The Xiangshan deposit in Jiangxi province is one of the most important uranium deposits in China. The aim of this study is to achieve a better understanding of mineralization in the Xiangshan deposit through numerical...The Xiangshan deposit in Jiangxi province is one of the most important uranium deposits in China. The aim of this study is to achieve a better understanding of mineralization in the Xiangshan deposit through numerical simulation. In order to find the most favorable locations of mineralization and to help further mineral exploration, a coupling deforma- tion and fluid flow model has been established to describe the mineralization process. In this model, the simulation re- constructs the strata deformations under fields of compressive stress and thrust structure on the hanging wall of the Zou-Shi fault. Compared with practical information, the simulation results are consistent with the No. 51 exploration section of the western Xiangshan. In addition, on the basis of geological information provided by previous investigators, the model simulates the flow process of fluids under compressive stress fields. The result suggests that many tensional areas are formed, which can help the fluid flowing upward from deeper parts. The fluid is easy to concentrate on the breccia fractured zone between two volcanic layers, especially on the intersection parts with faults, resulting in the for- mation of favourable locations of mineralization. In addition, the model is significant in guiding the exploration of ura- nium deposits in the western Xiangshan and provides clues for further exploration of deposits.展开更多
Hydrocarbon preservation conditions have restricted exploration in the Middle and Upper Yangtze,and structural deformation and fluid activity have played an important role in the origin and preservation of oil and gas...Hydrocarbon preservation conditions have restricted exploration in the Middle and Upper Yangtze,and structural deformation and fluid activity have played an important role in the origin and preservation of oil and gas.In order to study that how the deformation and fluid activity impact the hydrocarbon preservation,we did some field work and collected some calcite vein samples for analysis of deformation periods using acoustic emission and fluid inclusions.Combined with previous studies,the strata distribution,tectonic deformation and fluid characteristics show that there are three structural belts in the study area：East Sichuan,West Hunan and Hubei and the northwestern periphery of the Xuefeng Uplift,and that their tectonic deformation style,fluid inclusion characteristics and hydrocarbon preservation are different.The breakthrough thrusts were well developed in the anticline core,and a lot of hydrocarbon inclusions were found in calcite veins around the thrusts in East Sichuan.The breakthrough thrusts were only in the syncline core in West Hunan and Hubei,and the brine inclusions did not contain hydrocarbon in calcite veins around the thrusts.Many breakthrough thrusts were found in the northwestern periphery of the Xuefeng Uplift,where there were only rare calcite veins.The deformation and hydrocarbon inclusion indicated that when there was no fault breakthrough in East Sichuan,the Paleozoic covered by the Triassic regional cap was good for hydrocarbon preservation.The strata above the Lower Paleozoic were denuded,and lots of brine inclusions and deep infiltration of surface water were found in the West Hunan and Hubei,so only the part of the syncline area with a well developed Silurian regional cap had good preservation conditions.Intense tectonic movements and denudation were widely developed in the northwestern periphery of the Xuefeng Uplift,where there were only paleo-reservoirs,non-hydrocarbon fluid activity and poor preservation conditions.展开更多
The structural deformation of NO2 group induced by an intense femtosecond laser field of liquid nitromethane（NM）molecule is detected by time-and frequency-resolved coherent anti-Stokes Raman spectroscopy（CARS） tec...The structural deformation of NO2 group induced by an intense femtosecond laser field of liquid nitromethane（NM）molecule is detected by time-and frequency-resolved coherent anti-Stokes Raman spectroscopy（CARS） technique with the intense pump laser. Here, we present the mechanism of molecular alignment and deformation. The CARS spectra and its FFT spectra of liquid NM show that the NO2 torsional mode couples with the CN symmetric stretching mode and that the NO2 group undergoes ultrafast structural deformation with a relaxation time of 195 fs. The frequency of the NO2 torsional mode in liquid NM（50.8±0.3 cm^-1） at room temperature is found. Our results prove the structural deformation of two groups in liquid NM molecule occur simultaneously in the intense laser field.展开更多
In order to study the failure process of an anchorage structure and the evolution law of the body＇s defor- mation field, anchor push-out tests were carried out based on digital speckle correlation methods （DSCM）. T...In order to study the failure process of an anchorage structure and the evolution law of the body＇s defor- mation field, anchor push-out tests were carried out based on digital speckle correlation methods （DSCM）. The stress distribution of the anchorage interface was investigated using the particle flow numerical simulation method. The results indicate that there are three stages in the deformation and fail- ure process of an anchorage structure： elastic bonding stage, a de-bonding stage and a failure stage. The stress distribution in the interface controls the stability of the structure. In the elastic bonding stage, the shear stress peak point of the interface is close to the loading end, and the displacement field gradually develops into a ＂V＂ shape, in the de-bonding stage, there is a shear stress plateau in the center of the anchorage section, and shear strain localization begins to form in the deformation field. In the failure stage, the bonding of the interface fails rapidly and the shear stress peak point moves to the anchorage free end. The anchorage structure moves integrally along the macro-cracl~ The de-bonding stage is a research focus in the deformation and failure process of an anchorage structure, and plays an important guiding role in roadway support design and prediction of the stability of the surrounding rock.展开更多
Based on the latest geological,seismic,drilling and outcrop data,we studied the geological structure,tectonic evolution history and deformation process of the southwestern Sichuan fold-thrust belt to find out the pote...Based on the latest geological,seismic,drilling and outcrop data,we studied the geological structure,tectonic evolution history and deformation process of the southwestern Sichuan fold-thrust belt to find out the potential hydrocarbon exploration areas in deep layers.During key tectonic periods,the southwestern Sichuan fold-thrust belt developed some characteristic strata and structural deformation features,including the Pre-Sinian multi-row N-S strike rifts,step-shaped platform-margin structures of Sinian Dengying Formation,the western paleo-uplift in the early stage of Late Paleozoic,the Late Paleozoic–Middle Triassic carbonate platform,foreland slope and forebulge during Late Triassic to Cretaceous,and Cenozoic multi-strike rejuvenated fold-thrusting structures.The fold-thrust belt vertically shows a double-layer structural deformation controlled by the salt layer in the Middle Triassic Leikoupo Formation and the base detachment layer at present.The upper deformation layer develops the NE-SW strike thrusts propagating toward basin in long distance,while the deeper deformation layer had near north-south strike basement-involved folds,which deformed the detachment and thrusting structures formed earlier in the upper layer,with the deformation strength high in south part and weak in north part.The southern part of the fold-thrust belt is characterized by basement-involved fold-thrusts formed late,while the central-northern part is dominated by thin-skin thrusts in the shallow layer.The Wuzhongshan anticlinal belt near piedmont is characterized by over-thrust structure above the salt detachment,where the upper over-thrusting nappe consists of a complicated fold core and front limb of a fault-bend fold,while the deep layer has stable subtle in-situ structures.Favorable exploration strata and areas have been identified both in the upper and deeper deformation layers separated by regional salt detachment,wherein multiple anticlinal structures are targets for exploration.Other potential exploration strata and areas in southwestern Sichuan fold-thrust belt include the deep Sinian and Permian in the Wuzhongshan structure,pre-Sinian rifting sequences and related structures,platform-margin belt of Sinian Dengying Formation,and Indosinian paleo-uplift in the east of the Longquanshan structure.展开更多
Nowadays,an increasing number of ships and marine structures are manufactured and inevitably operated in rough sea.As a result,some phenomena related to the violent fluid-elastic structure interactions(e.g.,hydrodynam...Nowadays,an increasing number of ships and marine structures are manufactured and inevitably operated in rough sea.As a result,some phenomena related to the violent fluid-elastic structure interactions(e.g.,hydrodynamic slamming on marine vessels,tsunami impact on onshore structures,and sloshing in liquid containers)have aroused huge challenges to ocean engineering fields.In this paper,the moving particle semi-implicit(MPS)method and finite element method(FEM)coupled method is proposed for use in numerical investigations of the interaction between a regular wave and a horizontal suspended structure.The fluid domain calculated by the MPS method is dispersed into fluid particles,and the structure domain solved by the FEM method is dispersed into beam elements.The generation of the 2D regular wave is firstly conducted,and convergence verification is performed to determine appropriate particle spacing for the simulation.Next,the regular wave interacting with a rigid structure is initially performed and verified through the comparison with the laboratory experiments.By verification,the MPS-FEM coupled method can be applied to fluid-structure interaction(FSI)problems with waves.On this basis,taking the flexibility of structure into consideration,the elastic dynamic response of the structure subjected to the wave slamming is investigated,including the evolutions of the free surface,the variation of the wave impact pressures,the velocity distribution,and the structural deformation response.By comparison with the rigid case,the effects of the structural flexibility on wave-elastic structure interaction can be obtained.展开更多
To evaluate the effect of tectonic deformation on coal reservoir properties, we provide an analysis of the types of tectonically deformed coal, macroand microscopic deformation and discuss pore structural characterist...To evaluate the effect of tectonic deformation on coal reservoir properties, we provide an analysis of the types of tectonically deformed coal, macroand microscopic deformation and discuss pore structural characteristics and connectivity based on samples from the Puhe and Shanchahe coal mines. Our research shows that the tectonically deformed coal mostly includes cataclastic structural coal, mortar structural coal and schistose structural coal of a brittle deformation series. The major pore structures of different types of tectonically deformed coal are transitional pores and micropores. The pore volumes of macropores and visible fracture pores produced by structural deformations vary over a large range and increase with the intensity of tectonic deformation. Mesopores as connecting passages develop well in schistose structural coal. According to the shapes of intrusive mercury curves, tectonically deformed coal can be divided into parallel, open and occluded types. The parallel type has poor connectivity and is relatively closed; the open type reflects uniformly developed open pores with good connectivity while the occluded type is good for coalbed methane enrichment, but has poor connectivity between pores.展开更多
Based on SEM observance,the methods of low-temperature nitrogen and isothermal adsorption were used to test and analyze the coal samples of Hancheng,and pore structure characteristics of tectonic coals were discussed....Based on SEM observance,the methods of low-temperature nitrogen and isothermal adsorption were used to test and analyze the coal samples of Hancheng,and pore structure characteristics of tectonic coals were discussed.The results indicate that in the same coal rank,stratification and crack are well developed in cataclastic coal,which is mostly filled by mineral substance in the geohydrologic element abundance,results in pore connectivity variation.Granulated and mylonitic coal being of these characteristics,as develop microstructures and exogenous fractures as well as large quantity of pores resulted from gas generation and strong impermeability,stimulate the recovery of seepage coal,improve coal connectivity and enhance reservoir permeability.Absorption pore(micro-pore) is dominant in coal pore for different coal body structure,the percentage of which pore aperture is from 1 to 100 nm is 71.44% to 88.15%,including large of micro-pore with the 74.56%-94.70%;with the deformation becoming more intense in the same coal rank,mesopore enlarge further,open-end pores become thin-neck-bottle-shaped pores step by step,specific surface area of micro-pore for cataclastic coal is 0.0027 m 2 /g,while mylonitic coal increases to 7.479 m 2 /g,micro-pore gradually play a dominant role in effecting pore structural parameters.展开更多
In order to analyze the origin of carbon monoxide(CO) in coal seams, stress–strain experiments under temperature of 50, 150 and 250 °C were conducted using lignite from Kailuan mining area. Fourier transform inf...In order to analyze the origin of carbon monoxide(CO) in coal seams, stress–strain experiments under temperature of 50, 150 and 250 °C were conducted using lignite from Kailuan mining area. Fourier transform infrared spectroscopy and elemental analysis were carried out before and after deformation of the samples. The results indicated that CO generated at 150 and 250 °C; the gas component was mostly oxygen(O_2), with small amount of carbon dioxide(CO_2), methane(CH_4) and hydrogen(H_2). At 50 °C, O_2 and a little CO_2 were observed and no CO was found. The carbon content of the coal samples increased slightly after deformation, and the oxygen content, H/C ratio, and O/C ratio decreased. The molecular structure of coal displayed different evolution characteristics at various temperatures. At 50 and 150 °C, the falling off of side chains, broken of ether bond and directional realignment of the aliphatic chains resulting in the formation of long chains were the main performance of coal molecular structure evolution. While at 250 °C, the side chains fell off and short chains formed. Furthermore, at both 150 and 250 °C, condensed degree of aromatic ring increased. Under the action of temperature and pressure, CO forms in two ways.The first is that ether bond breaks, oxygen and carbon atoms combine together and forms CO, or O_2 forming in the broken of ether–oxygen bond leads to the oxidation of free radicals and resulting in the formation of CO. And the second is that CO derives from falling off of C=O group.展开更多
For photon detection, superconducting transition-edge sensor(TES) micro-calorimeters are excellent energy-resolving devices. In this study, we report our recent work in developing Ti-/Au-based TES. The Ti/Au TES devic...For photon detection, superconducting transition-edge sensor(TES) micro-calorimeters are excellent energy-resolving devices. In this study, we report our recent work in developing Ti-/Au-based TES. The Ti/Au TES devices were designed and implemented with a thickness ratio of 1:1 and different suspended structures using micromachining technology. The characteristics were evaluated and analyzed, including surface morphology, 3 D deformation of suspended Ti/Au TES device structure, I–V characteristics, and low-temperature superconductivity. The results showed that the surface of Ti/Au has good homogeneity and the surface roughness of Ti/Au is significantly increased compared with the substrate. The structure of Ti/Au bilayer film significantly affects the deformation of suspended devices, but the deformation does not affect the I–V characteristics of the devices. For devices with the Ti/Au bilayer(150 μm × 150 μm) and beams(100 μm × 25 μm), the transition temperature(T;) is 253 m K with a width of 6 m K, and the value of the temperature sensitivity α is 95.1.展开更多
Significant exploration progress has been made in ultra-deep clastic rocks in the Kuqa Depression,Tarim Basin,over recent years.A new round of comprehensive geological research has formed four new understandings:(1)Es...Significant exploration progress has been made in ultra-deep clastic rocks in the Kuqa Depression,Tarim Basin,over recent years.A new round of comprehensive geological research has formed four new understandings:(1)Establish structural model consisting of multi-detachment composite,multi-stage structural superposition and multi-layer deformation.Multi-stage structural traps are overlapped vertically,and a series of structural traps are discovered in underlying ultra-deep layers.(2)Five sets of high-quality large-scale source rocks of three types of organic phases are developed in the Triassic and Jurassic systems,and forming a good combination of source-reservoir-cap rocks in ultra-deep layers with three sets of large-scale regional reservoir and cap rocks.(3)The formation of large oil and gas fields is controlled by four factors which are source,reservoir,cap rocks and fault.Based on the spatial configuration relationship of these four factors,a new three-dimensional reservoir formation model for ultra-deep clastic rocks in the Kuqa Depression has been established.(4)The next key exploration fields for ultra-deep clastic rocks in the Kuqa Depression include conventional and unconventional oil and gas.The conventional oil and gas fields include the deep multi-layer oil-gas accumulation zone in Kelasu,tight sandstone gas of Jurassic Ahe Formation in the northern structural zone,multi-target layer lithological oil and gas reservoirs in Zhongqiu–Dina structural zone,lithologic-stratigraphic and buried hill composite reservoirs in south slope and other favorable areas.Unconventional oil and gas fields include deep coal rock gas of Jurassic Kezilenuer and Yangxia formations,Triassic Tariqike Formation and Middle-Lower Jurassic and Upper Triassic continental shale gas.The achievements have important reference significance for enriching the theory of ultra-deep clastic rock oil and gas exploration and guiding the future oil and gas exploration deployment.展开更多
基金Projects GPMR0547 supported by the State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences, and 2002 CB 412601 by the Chinese Ministry of Science and Technology
文摘The Xiangshan deposit in Jiangxi province is one of the most important uranium deposits in China. The aim of this study is to achieve a better understanding of mineralization in the Xiangshan deposit through numerical simulation. In order to find the most favorable locations of mineralization and to help further mineral exploration, a coupling deforma- tion and fluid flow model has been established to describe the mineralization process. In this model, the simulation re- constructs the strata deformations under fields of compressive stress and thrust structure on the hanging wall of the Zou-Shi fault. Compared with practical information, the simulation results are consistent with the No. 51 exploration section of the western Xiangshan. In addition, on the basis of geological information provided by previous investigators, the model simulates the flow process of fluids under compressive stress fields. The result suggests that many tensional areas are formed, which can help the fluid flowing upward from deeper parts. The fluid is easy to concentrate on the breccia fractured zone between two volcanic layers, especially on the intersection parts with faults, resulting in the for- mation of favourable locations of mineralization. In addition, the model is significant in guiding the exploration of ura- nium deposits in the western Xiangshan and provides clues for further exploration of deposits.
基金sponsored by the National Basic Research Program of China (Grant No. 2012CB214804,2005CB422107 and G1999043305)the National Natural Science Foundation of China (Grant Nos. 41172125,40972090, and 40672143)+1 种基金the National Key Scientific Project(Grant No. 2011ZX05002-006-007HZ, 2008ZX05005-002-008HZ-1)the Doctoral Fund of Ministry of Education of China (Grant No. 200804250001)
文摘Hydrocarbon preservation conditions have restricted exploration in the Middle and Upper Yangtze,and structural deformation and fluid activity have played an important role in the origin and preservation of oil and gas.In order to study that how the deformation and fluid activity impact the hydrocarbon preservation,we did some field work and collected some calcite vein samples for analysis of deformation periods using acoustic emission and fluid inclusions.Combined with previous studies,the strata distribution,tectonic deformation and fluid characteristics show that there are three structural belts in the study area：East Sichuan,West Hunan and Hubei and the northwestern periphery of the Xuefeng Uplift,and that their tectonic deformation style,fluid inclusion characteristics and hydrocarbon preservation are different.The breakthrough thrusts were well developed in the anticline core,and a lot of hydrocarbon inclusions were found in calcite veins around the thrusts in East Sichuan.The breakthrough thrusts were only in the syncline core in West Hunan and Hubei,and the brine inclusions did not contain hydrocarbon in calcite veins around the thrusts.Many breakthrough thrusts were found in the northwestern periphery of the Xuefeng Uplift,where there were only rare calcite veins.The deformation and hydrocarbon inclusion indicated that when there was no fault breakthrough in East Sichuan,the Paleozoic covered by the Triassic regional cap was good for hydrocarbon preservation.The strata above the Lower Paleozoic were denuded,and lots of brine inclusions and deep infiltration of surface water were found in the West Hunan and Hubei,so only the part of the syncline area with a well developed Silurian regional cap had good preservation conditions.Intense tectonic movements and denudation were widely developed in the northwestern periphery of the Xuefeng Uplift,where there were only paleo-reservoirs,non-hydrocarbon fluid activity and poor preservation conditions.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.21673211 and 21203047)the Foundation of Heilongjiang Bayi Agricultural University,China(Grant No.XZR2014-16)the Science Challenging Program of China(Grant No.JCKY2016212A501)
文摘The structural deformation of NO2 group induced by an intense femtosecond laser field of liquid nitromethane（NM）molecule is detected by time-and frequency-resolved coherent anti-Stokes Raman spectroscopy（CARS） technique with the intense pump laser. Here, we present the mechanism of molecular alignment and deformation. The CARS spectra and its FFT spectra of liquid NM show that the NO2 torsional mode couples with the CN symmetric stretching mode and that the NO2 group undergoes ultrafast structural deformation with a relaxation time of 195 fs. The frequency of the NO2 torsional mode in liquid NM（50.8±0.3 cm^-1） at room temperature is found. Our results prove the structural deformation of two groups in liquid NM molecule occur simultaneously in the intense laser field.
基金financially supported by the National Key Basic Research Program of China (No.2010CB226805)the National Natural Science Foundation of China (Nos.51474136 and 51474013)+1 种基金the Opening Project Fund of State Key Laboratory of Mining Disaster Prevention and Control Co-founded by Shandong Province and the Ministry of Science and Technology (No.MDPC2013KF06)the Research Award Fund for the Excellent Youth of Shandong University of Science and Technology (No.2011KYJQ106)
文摘In order to study the failure process of an anchorage structure and the evolution law of the body＇s defor- mation field, anchor push-out tests were carried out based on digital speckle correlation methods （DSCM）. The stress distribution of the anchorage interface was investigated using the particle flow numerical simulation method. The results indicate that there are three stages in the deformation and fail- ure process of an anchorage structure： elastic bonding stage, a de-bonding stage and a failure stage. The stress distribution in the interface controls the stability of the structure. In the elastic bonding stage, the shear stress peak point of the interface is close to the loading end, and the displacement field gradually develops into a ＂V＂ shape, in the de-bonding stage, there is a shear stress plateau in the center of the anchorage section, and shear strain localization begins to form in the deformation field. In the failure stage, the bonding of the interface fails rapidly and the shear stress peak point moves to the anchorage free end. The anchorage structure moves integrally along the macro-cracl~ The de-bonding stage is a research focus in the deformation and failure process of an anchorage structure, and plays an important guiding role in roadway support design and prediction of the stability of the surrounding rock.
基金Supported by the Petro China Science and Technology Project(2016E-0601,2019B-0503)China National Science and Technology Major Project(2016ZX05003-001)
文摘Based on the latest geological,seismic,drilling and outcrop data,we studied the geological structure,tectonic evolution history and deformation process of the southwestern Sichuan fold-thrust belt to find out the potential hydrocarbon exploration areas in deep layers.During key tectonic periods,the southwestern Sichuan fold-thrust belt developed some characteristic strata and structural deformation features,including the Pre-Sinian multi-row N-S strike rifts,step-shaped platform-margin structures of Sinian Dengying Formation,the western paleo-uplift in the early stage of Late Paleozoic,the Late Paleozoic–Middle Triassic carbonate platform,foreland slope and forebulge during Late Triassic to Cretaceous,and Cenozoic multi-strike rejuvenated fold-thrusting structures.The fold-thrust belt vertically shows a double-layer structural deformation controlled by the salt layer in the Middle Triassic Leikoupo Formation and the base detachment layer at present.The upper deformation layer develops the NE-SW strike thrusts propagating toward basin in long distance,while the deeper deformation layer had near north-south strike basement-involved folds,which deformed the detachment and thrusting structures formed earlier in the upper layer,with the deformation strength high in south part and weak in north part.The southern part of the fold-thrust belt is characterized by basement-involved fold-thrusts formed late,while the central-northern part is dominated by thin-skin thrusts in the shallow layer.The Wuzhongshan anticlinal belt near piedmont is characterized by over-thrust structure above the salt detachment,where the upper over-thrusting nappe consists of a complicated fold core and front limb of a fault-bend fold,while the deep layer has stable subtle in-situ structures.Favorable exploration strata and areas have been identified both in the upper and deeper deformation layers separated by regional salt detachment,wherein multiple anticlinal structures are targets for exploration.Other potential exploration strata and areas in southwestern Sichuan fold-thrust belt include the deep Sinian and Permian in the Wuzhongshan structure,pre-Sinian rifting sequences and related structures,platform-margin belt of Sinian Dengying Formation,and Indosinian paleo-uplift in the east of the Longquanshan structure.
基金supported by the National Natural Science Foundation of China(51879159,51490675,11432009,and 51579145)Chang Jiang Scholars Program(T2014099)+3 种基金Shanghai Excellent Academic Leaders Program(17XD1402300)Program for Professor of Special Appointment(Eastern Scholar)at Shanghai Institutions of Higher Learning(2013022)Innovative Special Project of Numerical Tank of Ministry of Industry and Information Technology of China(2016-23/09)Lloyd’s Register Foundation for doctoral student
文摘Nowadays,an increasing number of ships and marine structures are manufactured and inevitably operated in rough sea.As a result,some phenomena related to the violent fluid-elastic structure interactions(e.g.,hydrodynamic slamming on marine vessels,tsunami impact on onshore structures,and sloshing in liquid containers)have aroused huge challenges to ocean engineering fields.In this paper,the moving particle semi-implicit(MPS)method and finite element method(FEM)coupled method is proposed for use in numerical investigations of the interaction between a regular wave and a horizontal suspended structure.The fluid domain calculated by the MPS method is dispersed into fluid particles,and the structure domain solved by the FEM method is dispersed into beam elements.The generation of the 2D regular wave is firstly conducted,and convergence verification is performed to determine appropriate particle spacing for the simulation.Next,the regular wave interacting with a rigid structure is initially performed and verified through the comparison with the laboratory experiments.By verification,the MPS-FEM coupled method can be applied to fluid-structure interaction(FSI)problems with waves.On this basis,taking the flexibility of structure into consideration,the elastic dynamic response of the structure subjected to the wave slamming is investigated,including the evolutions of the free surface,the variation of the wave impact pressures,the velocity distribution,and the structural deformation response.By comparison with the rigid case,the effects of the structural flexibility on wave-elastic structure interaction can be obtained.
基金supported by the National Natural Science Foundation of China (No.40672101)the Key National Natural Science Foundation of China (No.40730422)+1 种基金the National Science and Technology Key Special Project from the Ministry of Technology of China (No. 2008ZX05034)the China Scholarship Council (CSC)
文摘To evaluate the effect of tectonic deformation on coal reservoir properties, we provide an analysis of the types of tectonically deformed coal, macroand microscopic deformation and discuss pore structural characteristics and connectivity based on samples from the Puhe and Shanchahe coal mines. Our research shows that the tectonically deformed coal mostly includes cataclastic structural coal, mortar structural coal and schistose structural coal of a brittle deformation series. The major pore structures of different types of tectonically deformed coal are transitional pores and micropores. The pore volumes of macropores and visible fracture pores produced by structural deformations vary over a large range and increase with the intensity of tectonic deformation. Mesopores as connecting passages develop well in schistose structural coal. According to the shapes of intrusive mercury curves, tectonically deformed coal can be divided into parallel, open and occluded types. The parallel type has poor connectivity and is relatively closed; the open type reflects uniformly developed open pores with good connectivity while the occluded type is good for coalbed methane enrichment, but has poor connectivity between pores.
基金funded by the National Major Research Program for Science and Technology of China (Nos. 2009ZX05062and 2011ZX05062-009)
文摘Based on SEM observance,the methods of low-temperature nitrogen and isothermal adsorption were used to test and analyze the coal samples of Hancheng,and pore structure characteristics of tectonic coals were discussed.The results indicate that in the same coal rank,stratification and crack are well developed in cataclastic coal,which is mostly filled by mineral substance in the geohydrologic element abundance,results in pore connectivity variation.Granulated and mylonitic coal being of these characteristics,as develop microstructures and exogenous fractures as well as large quantity of pores resulted from gas generation and strong impermeability,stimulate the recovery of seepage coal,improve coal connectivity and enhance reservoir permeability.Absorption pore(micro-pore) is dominant in coal pore for different coal body structure,the percentage of which pore aperture is from 1 to 100 nm is 71.44% to 88.15%,including large of micro-pore with the 74.56%-94.70%;with the deformation becoming more intense in the same coal rank,mesopore enlarge further,open-end pores become thin-neck-bottle-shaped pores step by step,specific surface area of micro-pore for cataclastic coal is 0.0027 m 2 /g,while mylonitic coal increases to 7.479 m 2 /g,micro-pore gradually play a dominant role in effecting pore structural parameters.
基金financial support from the National Science foundation of China(No.41430317)the Discipline Innovative Engineering Plan sponsored by the Ministry of Education of China+1 种基金the State Administration of Foreign Experts Affairs of China(No.13023)the Priority Academic Program Development of Jiangsu Higher Education Institutions
文摘In order to analyze the origin of carbon monoxide(CO) in coal seams, stress–strain experiments under temperature of 50, 150 and 250 °C were conducted using lignite from Kailuan mining area. Fourier transform infrared spectroscopy and elemental analysis were carried out before and after deformation of the samples. The results indicated that CO generated at 150 and 250 °C; the gas component was mostly oxygen(O_2), with small amount of carbon dioxide(CO_2), methane(CH_4) and hydrogen(H_2). At 50 °C, O_2 and a little CO_2 were observed and no CO was found. The carbon content of the coal samples increased slightly after deformation, and the oxygen content, H/C ratio, and O/C ratio decreased. The molecular structure of coal displayed different evolution characteristics at various temperatures. At 50 and 150 °C, the falling off of side chains, broken of ether bond and directional realignment of the aliphatic chains resulting in the formation of long chains were the main performance of coal molecular structure evolution. While at 250 °C, the side chains fell off and short chains formed. Furthermore, at both 150 and 250 °C, condensed degree of aromatic ring increased. Under the action of temperature and pressure, CO forms in two ways.The first is that ether bond breaks, oxygen and carbon atoms combine together and forms CO, or O_2 forming in the broken of ether–oxygen bond leads to the oxidation of free radicals and resulting in the formation of CO. And the second is that CO derives from falling off of C=O group.
文摘For photon detection, superconducting transition-edge sensor(TES) micro-calorimeters are excellent energy-resolving devices. In this study, we report our recent work in developing Ti-/Au-based TES. The Ti/Au TES devices were designed and implemented with a thickness ratio of 1:1 and different suspended structures using micromachining technology. The characteristics were evaluated and analyzed, including surface morphology, 3 D deformation of suspended Ti/Au TES device structure, I–V characteristics, and low-temperature superconductivity. The results showed that the surface of Ti/Au has good homogeneity and the surface roughness of Ti/Au is significantly increased compared with the substrate. The structure of Ti/Au bilayer film significantly affects the deformation of suspended devices, but the deformation does not affect the I–V characteristics of the devices. For devices with the Ti/Au bilayer(150 μm × 150 μm) and beams(100 μm × 25 μm), the transition temperature(T;) is 253 m K with a width of 6 m K, and the value of the temperature sensitivity α is 95.1.
基金Supported by the National Natural Science Foundation of China(U22B6002)PetroChina Science and Technology Project(2023ZZ14).
文摘Significant exploration progress has been made in ultra-deep clastic rocks in the Kuqa Depression,Tarim Basin,over recent years.A new round of comprehensive geological research has formed four new understandings:(1)Establish structural model consisting of multi-detachment composite,multi-stage structural superposition and multi-layer deformation.Multi-stage structural traps are overlapped vertically,and a series of structural traps are discovered in underlying ultra-deep layers.(2)Five sets of high-quality large-scale source rocks of three types of organic phases are developed in the Triassic and Jurassic systems,and forming a good combination of source-reservoir-cap rocks in ultra-deep layers with three sets of large-scale regional reservoir and cap rocks.(3)The formation of large oil and gas fields is controlled by four factors which are source,reservoir,cap rocks and fault.Based on the spatial configuration relationship of these four factors,a new three-dimensional reservoir formation model for ultra-deep clastic rocks in the Kuqa Depression has been established.(4)The next key exploration fields for ultra-deep clastic rocks in the Kuqa Depression include conventional and unconventional oil and gas.The conventional oil and gas fields include the deep multi-layer oil-gas accumulation zone in Kelasu,tight sandstone gas of Jurassic Ahe Formation in the northern structural zone,multi-target layer lithological oil and gas reservoirs in Zhongqiu–Dina structural zone,lithologic-stratigraphic and buried hill composite reservoirs in south slope and other favorable areas.Unconventional oil and gas fields include deep coal rock gas of Jurassic Kezilenuer and Yangxia formations,Triassic Tariqike Formation and Middle-Lower Jurassic and Upper Triassic continental shale gas.The achievements have important reference significance for enriching the theory of ultra-deep clastic rock oil and gas exploration and guiding the future oil and gas exploration deployment.
