共8页
Perovskite solar cells(PSCs)have emerged as a promising photovoltaic technology because of their high light absorption coefficient,long carrier diffusion distance,and tunable bandgap.However,PSCs face challenges such ... Perovskite solar cells(PSCs)have emerged as a promising photovoltaic technology because of their high light absorption coefficient,long carrier diffusion distance,and tunable bandgap.However,PSCs face challenges such as hysteresis effects and stability issues.In this study,we introduced a novel approach to improve film crystallization by leveraging 4-tert-butylpyridine(TBP)molecules,thereby enhancing the performance and stability of PSCs.Our findings demonstrate the effective removal of PbI_(2)from the perovskite surface through strong coordination with TBP molecules.Additionally,by carefully adjusting the concentration of the TBP solution,we achieved enhanced film crystallinity without disrupting the perovskite structure.The TBP-treated perovskite films exhibit a low defect density,improved crystallinity,and improved carrier lifetime.As a result,the PSCs manufactured with TBP treatment achieve power conversion efficiency(PCE)exceeding 24%.Moreover,we obtained the PCE of 21.39%for the 12.25 cm^(2)module. 展开更多
关键词 4-tert-butylpyridine Film crystallization Perovskite solar cells Power conversion efficiency Stability improvement
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The impact of industrial transformation on green economic efficiency:New evidence based on energy use
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作者 Jin-Xing Jiang Jing-Jing Wang Yu Cheng 《Petroleum Science》 SCIE EI CAS CSCD 2024年第5期3644-3655,共12页
Developing a green economy is key to achieving the 2030 Sustainable Development Goals. This paper uses the SBM-GML index, which includes non-desired outputs, to measure the trend of regional green economic efficiency ... Developing a green economy is key to achieving the 2030 Sustainable Development Goals. This paper uses the SBM-GML index, which includes non-desired outputs, to measure the trend of regional green economic efficiency changes and analyze the impact mechanism and realization path of industrial transformation on green economic efficiency. The research results show that advanced industrial structure has a positive influence on green economic efficiency nationwide, while energy utilization structure and energy utilization efficiency have positive partial intermediary effects in the influence path;industrial structure rationalization is also significantly positively related to green economic efficiency nationwide, and the mediating effect of energy utilization is positive. The impact of industrial transformation on green economic efficiency has regional heterogeneity, and the mediating effect of energy use also differs. Among them, the impact effect in the eastern region is basically consistent with the national sample, but is negative in the central and western regions. This paper proposes countermeasures in terms of adjusting the industrial structure, improving energy efficiency, and perfecting industrial and energy policies, which can provide theoretical and practical references for promoting the transformation and upgrading of regional industrial structure, optimizing energy utilization, and advancing the efficiency of the national and regional green economy. 展开更多
关键词 Industrial transformation Energy use Green economic efficiency The SBM-GML model Mediating effect model
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Effect of antioxidants on the efficiency of jet milling and the powder characteristics of Sm2Co17 permanent magnets
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作者 Da-Shuai Xu Lei Liu +6 位作者 Jian-Hui Yuan Bo Zhou Chuang-Hui Dong Feng-Qing Wang Yong Ding Ying-Li Sun A-Ru Yan 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第9期615-620,共6页
This study investigated the effect of antioxidants on the grinding efficiency,magnetic powder characteristics,microstructure,and magnetic properties of 2:17 type SmCo permanent magnet materials.The results show that a... This study investigated the effect of antioxidants on the grinding efficiency,magnetic powder characteristics,microstructure,and magnetic properties of 2:17 type SmCo permanent magnet materials.The results show that adding antioxidants helps improve the dispersion among magnetic powders,leading to a 33.3%decrease in jet milling time and a 15.8%increase in magnet powder production yield.Additionally,adding antioxidants enhances the oxidation resistance of the magnetic powders.After being stored in a constant temperature air environment at 25C for 48 h,the O content in the powder decreased by 33%compared to samples without antioxidants.While in the magnet body,the O content decreased from 0.21 wt.%to 0.14 wt.%,which helps increase the effective Sm content and domain wall pinning uniformity in the magnet.Excellent magnetic properties were obtained in the magnet with added antioxidants:B_(r)=11.6 kGs,SF=79.6%,H_(cj)=16.8 kOe,and(BH)_(max)=32.5 MGOe. 展开更多
关键词 ANTIOXIDANT SmCo permanent magnet oxidation resistance grinding efficiency
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Reheat effect on the improvement in efficiency of the turbine driven by pulse detonation
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作者 Junyu Liu Zhiwu Wang +3 位作者 Zixu Zhang Junlin Li Weifeng Qin Jingjing Huang 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第1期200-210,共11页
Due to the strong unsteadiness of pulse detonation,large flow losses are generated when the detonation wave interacts with the turbine blades,resulting in low turbine efficiency.Considering that the flow losses are di... Due to the strong unsteadiness of pulse detonation,large flow losses are generated when the detonation wave interacts with the turbine blades,resulting in low turbine efficiency.Considering that the flow losses are dissipated into the gas as heat energy,some of them can be recycled during the expansion process in subsequent stages by the reheat effect,which should be helpful to improve the detonationdriven turbine efficiency.Taking this into account,this paper developed a numerical model of the detonation chamber coupled with a two-stage axial turbine,and a stoichiometric hydrogen-air mixture was used.The improvement in turbine efficiency attributable to the reheat effect was calculated by comparing the average efficiency of the stages with the efficiency of the two-stage turbine.The research indicated that the first stage was critical in suppressing the flow unsteadiness caused by pulse detonation,which stabilized the intake condition of the second stage and consequently allowed much of the flow losses from the first stage to be recycled,so that the efficiency of the two-stage turbine was improved.At a 95%confidence level,the efficiency improvement was stable at 4.5%—5.3%,demonstrating that the reheat effect is significant in improving the efficiency of the detonation-driven turbine. 展开更多
关键词 Pulse detonation turbine engine Hydrogen detonation Turbine efficiency Reheat effect Multi-cycle detonation
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Enhancing efficiency and stability of organic solar cells through a simplified four-step synthesis of fully non-fused ring electron acceptor
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作者 Chenyang Han Huanhuan Gao +7 位作者 Yanna Sun Yuanyuan Kan Zhaozhao Bi Wei Ma Yani Zhang Juan Antonio Zapien Yingguo Yang Ke Gao 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第6期601-608,I0015,共9页
Design and synthesis of superior cost-effective non-fullerene acceptors(NFAs)are still big challenges for facilitating the commercialization of organic solar cells(OSCs),yet to be realized.Herein,two medium bandgap fu... Design and synthesis of superior cost-effective non-fullerene acceptors(NFAs)are still big challenges for facilitating the commercialization of organic solar cells(OSCs),yet to be realized.Herein,two medium bandgap fully non-fused ring electron acceptors(NFREAs,medium bandgap,i,e.,1,3-1,8 eV),namely PTR-2Cl and PTR-4Cl are synthesized with only four steps by using intramolecular noncovalent interaction central core,structured alkyl side chain orientation linking units and flanking with different electron-withdrawing end group.Among them,PTR-4C1 exhibits increased average electrostatic potential(ESP)difference with polymer donor,enhanced crystallinity and compactπ-πstacking compared with the control molecule PTR-2CI.As a result,the PTR-4Cl-based OSC achieved an impressive power conversion efficiency(PCE)of 14.72%,with a much higher open-circuit voltage(V_(OC))of 0.953 V and significantly improved fill factor(FF)of 0.758,demonstrating one of the best acceptor material in the top-performing fully NFREA-based OSCs with both high PCE and V_(OC).Notably,PTR-4Cl-based cells maintain a good T_80lifetime of its initial PCE after over 936 h under a continuous thermal annealing treatment and over1300 h T_(80)lifetime without encapsulation.This work provides a cost-effective design strategy for NFREAs on obtaining high V_(OC),efficient exciton dissociation,and ordered molecular packing and thus high-efficiency and stable OSCs. 展开更多
关键词 Organic solar cells Fully non-fused ring acceptors End group engineering Morphology regulation High efficiency
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A hierarchical salt-rejection strategy for sustainable and high-efficiency solar-driven desalination
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作者 Zhengyi Mao Xuliang Chen +7 位作者 Yingxian Chen Junda Shen Jianpan Huang Yuhan Chen Xiaoguang Duan Yicheng Han Kannie Wai Yan Chan Jian LU 《Nano Materials Science》 EI CAS CSCD 2024年第1期38-43,共6页
Solar steam generation(SSG)is widely regarded as one of the most sustainable technologies for seawater desalination.However,salt fouling severely compromises the evaporation performance and lifetime of evaporators,lim... Solar steam generation(SSG)is widely regarded as one of the most sustainable technologies for seawater desalination.However,salt fouling severely compromises the evaporation performance and lifetime of evaporators,limiting their practical applications.Herein,we propose a hierarchical salt-rejection(HSR)strategy to prevent salt precipitation during long-term evaporation while maintaining a rapid evaporation rate,even in high-salinity brine.The salt diffusion process is segmented into three steps—insulation,branching diffusion,and arterial transport—that significantly enhance the salt-resistance properties of the evaporator.Moreover,the HSR strategy overcomes the tradeoff between salt resistance and evaporation rate.Consequently,a high evaporation rate of 2.84 kg m^(-2) h^(-1),stable evaporation for 7 days cyclic tests in 20 wt%NaCl solution,and continuous operation for 170 h in natural seawater under 1 sun illumination were achieved.Compared with control evaporators,the HSR evaporator exhibited a>54%enhancement in total water evaporation mass during 24 h continuous evaporation in 20 wt%salt water.Furthermore,a water collection device equipped with the HSR evaporator realized a high water purification rate(1.1 kg m^(-2) h^(-1)),highlighting its potential for agricultural applications. 展开更多
关键词 Solar water evaporation 3D printing Salt-rejection Hierarchical structures High efficiency
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Optimizing the power conversion processes in diluted donor/acceptor heterojunctions towards 19.4%efficiency all-polymer solar cells
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作者 Liang Wang Chen Chen +11 位作者 Zirui Gan Chenhao Liu Chuanhang Guo Weiyi Xia Wei Sun Jingchao Cheng Yuandong Sun Jing Zhou Zexin Chen Dan Liu Wei Li Tao Wang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第9期345-350,共6页
All polymer solar cells(all-PSCs)promise mechanically-flexible and morphologically-stable organic photovoltaics and have aroused increased interests very recently.However,due to their disorderly conformation structure... All polymer solar cells(all-PSCs)promise mechanically-flexible and morphologically-stable organic photovoltaics and have aroused increased interests very recently.However,due to their disorderly conformation structures within the photoactive film,inefficient charge generation and carrier transport are observed which lead to inferior photovoltaic performance compared to smaller molecular acceptor-based photovoltaics.Here,by diluting PM6 with a cutting-edge polymeric acceptor PY-IT and diluting PY-IT with PM6 or D18,donor-dominating or acceptor-dominating heterojunctions were prepared.Synchrotron X-ray and multiple spectrometer techniques reveal that the diluted heterojunctions receive increased structural order,translating to enhanced carrier mobility,improved exciton diffusion length,and suppressed non-radiative recombination loss during the power conversion.As the results,the corresponding PM6+1%PY-IT/PY-IT+1%D18 and PM6+1%PY-IT/PY-IT+1%PM6 devices fabricated by layer-by-layer deposition received superior power conversion efficiency(PCE)of 19.4%and 18.8%respectively,along with enhanced operational lifetimes in air,outperforming the PCE of 17.5%in the PM6/PY-IT reference device. 展开更多
关键词 All-polymer solar cells Power conversion efficiency Structural order Charge generation
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Cooperative activation of sodium channels for downgrading the energy efficiency in neuronal information processing
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作者 严浩然 颜家琦 +1 位作者 俞连春 邵玉峰 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第5期758-763,共6页
The Hodgkin–Huxley model assumes independent ion channel activation,although mutual interactions are common in biological systems.This raises the problem why neurons would favor independent over cooperative channel a... The Hodgkin–Huxley model assumes independent ion channel activation,although mutual interactions are common in biological systems.This raises the problem why neurons would favor independent over cooperative channel activation.In this study,we evaluate how cooperative activation of sodium channels affects the neuron’s information processing and energy consumption.Simulations of the stochastic Hodgkin–Huxley model with cooperative activation of sodium channels show that,while cooperative activation enhances neuronal information processing capacity,it greatly increases the neuron’s energy consumption.As a result,cooperative activation of sodium channel degrades the energy efficiency for neuronal information processing.This discovery improves our understanding of the design principles for neural systems,and may provide insights into future designs of the neuromorphic computing devices as well as systematic understanding of pathological mechanisms for neural diseases. 展开更多
关键词 energy efficiency ion channel noise action potential generation neuronal dynamics
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Power transfer efficiency in an air-breathing radio frequency ion thruster
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作者 黄高煌 李宏 +1 位作者 高飞 王友年 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第7期430-438,共9页
Due to a series of challenges such as low-orbit maintenance of satellites, the air-breathing electric propulsion has got widespread attention. Commonly, the radio frequency ion thruster is favored by low-orbit mission... Due to a series of challenges such as low-orbit maintenance of satellites, the air-breathing electric propulsion has got widespread attention. Commonly, the radio frequency ion thruster is favored by low-orbit missions due to its high specific impulse and efficiency. In this paper, the power transfer efficiency of the radio frequency ion thruster with different gas compositions is studied experimentally, which is obtained by measuring the radio frequency power and current of the antenna coil with and without discharge operation. The results show that increasing the turns of antenna coils can effectively improve the radio frequency power transfer efficiency, which is due to the improvement of Q factor. In pure N_2 discharge,with the increase of radio frequency power, the radio frequency power transfer efficiency first rises rapidly and then exhibits a less steep increasing trend. The radio frequency power transfer efficiency increases with the increase of gas pressure at relatively high power, while declines rapidly at relatively low power. In N_(2)/O_(2) discharge, increasing the N_(2) content at high power can improve the radio frequency power transfer efficiency, but the opposite was observed at low power. In order to give a better understanding of these trends, an analytic solution in limit cases is utilized, and a Langmuir probe was employed to measure the electron density. It is found that the evolution of radio frequency power transfer efficiency can be well explained by the variation of plasma resistance, which is related to the electron density and the effective electron collision frequency. 展开更多
关键词 radio frequency ion thruster inductively coupled plasma power transfer efficiency analytic solution
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Secure Computation Efficiency Resource Allocation for Massive MIMO-Enabled Mobile Edge Computing Networks
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作者 Sun Gangcan Sun Jiwei +3 位作者 Hao Wanming Zhu Zhengyu Ji Xiang Zhou Yiqing 《China Communications》 SCIE CSCD 2024年第11期150-162,共13页
In this article,the secure computation efficiency(SCE)problem is studied in a massive multipleinput multiple-output(mMIMO)-assisted mobile edge computing(MEC)network.We first derive the secure transmission rate based ... In this article,the secure computation efficiency(SCE)problem is studied in a massive multipleinput multiple-output(mMIMO)-assisted mobile edge computing(MEC)network.We first derive the secure transmission rate based on the mMIMO under imperfect channel state information.Based on this,the SCE maximization problem is formulated by jointly optimizing the local computation frequency,the offloading time,the downloading time,the users and the base station transmit power.Due to its difficulty to directly solve the formulated problem,we first transform the fractional objective function into the subtractive form one via the dinkelbach method.Next,the original problem is transformed into a convex one by applying the successive convex approximation technique,and an iteration algorithm is proposed to obtain the solutions.Finally,the stimulations are conducted to show that the performance of the proposed schemes is superior to that of the other schemes. 展开更多
关键词 EAVESDROPPING massive multiple input multiple output mobile edge computing partial offloading secure computation efficiency
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High Energy Efficiency Dynamic Connected Hybrid Precoding for mm Wave Massive MIMO Systems
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作者 Du Ruiyan Liu Huajing +1 位作者 Li Tiangui Liu Fulai 《China Communications》 SCIE CSCD 2024年第5期36-44,共9页
This paper considers a high energy efficiency dynamic connected(HEDC)structure,which promotes the practicability and reduces the power consumption of hybrid precoding system by lowresolution phase shifters(PSs).Based ... This paper considers a high energy efficiency dynamic connected(HEDC)structure,which promotes the practicability and reduces the power consumption of hybrid precoding system by lowresolution phase shifters(PSs).Based on the proposed structure,a new hybrid precoding algorithm is presented to optimize the energy efficiency,namely,HP-HEDC algorithm.Firstly,via a new defined effective optimal precoding matrix,the problem of optimizing the analog switch precoding matrix is formulated as a sparse representation problem.Thus,the optimal analog switch precoding matrix can be readily obtained by the branch-and-bound method.Then,the digital precoding matrix optimization problem is modeled as a dictionary update problem and solved by the method of optimal direction(MOD).Finally,the diagonal entries of the analog PS precoding matrix are optimized by exhaustive search independently since PS and antenna is one-to-one.Simulation results show that the HEDC structure enjoys low power consumption and satisfactory spectral efficiency.The proposed algorithm presents at least 50%energy efficiency improvement compared with other algorithms when the PS resolution is set as 3-bit. 展开更多
关键词 energy efficiency hybrid precoding mmWave optimized resolution phase shifter
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