Li-rich layered oxide(LRLO)cathodes have been regarded as promising candidates for next-generation Li-ion batteries due to their exceptionally high energy density,which combines cationic and anionic redox activities.H...Li-rich layered oxide(LRLO)cathodes have been regarded as promising candidates for next-generation Li-ion batteries due to their exceptionally high energy density,which combines cationic and anionic redox activities.However,continuous voltage decay during cycling remains the primary obstacle for practical applications,which has yet to be fundamentally addressed.It is widely acknowledged that voltage decay originates from the irreversible migration of transition metal ions,which usually further exacerbates structural evolution and aggravates the irreversible oxygen redox reactions.Recently,constructing O2-type structure has been considered one of the most promising approaches for inhibiting voltage decay.In this review,the relationship between voltage decay and structural evolution is systematically elucidated.Strategies to suppress voltage decay are systematically summarized.Additionally,the design of O2-type structure and the corresponding mechanism of suppressing voltage decay are comprehensively discussed.Unfortunately,the reported O2-type LRLO cathodes still exhibit partially disordered structure with extended cycles.Herein,the factors that may cause the irreversible transition metal migrations in O2-type LRLO materials are also explored,while the perspectives and challenges for designing high-performance O2-type LRLO cathodes without voltage decay are proposed.展开更多
A multi-channel polarimeter-interferometer has been developed on the Keda Torus eXperiment(KTX)for the study of equilibrium dynamics and internal magnetic fluctuations.A three-wave technique based on terahertz solid-s...A multi-channel polarimeter-interferometer has been developed on the Keda Torus eXperiment(KTX)for the study of equilibrium dynamics and internal magnetic fluctuations.A three-wave technique based on terahertz solid-state sources(-650 GHz)is applied for simultaneous measurements of electron density and Faraday rotation angle.The output power of the microwave source is 2 mW.Faraday rotation effect using a rotating wave plate is tested with phase noise less than 0.8°,and the density phase noise is less than 0.9°.Measurement of Faraday rotation angle and density for discharges on KTX have demonstrated high sensitivity to internal MHD activities.展开更多
A new compact torus injector(KTX-CTI)has been built for injection experiments on the Keda Torus eXperiment(KTX)reversed field pinch(RFP).The aim is to study the fundamental physics governing the compact torus(CT)centr...A new compact torus injector(KTX-CTI)has been built for injection experiments on the Keda Torus eXperiment(KTX)reversed field pinch(RFP).The aim is to study the fundamental physics governing the compact torus(CT)central fueling processes.In experiments conducted under the sole influence of a 0.1 T toroidal magnetic field,the injected CT successfully penetrated the entire toroidal magnetic field,reaching the inner wall of the KTX vacuum vessel.Upon reaching the inner wall,the CT diffused both radially outward and toroidally within the vessel at a discernible diffusion speed.Moreover,the inherent helicity within the CT induced a modest KTX plasma current of 200 A,consistent with predictions based on helicity conservation.CT injection demonstrated the capability to initiate KTX discharges at low loop voltages,suggesting its potential as a pre-ionization and current startup technique.During RFP discharges featuring CT injection,the central plasma density was found to exceed the Greenwald density limit,with more peaked density profiles,indicating the predominant confinement of CT plasma within the core region of the KTX bulk plasma.展开更多
A compact torus injection system,KTX-CTI,has been developed for the planned injection experiments on the Keda Torus e Xperiment(KTX)reversed field pinch(RFP)device to investigate the physics and engineering issues ass...A compact torus injection system,KTX-CTI,has been developed for the planned injection experiments on the Keda Torus e Xperiment(KTX)reversed field pinch(RFP)device to investigate the physics and engineering issues associated with interaction between a compact torus(CT)and RFP.The key interests include fueling directly into the reactor center,confinement improvement,and the injection of momentum and helicity into the RFP discharges.The CT velocity and mass have been measured using a multichannel optical fiber interferometer,and for the first time the time evolution of the CT density profile during CT propagation is obtained.The effects of discharge parameters on the number of injected particles,CT velocity and CT density have been characterized:the maximum hydrogen CT plasma mass,m,CTis 50μg,corresponding to 30%of the mass in a typical KTX plasma;the CT velocity exceeds 120 km s-1.It is observed for the first time that multiple CTs can be produced and emitted during a very short period(<100μs)in one discharge,which is significant for the future study of repetitive CT injection,even with an ultra-high frequency.展开更多
Though oxygen defects are associated with deteriorated structures and aggravated cycling performance in traditional layered cathodes,the role of oxygen defects is still ambiguous in Li-rich layered oxides due to the i...Though oxygen defects are associated with deteriorated structures and aggravated cycling performance in traditional layered cathodes,the role of oxygen defects is still ambiguous in Li-rich layered oxides due to the involvement of oxygen redox.Herein,a Co-free Li-rich layered oxide Li_(1.286)Ni_(0.071)Mn_(0.643)O_(2)has been prepared by a co-precipitation method to systematically investigate the undefined effects of the oxygen defects.A significant O_(2)release and the propagation of oxygen vacancies were detected by operando differential electrochemical mass spectroscopy(DEMS)and electron energy loss spectroscopy(EELS),respectively.Scanning transmission electron microscopy-high angle annular dark field(STEMHAADF)reveals the oxygen vacancies fusing to nanovoids and monitors a stepwise electrochemical activation process of the large Li_(2)MnO_(3)domain upon cycling.Combined with the quantitative analysis conducted by the energy dispersive spectrometer(EDS),existed nano-scale oxygen defects actually expose more surface to the electrolyte for facilitating the electrochemical activation and subsequently increasing available capacity.Overall,this work persuasively elucidates the function of oxygen defects on oxygen redox in Co-free Li-rich layered oxides.展开更多
A 10-channel Hα diagnostic system has been designed with the rapid response rate of 300 kHz, spatial resolution of about 40 mm, and overlap between adjacent channels of about 3%, and it has been implemented successfu...A 10-channel Hα diagnostic system has been designed with the rapid response rate of 300 kHz, spatial resolution of about 40 mm, and overlap between adjacent channels of about 3%, and it has been implemented successfully on Keda Torus eXperiment(KTX), a newly constructed, reversed field pinch(RFP) experimental device at the University of Science and Technology of China(USTC). This diagnostic system is a very important tool for the initial KTX operations. It is compact,with an aperture slit replacing the traditional optical lens system. A flexural interference filter is designed to prevent the center wavelength from shifting too much as the increase of angle from vertical incidence. To eliminate the stray light,the interior of the system is covered with the black aluminum foil having a very high absorptivity. Using the Hαemission data, together with the profiles of electron temperature and density obtained from the Langmuir probe, the neutral density profiles have been calculated for KTX plasmas. The rapid response rate and good spatial resolution of this Hαdiagnostic system will be beneficial for many studies in RFP plasma physics.展开更多
A fast radial scanning probe system was constructed for the Keda Torus eXperiment(KTX)to measure the profiles of boundary plasma parameters such as floating potential,electron density,temperature,transport fluxes,etc....A fast radial scanning probe system was constructed for the Keda Torus eXperiment(KTX)to measure the profiles of boundary plasma parameters such as floating potential,electron density,temperature,transport fluxes,etc.The scanning probe system is driven by slow and fast motion mechanisms,corresponding to the stand-by movement of a stepping motor and the fast scanning movement of a high-torque servo-motor,respectively.In fast scanning,the scanner drives the probe radially up to 20 cm at a maximum velocity of 4.0 m s-1.A noncontact magnetic grating ruler with a high spatial resolution of 5μm is used for the displacement measurement.New scanning probe can reach the center of plasmas rapidly.The comparison of plasma floating potential profiles obtained by a fixed radial rake probe and the single scanning probe suggests that the high-speed scanning probe system is reliable for measuring edge plasma parameter profiles on the KTX device.展开更多
A 100-channel double-foil soft X-ray array imaging(DSXAI)diagnostic system has been developed for the HL-2A tokamak to obtain tomographic bremsstrahlung emissivity and electron temperature(T_(e)).This system employs a...A 100-channel double-foil soft X-ray array imaging(DSXAI)diagnostic system has been developed for the HL-2A tokamak to obtain tomographic bremsstrahlung emissivity and electron temperature(T_(e)).This system employs a double-foil technique to determine T_(e) by comparing the soft X-ray(SXR)emissivities from the same plasma location through two beryllium(Be)foils of differing thickness.The DSXAI system comprises five photocameras mounted at two different poloidal cross-sections,separated toroidally by 15°,allowing for three distinct poloidal viewing angles.Each photocamera features 20 channels,offering a temporal resolution of approximately 4μs and a spatial resolution of about 8 cm,with no channel overlap.Each photocamera contains two identical optical systems,each defined by an aperture slit and a photodiode array.The double-foil configuration is realized by placing these two optical systems,each with a different Be foil,in close proximity.Initial experimental results demonstrate that the DSXAI diagnostic system performs well,successfully reconstructing 2-dimensional(2D)tomographic SXR emissivity and T_(e) on the HL-2A tokamak.This study provides valuable insights for the future implementation of similar diagnostic systems on fusion reactors like ITER.展开更多
基金funded by the National Natural Science Foundation of China(Grant Nos.22279092 and 5202780089).
文摘Li-rich layered oxide(LRLO)cathodes have been regarded as promising candidates for next-generation Li-ion batteries due to their exceptionally high energy density,which combines cationic and anionic redox activities.However,continuous voltage decay during cycling remains the primary obstacle for practical applications,which has yet to be fundamentally addressed.It is widely acknowledged that voltage decay originates from the irreversible migration of transition metal ions,which usually further exacerbates structural evolution and aggravates the irreversible oxygen redox reactions.Recently,constructing O2-type structure has been considered one of the most promising approaches for inhibiting voltage decay.In this review,the relationship between voltage decay and structural evolution is systematically elucidated.Strategies to suppress voltage decay are systematically summarized.Additionally,the design of O2-type structure and the corresponding mechanism of suppressing voltage decay are comprehensively discussed.Unfortunately,the reported O2-type LRLO cathodes still exhibit partially disordered structure with extended cycles.Herein,the factors that may cause the irreversible transition metal migrations in O2-type LRLO materials are also explored,while the perspectives and challenges for designing high-performance O2-type LRLO cathodes without voltage decay are proposed.
基金supported by National Natural Science Foundation of China(No.12175227)the Fundamental Research Funds for the Central Universities(No.USTC 20210079)the Collaborative Innovation Program of Hefei Science Center,CAS(No.2022HSC-CIP022)。
文摘A multi-channel polarimeter-interferometer has been developed on the Keda Torus eXperiment(KTX)for the study of equilibrium dynamics and internal magnetic fluctuations.A three-wave technique based on terahertz solid-state sources(-650 GHz)is applied for simultaneous measurements of electron density and Faraday rotation angle.The output power of the microwave source is 2 mW.Faraday rotation effect using a rotating wave plate is tested with phase noise less than 0.8°,and the density phase noise is less than 0.9°.Measurement of Faraday rotation angle and density for discharges on KTX have demonstrated high sensitivity to internal MHD activities.
基金supported by the National Magnetic Confinement Fusion Science Program of China(Nos.2022YFE03100000 and 2017YFE0301701)National Natural Science Foundation of China(Nos.12375226,11875255,11635008,11375188 and 11975231)the Fundamental Research Funds for the Central Universities(No.wk34200000022)。
文摘A new compact torus injector(KTX-CTI)has been built for injection experiments on the Keda Torus eXperiment(KTX)reversed field pinch(RFP).The aim is to study the fundamental physics governing the compact torus(CT)central fueling processes.In experiments conducted under the sole influence of a 0.1 T toroidal magnetic field,the injected CT successfully penetrated the entire toroidal magnetic field,reaching the inner wall of the KTX vacuum vessel.Upon reaching the inner wall,the CT diffused both radially outward and toroidally within the vessel at a discernible diffusion speed.Moreover,the inherent helicity within the CT induced a modest KTX plasma current of 200 A,consistent with predictions based on helicity conservation.CT injection demonstrated the capability to initiate KTX discharges at low loop voltages,suggesting its potential as a pre-ionization and current startup technique.During RFP discharges featuring CT injection,the central plasma density was found to exceed the Greenwald density limit,with more peaked density profiles,indicating the predominant confinement of CT plasma within the core region of the KTX bulk plasma.
基金supported by the National Magnetic Confinement Fusion Science Program of China(Nos.2017YFE0301700 and 2017YFE0301701)National Natural Science Foundation of China(Nos.11875255,11635008,11375188 and 11975231)。
文摘A compact torus injection system,KTX-CTI,has been developed for the planned injection experiments on the Keda Torus e Xperiment(KTX)reversed field pinch(RFP)device to investigate the physics and engineering issues associated with interaction between a compact torus(CT)and RFP.The key interests include fueling directly into the reactor center,confinement improvement,and the injection of momentum and helicity into the RFP discharges.The CT velocity and mass have been measured using a multichannel optical fiber interferometer,and for the first time the time evolution of the CT density profile during CT propagation is obtained.The effects of discharge parameters on the number of injected particles,CT velocity and CT density have been characterized:the maximum hydrogen CT plasma mass,m,CTis 50μg,corresponding to 30%of the mass in a typical KTX plasma;the CT velocity exceeds 120 km s-1.It is observed for the first time that multiple CTs can be produced and emitted during a very short period(<100μs)in one discharge,which is significant for the future study of repetitive CT injection,even with an ultra-high frequency.
基金supported by the National Natural Science Foundation of China(52272253)the"Lingyan"Research and Development Plan of Zhejiang Province(2022C01071)+2 种基金the S&T Innovation 2025 Major Special Programme of Ningbo(2018B10081)the Natural Science Foundation of Ningbo(202003N4030)the Youth Innovation Promotion Association of Chinese Academy of Sciences(2022299)。
文摘Though oxygen defects are associated with deteriorated structures and aggravated cycling performance in traditional layered cathodes,the role of oxygen defects is still ambiguous in Li-rich layered oxides due to the involvement of oxygen redox.Herein,a Co-free Li-rich layered oxide Li_(1.286)Ni_(0.071)Mn_(0.643)O_(2)has been prepared by a co-precipitation method to systematically investigate the undefined effects of the oxygen defects.A significant O_(2)release and the propagation of oxygen vacancies were detected by operando differential electrochemical mass spectroscopy(DEMS)and electron energy loss spectroscopy(EELS),respectively.Scanning transmission electron microscopy-high angle annular dark field(STEMHAADF)reveals the oxygen vacancies fusing to nanovoids and monitors a stepwise electrochemical activation process of the large Li_(2)MnO_(3)domain upon cycling.Combined with the quantitative analysis conducted by the energy dispersive spectrometer(EDS),existed nano-scale oxygen defects actually expose more surface to the electrolyte for facilitating the electrochemical activation and subsequently increasing available capacity.Overall,this work persuasively elucidates the function of oxygen defects on oxygen redox in Co-free Li-rich layered oxides.
基金Project supported by the National Magnetic Confinement Fusion Science Program of China(Grant No.2017YFE0301700)the National Natural Science Foundation of China(Grant No.11635008)
文摘A 10-channel Hα diagnostic system has been designed with the rapid response rate of 300 kHz, spatial resolution of about 40 mm, and overlap between adjacent channels of about 3%, and it has been implemented successfully on Keda Torus eXperiment(KTX), a newly constructed, reversed field pinch(RFP) experimental device at the University of Science and Technology of China(USTC). This diagnostic system is a very important tool for the initial KTX operations. It is compact,with an aperture slit replacing the traditional optical lens system. A flexural interference filter is designed to prevent the center wavelength from shifting too much as the increase of angle from vertical incidence. To eliminate the stray light,the interior of the system is covered with the black aluminum foil having a very high absorptivity. Using the Hαemission data, together with the profiles of electron temperature and density obtained from the Langmuir probe, the neutral density profiles have been calculated for KTX plasmas. The rapid response rate and good spatial resolution of this Hαdiagnostic system will be beneficial for many studies in RFP plasma physics.
基金supported by the National Magnetic Confinement Fusion Science Program of China(No.2017YFE0301700)National Natural Science Foundation of China(No.11635008).
文摘A fast radial scanning probe system was constructed for the Keda Torus eXperiment(KTX)to measure the profiles of boundary plasma parameters such as floating potential,electron density,temperature,transport fluxes,etc.The scanning probe system is driven by slow and fast motion mechanisms,corresponding to the stand-by movement of a stepping motor and the fast scanning movement of a high-torque servo-motor,respectively.In fast scanning,the scanner drives the probe radially up to 20 cm at a maximum velocity of 4.0 m s-1.A noncontact magnetic grating ruler with a high spatial resolution of 5μm is used for the displacement measurement.New scanning probe can reach the center of plasmas rapidly.The comparison of plasma floating potential profiles obtained by a fixed radial rake probe and the single scanning probe suggests that the high-speed scanning probe system is reliable for measuring edge plasma parameter profiles on the KTX device.
基金supported by the National Magnetic Confinement Fusion Science Program of China (Nos.2022YFE03100004,2017YFE0301700,2017YFE0301701 and 2022YFE03060003)National Natural Science Foundation of China (Nos.12375226,12175227,11875255 and 11975231)+2 种基金the China Postdoctoral Science Foundation (No.2022M723066)the Fundamental Research Funds for the Central Universitiesthe Collaborative Innovation Program of Hefei Science Center,CAS (No.2022HSCCIP022)。
文摘A 100-channel double-foil soft X-ray array imaging(DSXAI)diagnostic system has been developed for the HL-2A tokamak to obtain tomographic bremsstrahlung emissivity and electron temperature(T_(e)).This system employs a double-foil technique to determine T_(e) by comparing the soft X-ray(SXR)emissivities from the same plasma location through two beryllium(Be)foils of differing thickness.The DSXAI system comprises five photocameras mounted at two different poloidal cross-sections,separated toroidally by 15°,allowing for three distinct poloidal viewing angles.Each photocamera features 20 channels,offering a temporal resolution of approximately 4μs and a spatial resolution of about 8 cm,with no channel overlap.Each photocamera contains two identical optical systems,each defined by an aperture slit and a photodiode array.The double-foil configuration is realized by placing these two optical systems,each with a different Be foil,in close proximity.Initial experimental results demonstrate that the DSXAI diagnostic system performs well,successfully reconstructing 2-dimensional(2D)tomographic SXR emissivity and T_(e) on the HL-2A tokamak.This study provides valuable insights for the future implementation of similar diagnostic systems on fusion reactors like ITER.
