To solve the critical problems of lithium rich cathode materials, e.g., structure instability and short cycle life, we have successfully prepared a ZrO2-coated and Zr-doping xLi2MnO3·(1–x)LiMO2 hollow architectu...To solve the critical problems of lithium rich cathode materials, e.g., structure instability and short cycle life, we have successfully prepared a ZrO2-coated and Zr-doping xLi2MnO3·(1–x)LiMO2 hollow architecture via one-time sintering process. The modified structural materials as lithium-ion cathodes present good structural stability and superior cycle performance in LIBs. The discharge capacity of the ZrO2-coated and Zr-doped hollow pristine is 220 mAh g-1 at the 20th cycle at 0.2 C(discharge capacity loss, 2.7%)and 150 m Ah g-1 at the 100 th cycle at 1 C(discharge capacity loss, 17.7%), respectively. However, hollow pristine electrode only delivers 203 m Ah g-1 at the 20 th cycle at 0.2 C and 124 mAh g-1 at the 100 th cycle at 1 C, respectively, and the corresponding to capacity retention is 92.2% and 72.8%, respectively.Diffusion coefficients of modified hollow pristine electrode are much higher than that of hollow pristine electrode after 100 cycles(approach to 1.4 times). In addition, we simulate the adsorption reaction of HF on the surface of ZrO2-coated layer by the first-principles theory. The calculations prove that the adsorption energy of HF on the surface of ZrO2-coated layer is about-1.699 e V, and the ZrO2-coated layer could protect the hollow spherical xLi2MnO3·(1–x)LiMO2 from erosion by HF. Our results would be applicable for systematic amelioration of high-performance lithium rich material for anode with the respect of practical application.展开更多
A new method for manufacturing explosive charge liner of petroleum perforation bullet, using hot press sintering technique, has been introduced in the paper. The sintering process of making explosive charge liner has...A new method for manufacturing explosive charge liner of petroleum perforation bullet, using hot press sintering technique, has been introduced in the paper. The sintering process of making explosive charge liner has been investigated. The mechanical test and SEM analysis indicate that the property of the liner produced by the process is satisfied.展开更多
由于烧结过程中存在众多不确定性因素,使得机理分析和点预测结果的可靠性不足.基于此提出随机森林-极限树-核密度估计(random forest-extreme tree-kernel density estimation,RF-ET-KDE)算法对物理指标(粒度、水分)进行区间预测.首先,...由于烧结过程中存在众多不确定性因素,使得机理分析和点预测结果的可靠性不足.基于此提出随机森林-极限树-核密度估计(random forest-extreme tree-kernel density estimation,RF-ET-KDE)算法对物理指标(粒度、水分)进行区间预测.首先,采用数据预处理和特征选择操作筛选出最适合建模的特征变量.其次,使用基于Stacking的RF-ET算法对指标进行点预测,该算法使得模型有较高的准确性和泛化性.然后,采用KDE算法计算指标的预测误差,得到了一定置信水平下的分布区间和区间预测结果.最后,用所建模型与其余组合模型进行对比.结果表明,RF-ET算法有较高的点预测效果,KDE算法可以很好地量化指标的误差,可以得到较高可靠度的区间预测结果.展开更多
基金the financial support by the Natural Science Foundation of Guangdong Province(2019A1515012111)the National Natural Science Foundation of China(51804199 and 51604081)+2 种基金the Science and Technology Innovation Commission of Shenzhen(JCYJ20190808173815205 and 20180123)the Shenzhen Science and Technology Program(KQTD20180412181422399)“Chenguang Program”supported by Shanghai Education Development Foundation and Shanghai Municipal Education Commission(16CG40)。
文摘To solve the critical problems of lithium rich cathode materials, e.g., structure instability and short cycle life, we have successfully prepared a ZrO2-coated and Zr-doping xLi2MnO3·(1–x)LiMO2 hollow architecture via one-time sintering process. The modified structural materials as lithium-ion cathodes present good structural stability and superior cycle performance in LIBs. The discharge capacity of the ZrO2-coated and Zr-doped hollow pristine is 220 mAh g-1 at the 20th cycle at 0.2 C(discharge capacity loss, 2.7%)and 150 m Ah g-1 at the 100 th cycle at 1 C(discharge capacity loss, 17.7%), respectively. However, hollow pristine electrode only delivers 203 m Ah g-1 at the 20 th cycle at 0.2 C and 124 mAh g-1 at the 100 th cycle at 1 C, respectively, and the corresponding to capacity retention is 92.2% and 72.8%, respectively.Diffusion coefficients of modified hollow pristine electrode are much higher than that of hollow pristine electrode after 100 cycles(approach to 1.4 times). In addition, we simulate the adsorption reaction of HF on the surface of ZrO2-coated layer by the first-principles theory. The calculations prove that the adsorption energy of HF on the surface of ZrO2-coated layer is about-1.699 e V, and the ZrO2-coated layer could protect the hollow spherical xLi2MnO3·(1–x)LiMO2 from erosion by HF. Our results would be applicable for systematic amelioration of high-performance lithium rich material for anode with the respect of practical application.
文摘A new method for manufacturing explosive charge liner of petroleum perforation bullet, using hot press sintering technique, has been introduced in the paper. The sintering process of making explosive charge liner has been investigated. The mechanical test and SEM analysis indicate that the property of the liner produced by the process is satisfied.
文摘由于烧结过程中存在众多不确定性因素,使得机理分析和点预测结果的可靠性不足.基于此提出随机森林-极限树-核密度估计(random forest-extreme tree-kernel density estimation,RF-ET-KDE)算法对物理指标(粒度、水分)进行区间预测.首先,采用数据预处理和特征选择操作筛选出最适合建模的特征变量.其次,使用基于Stacking的RF-ET算法对指标进行点预测,该算法使得模型有较高的准确性和泛化性.然后,采用KDE算法计算指标的预测误差,得到了一定置信水平下的分布区间和区间预测结果.最后,用所建模型与其余组合模型进行对比.结果表明,RF-ET算法有较高的点预测效果,KDE算法可以很好地量化指标的误差,可以得到较高可靠度的区间预测结果.
