Turquoise, a hydrous phosphate of copper and aluminum, is highly valued for its unique colour and historical significance. The similarity in colour, quality, and pattern between turquoises from different localities ma...Turquoise, a hydrous phosphate of copper and aluminum, is highly valued for its unique colour and historical significance. The similarity in colour, quality, and pattern between turquoises from different localities may lead to confusion in determining their origins. This is particularly evident in the case of turquoises from Meiduk in Iran and Tongling in China(Fig.1).In Iran, turquoise deposits are typically associated with magmatic zones, specifically in the Meiduk mine, located 85 kilometers northwest of the Sar Cheshmeh porphyry copper deposit in Kerman Province. The deposit is hosted by Eocene volcanic rocks of andesitic-basaltic composition with porphyry-type mineralization associated with two Miocene calc-alkaline intrusive phases. Five distinct zones of the hypogene alteration include potassic, potassic-phyllic, phyllic, and propylitic zones, which are rich in magnetite. Mineralization processes include stockwork, dissemination, veinlets, and veins rich in garnet, chalcopyrite, magnetite, and anhydrite. Turquoise is found in transitional, leached, and supergene zones, primarily as fracture and seam fillers. In contrast, Chinese turquoises are more often found in sedimentary rocks, with significant exceptions in places like the Tongling mine in Anhui Province, which are hosted within magmatic rocks. The turquoise from Tongling is found in the Tongling area within the Middle-lower Yangtze Metallogenic Belt, an area characterized by complex tectonics and intense magmatic and metallogenic activities. The turquoise deposits are associated with iron-copper polymetallic mineralization within Early Cretaceous volcanic rocks.The turquoise from Meiduk exhibited a specific gravity range of 2.22 g/cm^(3)to 2.71 g/cm^(3), SWUV fluorescence from none to medium, and LWUV fluorescence from faint to strong, indicating diverse mineralogical compositions. SEM examination of turquoise from Meiduk reveals a variety of mineral morphologies. The turquoise displays closely packed arrays of elongated needle-like crystals, measuring 2 μm to 9 μm in length and 0.1 μm to 0.4 μm in thickness, indicating a dynamic growth environment. The density and alignment of these crystals suggest the space-constrained setting, likely influenced by rapid deposition from mineral-laden fluids, with crystals interlocked due to simultaneous nucleation events. Some crystals appear similarly elongated but are more dispersed, with greater separation between individual crystals. In other areas, the elongated turquoise crystals are tightly intergrown, creating a dense textural appearance, pointing to a stage where growth space became limited, resulting in an interlocking matrix. Additionally, some crystals radiate outward from a central point, forming a spherical pattern reaching about 18 μm. The turquoise from Tongling show a specific gravity range of 2.26 g/cm^(3)to 2.60 g/cm^(3), with consistent medium SWUV fluorescence and strong LWUV fluorescence. SEM examination reveals needle structures, plate-like structures, and spheroidal aggregates composed of needle and plate-like microcrystals. These spherical aggregates, some with diameters around 26 μm, exhibit the concentric growth structure covered by turquoise microcrystals, with crystal lengths of 8 μm. The surface needle-like microcrystals vary in size, approximately 3 μm in length, 2 μm in width, and 0.2 to 0.6 μm in thickness.Optical microscopy, Raman and FTIR spectroscopy reported the presence of quartz, gypsum, iron oxides such as jarosite and goethite, biotite, sericite, pyrite, galena, bornite, graphene oxide, malachite, and azurite as major associated minerals of Meiduk's. In contrast, the Tongling mine features minerals such as quartz, anatase, barite, sodium feldspar, illite, and malachite.Through EPMA and LA-ICP-MS results, the turquoises of Tongling exhibit similar average iron content(1.28% and 1.26% respectively), but significant differences in copper content. The turquoises of Meiduk have the average copper content of 6.97%, whereas Tongling samples show the higher content of 11.38%. Na, K, and Ca concentrations are also higher in Meiduk samples, suggesting interaction with alkali-rich fluids and potassic alteration. Trace elements such as Ti, Cr, Zn, Se, and Mo serve as tracing agents for Meiduk samples, while Be and W are associated with Tongling samples. Regarding rare earth elements(REEs), Meiduk samples show diverse δCe(0.14-4.62) and δEu(0.65-15.78) values, indicating a wide range of oxidation states and europium anomalies. The significant variability in LREE/HREE ratios(0.39-31.74) and ΣREE concentrations(0.25-240.72 ppm) suggests heterogeneous REE fractionation patterns. In contrast, Tongling samples display δCe(0.070-2.51) and δEu(0.238-4.87) ranges, with more consistent LREE/HREE ratios(0.128-10.2) and ΣREE values(0.069-4.08 ppm), indicating stable REE fractionation dynamics.This comparative study of turquoises from the Meiduk mine in Iran and the Tongling mine in China reveals significant similarities and differences in their geochemical and mineralogical characteristics. Both deposits are hosted within magmatic rocks and produce turquoise as a byproduct in open-pit copper mining operations, exhibiting comparable colors, patterns, and morphologies. However, distinct differences are noted in their mineral compositions and trace elements, with turquoise from Meiduk associated with a complex hydrothermal system rich in various sulfide and oxide minerals and higher copper, Na, K, and Ca concentrations, indicating alkali-rich fluid interactions. In contrast, the turquoise from Tongling, influenced by both volcanic and sedimentary processes, shows a higher copper content, presence of barite, and different trace elements such as Be and W. The REE patterns also highlight the contrasting geological histories and environmental conditions at each site, with Meiduk samples showing a broader range of oxidation states and europium anomalies compared to the more stable REE fractionation dynamics in Tongling samples. These differences underscore the importance of detailed geochemical and mineralogical analyses for accurate provenance determination in gemmological and archaeological contexts.展开更多
In recent years,high-speed railways(HSRs)have developed rapidly with a high transportation capacity and high comfort level.A tunnel is a complex high-speed rail terrain environment.It is very important to establish an...In recent years,high-speed railways(HSRs)have developed rapidly with a high transportation capacity and high comfort level.A tunnel is a complex high-speed rail terrain environment.It is very important to establish an accurate channel propagation model for a railway tunnel environment to improve the safety of HSR operation.In this paper,a method for finite-state Markov chain(FSMC)channel modeling with least squares fitting based on non-uniform interval division is proposed.First,a path loss model is obtained according to measured data.The communication distance between the transmitter and receiver in the tunnel is non-uniformly divided into several large non-overlapping intervals based on the path loss model.Then,the Lloyd-Max quantization method is used to determine the threshold of the signal-to-noise ratio(SNR)and the channel state quantization value and obtain the FSMC state transition probability matrix.Simulation experiments show that the proposed wireless channel model has a low mean square error(MSE)and can accurately predict the received signal power in a railway tunnel environment.展开更多
Debye-screening effects on the electron-impact excitation(EIE)processes for the dipole-allowed transition 1 s_(2)^(1)S→1 s2 p^(1)P in He-like Al^(11+)and Fe^(24+)ions are investigated using the fully relativistic dis...Debye-screening effects on the electron-impact excitation(EIE)processes for the dipole-allowed transition 1 s_(2)^(1)S→1 s2 p^(1)P in He-like Al^(11+)and Fe^(24+)ions are investigated using the fully relativistic distorted-wave methods with the Debye-Huckel(DH)model potential.Debye-screening effects on the continuum-bound(CB)interaction and target ion are discussed,both of which result in reduction of EIE cross sections.This reduction due to screening on the CB interaction is dominant.The non-spherical and spherical DH potentials are adopted for considering the screening effect on the CB interaction.It is found that the spherical DH potential could significantly overestimate the influence of plasma screening on EIE cross sections for multielectron He-like ions.展开更多
The electron excitation processes of H(1s)+He(1s^(2))→H(2s/2p)+He(1s^(2))are studied in impact energy range of 20-2000 e V/u by using the quantum-mechanical molecular orbital close-coupling(QMOCC)method.Total and sta...The electron excitation processes of H(1s)+He(1s^(2))→H(2s/2p)+He(1s^(2))are studied in impact energy range of 20-2000 e V/u by using the quantum-mechanical molecular orbital close-coupling(QMOCC)method.Total and state-selective cross sections have been obtained and compared with the available theoretical and experimental results.The results agree well with available measurements in the overlapping energy regions overall.The comparison of our results with other theoretical calculations further demonstrates the importance of considering a sufficient number of channels.The datasets presented in this paper,including the excitation cross sections,are openly available at https://www.doi.org/10.57760/sciencedb.j00113.00083.展开更多
Zinc-air batteries(ZABs)are promising energy storage systems because of high theoretical energy density,safety,low cost,and abundance of zinc.However,the slow multi-step reaction of oxygen and heavy reliance on noble-...Zinc-air batteries(ZABs)are promising energy storage systems because of high theoretical energy density,safety,low cost,and abundance of zinc.However,the slow multi-step reaction of oxygen and heavy reliance on noble-metal catalysts hinder the practical applications of ZABs.Therefore,feasible and advanced non-noble-metal elec-trocatalysts for air cathodes need to be identified to promote the oxygen catalytic reaction.In this review,we initially introduced the advancement of ZABs in the past two decades and provided an overview of key developments in this field.Then,we discussed the work-ing mechanism and the design of bifunctional electrocatalysts from the perspective of morphology design,crystal structure tuning,interface strategy,and atomic engineering.We also included theoretical studies,machine learning,and advanced characterization technologies to provide a comprehensive understanding of the structure-performance relationship of electrocatalysts and the reaction pathways of the oxygen redox reactions.Finally,we discussed the challenges and prospects related to designing advanced non-noble-metal bifunctional electrocatalysts for ZABs.展开更多
The semiclassical non-perturbative atomic orbital close-coupling approach has been employed to study the electron capture and excitation processes in He^(2+)-H(1s)and He^(2+)-H(2s)collision systems.In order to ensure ...The semiclassical non-perturbative atomic orbital close-coupling approach has been employed to study the electron capture and excitation processes in He^(2+)-H(1s)and He^(2+)-H(2s)collision systems.In order to ensure the accuracy of our calculated cross sections,a large number of high excited states and pseudostates are included in the expansion basis sets which are centered on the target and projectile,respectively.The total and partial charge transfer and excitation cross sections are obtained for a wide-energy domain ranging from 1 keV/amu to 200 keV/amu.The present calculations are also compared with the results from other theoretical methods.These cross section data are useful for the investigation of astrophysics and laboratory plasma.展开更多
Soil organic carbon （SOC） is an effective indicator of soil fertility and productivity, and it varies spatially and temporally in relation to other soil properties. Spatial variability of SOC in the forestlands of n...Soil organic carbon （SOC） is an effective indicator of soil fertility and productivity, and it varies spatially and temporally in relation to other soil properties. Spatial variability of SOC in the forestlands of northeast China was characterized using geostatistics. Soil samples at the depths of 0-20 era, 20-40 cm and 40-60 cm were collected from six- ty-three temporary plots to evaluate SOC concentration and density （SOCD） and other soil properties. We analyzed correlations between SOC and soil properties. Soil organic carbon concentrations were high. The total amount of C stored in soil （0-60 cm） was 16.23 kg·m-2 with the highest SOCD of 7.98 kg·m-2 in topsoil. Soil properties in most cases differed by horizon, suggesting different processes and effects in each horizon. Soil organic carbon had positive relationships with total N, P and K as well as readily available K, but did not show a significant posi- tive correlation with available P. Spatial factors including elevation, slope and aspect affected SOC distribution. Soil organic carbon at 0-60 cm had strong spatial autocorrelation with nugget/sill ratio of 5.7%, and moderate structured dependence was found at 0-20 cm, which indicated the existence of a highly developed spatial structure. Spatial distributionsof SOC concentration and SOCD were estimated using regres- sion-kriging, with higher prediction accuracy than ordinary kriging. The fractal dimension of SOC indicated the preferential pattern of SOC dis- tribution, with the greatest spatial heterogeneity and strongest spatial dependence in the northeast-southwest direction.展开更多
Soil organic carbon(SOC)mineralization is closely related to carbon source or sink of terrestrial ecosystem.Natural stands of Larix olgensis on the Jincang forest farm,Jilin Province were selected to investigate the d...Soil organic carbon(SOC)mineralization is closely related to carbon source or sink of terrestrial ecosystem.Natural stands of Larix olgensis on the Jincang forest farm,Jilin Province were selected to investigate the dynamics of SOC mineralization and its correlations with other soil properties in a young forest and mid-aged forest at soil depths of 0–10,>10–20,>20–40 and>40–60 cm.The results showed that compared with a mid-aged forest,the SOC stock in the young forest was 32%higher.Potentially mineralizable soil carbon(C0)in the young forest was 1.1–2.5 g kg^-1,accounting for 5.5–8.1%of total SOC during the 105 days incubation period and 0.3–1.5 g kg^-1 in the mid-aged forest at different soil depths,occupying 2.8–3.4%of total SOC.There was a significant difference in C0 among the soil depths.The dynamics of the SOC mineralization was a good fit to a three-pool(labile,intermediate and stable)carbon decomposition kinetic model.The SOC decomposition rate for different stand ages and different soil depths reached high levels for the first 15 days.Correlation analysis revealed that the C0 was significantly positively related with SOC content,soil total N(TN)and readily available K(AK)concentration.The labile soil carbon pool was significantly related to SOC and TN concentration,and significantly negatively correlated with soil bulk density.The intermediate carbon pool was positively associated with TN and AK.The stable carbon pool had negative correlations with SOC,TN and AK.展开更多
The popularity of wearable devices and smartphones has fueled the development of Mobile Augmented Reality(MAR),which provides immersive experiences over the real world using techniques,such as computer vision and deep...The popularity of wearable devices and smartphones has fueled the development of Mobile Augmented Reality(MAR),which provides immersive experiences over the real world using techniques,such as computer vision and deep learning.However,the hardware-specific MAR is costly and heavy,and the App-based MAR requires an additional download and installation and it also lacks cross-platform ability.These limitations hamper the pervasive promotion of MAR.This paper argues that mobile Web AR(MWAR)holds the potential to become a practical and pervasive solution that can effectively scale to millions of end-users because MWAR can be developed as a lightweight,cross-platform,and low-cost solution for end-to-end delivery of MAR.The main challenges for making MWAR a reality lie in the low efficiency for dense computing in Web browsers,a large delay for real-time interactions over mobile networks,and the lack of standardization.The good news is that the newly emerging 5G and Beyond 5G(B5G)cellular networks can mitigate these issues to some extent via techniques such as network slicing,device-to-device communication,and mobile edge computing.In this paper,we first give an overview of the challenges and opportunities of MWAR in the 5G era.Then we describe our design and development of a generic service-oriented framework(called MWAR5)to provide a scalable,flexible,and easy to deploy MWAR solution.We evaluate the performance of our MWAR5 system in an actually deployed 5G trial network under the collaborative configurations,which shows encouraging results.Moreover,we also share the experiences and insights from our development and deployment,including some exciting future directions of MWAR over 5G and B5G networks.展开更多
BACKGROUND:This study aimed to observe the effect of early goal directed therapy(EGDT)on tissue perfusion,microcirculation and tissue oxygenation in patients with septic shock.METHODS:Patients with early septic shock(...BACKGROUND:This study aimed to observe the effect of early goal directed therapy(EGDT)on tissue perfusion,microcirculation and tissue oxygenation in patients with septic shock.METHODS:Patients with early septic shock(<24 hours) who had been admitted to the ICU of Zhongda Hospital Affiliated to Southeast University from September 2009 through May 2011 were enrolled(research time:12 months),and they didn't meet the criteria of EGDT.Patients who had one of the following were excluded:stroke,brain injury,other types of shock,severe heart failure,acute myocardial infarction,age below 18 years,pregnancy,end-stage disease,cardiac arrest,extensive burns,oral bleeding,difficulty in opening the mouth,and the onset of septic shock beyond 24 hours.Patients treated with the standard protocol of EGDT were included.Transcutaneous pressure of oxygen and carbon dioxide(PtcO_2,PtcCO_2) were monitored and hemodynamic measurements were obtained.Side-stream dark field(SDF) imaging device was applied to obtain sublingual microcirculation.Hemodynamics,tissue oxygen,and sublingual microcirculation were compared before and after EGDT.If the variable meets the normal distribution,Student's t test was applied.Otherwise,Wilcoxon's rank-sum test was used.Correlation between variables was analyzed with Pearson's product-moment correlation coefficient method.RESULTS:Twenty patients were involved,but one patient wasn't analyzed because he didn't meet the EGDT criteria.PtcO_2 and PtcCO_2 were monitored in 19 patients,of whom sublingual microcirculation was obtained.After EGDT,PtcO_2 increased from 62.7+24.0 mmHg to 78.0±30.9mmHg(P<0.05) and tissue oxygenation index(PtcO_2/FiO_2) was 110.7+60.4 mmHg before EGDT and 141.6±78.2 mmHg after EGDT(P<0.05).The difference between PtcCO_2 and PCO_2 decreased significantly after EGDT(P<0.05).The density of perfused small vessels(PPV) and microcirculatory flow index of small vessels(MFI) tended to increase,but there were no significant differences between them(P>0.05).PtcO_2,PtcO_2/FiO_2,and PtcCO_2 were not linearly related to central venous saturation,lactate,oxygen delivery,and oxygen consumption(P>0.05).CONCLUSION:Peripheral perfusion was improved after EGDT in patients with septic shock,and it was not exactly reflected by the index of systemic perfusion.展开更多
Background:The masses of-2500 nuclei have been measured experimentally;however,>7000 isotopes are predicted to exist in the nuclear landscape from H(Z=1)to Og(Z=118)based on various theoretical calculations.Explori...Background:The masses of-2500 nuclei have been measured experimentally;however,>7000 isotopes are predicted to exist in the nuclear landscape from H(Z=1)to Og(Z=118)based on various theoretical calculations.Exploring the mass of the remaining isotopes is a popular topic in nuclear physics.Machine learning has served as a powerful tool for learning complex representations of big data in many fields.Purpose:We use Light Gradient Boosting Machine(LightGBM),which is a highly efficient machine learning algorithm,to predict the masses of unknown nuclei and to explore the nuclear landscape on the neutron-rich side from learning the measured nuclear masses.Methods:Several characteristic quantities(e.g.,mass number and proton number)are fed into the LightGBM algorithm to mimic the patterns of the residual δ(Z,A)between the experimental binding energy and the theoret-ical one given by the liquid-drop model(LDM),Duflo–Zucker(DZ,also dubbed DZ28)mass model,finite-range droplet model(FRDM,also dubbed FRDM2012),as well as the Weizsacker–Skyrme(WS4)model to refine these mass models.Results:By using the experimental data of 80%of known nuclei as the training dataset,the root mean square devia-tions(RMSDs)between the predicted and the experimental binding energy of the remaining 20%are approximately 0.234±0.022,0.213±0.018,0.170±0.011,and 0.222±0.016 MeV for the LightGBM-refined LDM,DZ model,WS4 model,and FRDM,respectively.These values are approximately 90%,65%,40%,and 60%smaller than those of the corresponding origin mass models.The RMSD for 66 newly measured nuclei that appeared in AME2020 was also significantly improved.The one-neutron and two-neutron separation energies predicted by these refined models are consistent with several theoretical predictions based on various physical models.In addition,the two-neutron separation energies of several newly measured nuclei(e.g.,some isotopes of Ca,Ti,Pm,and Sm)pre-dicted with LightGBM-refined mass models are also in good agreement with the latest experimental data.Conclusions:LightGBM can be used to refine theoretical nuclear mass models and predict the binding energy of unknown nuclei.Moreover,the correlation between the input characteristic quantities and the output can be inter-preted by SHapley additive exPlanations(a popular explainable artificial intelligence tool),which may provide new insights for developing theoretical nuclear mass models.展开更多
We estimated forest biomass carbon storage and carbon density from 1949 to 2008 based on nine consecutive forest inventories in Henan Province,China.According to the definitions of the forest inventory,Henan forests w...We estimated forest biomass carbon storage and carbon density from 1949 to 2008 based on nine consecutive forest inventories in Henan Province,China.According to the definitions of the forest inventory,Henan forests were categorized into five groups: forest stands,economic forests,bamboo forests,open forests,and shrub forests.We estimated biomass carbon in forest stands for each inventory period by using the continuous biomass expansion factor method.We used the mean biomass density method to estimate carbon stocks in economic,bamboo,open and shrub forests.Over the 60-year period,total forest vegetation carbon storage increased from34.6 Tg(1 Tg = 1×10;g) in 1949 to 80.4 Tg in 2008,a net vegetation carbon increase of 45.8 Tg.By stand type,increases were 39.8 Tg in forest stands,5.5 Tg in economic forests,0.6 Tg in bamboo forests,and-0.1 Tg in open forests combine shrub forests.Carbon storageincreased at an average annual rate of 0.8 Tg carbon over the study period.Carbon was mainly stored in young and middle-aged forests,which together accounted for 70–88%of the total forest carbon storage in different inventory periods.Broad-leaved forest was the main contributor to forest carbon sequestration.From 1998 to 2008,during implementation of national afforestation and reforestation programs,the carbon storage of planted forest increased sharply from 3.9 to 37.9 Tg.Our results show that with the growth of young planted forest,Henan Province forests realized large gains in carbon sequestration over a 60-year period that was characterized in part by a nation-wide tree planting program.展开更多
After fast developing of single-junction perovskite solar cells and organic solar cells in the past 10 years,it is becoming harder and harder to improve their power conversion efficiencies.Tandem solar cells are recei...After fast developing of single-junction perovskite solar cells and organic solar cells in the past 10 years,it is becoming harder and harder to improve their power conversion efficiencies.Tandem solar cells are receiving more and more attention because they have much higher theoretical efficiency than single-junction solar cells.Good device performance has been achieved for perovskite/silicon and perovskite/perovskite tandem solar cells,including 2-terminal and 4-terminal structures.However,very few studies have been done about 4-terminal inorganic perovskite/organic tandem solar cells.In this work,semi-transparent inorganic perovskite solar cells and organic solar cells are used to fabricate 4-terminal inorganic perovskite/organic tandem solar cells,achieving a power conversion efficiency of 21.25%for the tandem cells with spin-coated perovskite layer.By using drop-coating instead of spin-coating to make the inorganic perovskite films,4-terminal tandem cells with an efficiency of 22.34%are made.The efficiency is higher than the reported 2-terminal and 4-terminal inorganic perovskite/organic tandem solar cells.In addition,equivalent 2-terminal tandem solar cells were fabricated by connecting the sub-cells in series.The stability of organic solar cells under continuous illumination is improved by using semi-transparent perovskite solar cells as filter.展开更多
Lithium metal batteries represent promising candidates for high-energy-density batteries, however, many challenges must still be overcome,e.g., interface instability and dendrite growth. In this work, nano silica aero...Lithium metal batteries represent promising candidates for high-energy-density batteries, however, many challenges must still be overcome,e.g., interface instability and dendrite growth. In this work, nano silica aerogel was employed to generate a hybrid film with high lithium ion conductivity(0.6 mS cm^(-1)at room temperature) via an in situ crosslinking reaction. TOF-SIMS profile analysis has revealed conversion mechanism of hybrid film to Li–Si alloy/Li F biphasic interface layer, suggesting that the Li–Si alloy and Li F-rich interface layer promoted rapid Li+transport and shielded the Li anodes from corrosive reactions with electrolyte-derived products. When coupled with nickel-cobalt-manganese-based cathodes, the batteries achieve outstanding capacity retention over 1000 cycles at 1 C. Additionally the developed film coated on Li enabled high coulombic efficiency(99.5%) after long-term cycling when coupled with S cathodes. Overall, the results presented herein confirm an effective strategy for the development of high-energy batteries.展开更多
Development of high-performance and cost-effective catalysts for electrocatalytic hydrogen evolution reaction(HER)play crucial role in the growing hydrogen economy.Recently,the atomically dispersed metal catalysts hav...Development of high-performance and cost-effective catalysts for electrocatalytic hydrogen evolution reaction(HER)play crucial role in the growing hydrogen economy.Recently,the atomically dispersed metal catalysts have attracted increasing attention due to their ultimate atom utilization and great potential for highly cost-effective and high-efficiency HER electrocatalyst.Herein,we propose a hightemperature treatment strategy to furtherly improve the HER performance of atomically dispersed Ptbased catalyst.Interestingly,after appropriate high-temperature treatment on the atomically dispersed Pt0.8@CN,the Pt species on the designed N-doped porous carbon substrate with rich defect sites can be re-dispersed to single atom state with new coordination environment.The obtained Pt0.8@CN-1000 shows superior HER performance with overpotential of 13 m V at 10 m A cm^(-2)and mass activity of 11,284 m A/mgPtat-0.1 V,much higher than that of the pristine Pt0.8@CN and commercial Pt/C catalyst.The experimental and theoretical investigations indicate that the high-temperature treatment induces the restructuring of coordination environment and then the optimized Pt electronic state leads to the enhanced HER performances.This work affords new strategy and insights to develop the atomically dispersed high-efficiency catalysts.展开更多
All-inorganic,hole-transporting-layer-free CsPbIBr_(2)perovskite solar cells have great potential for development,but their device performance needs to be further improved.Recently,metal nanostructures have been succe...All-inorganic,hole-transporting-layer-free CsPbIBr_(2)perovskite solar cells have great potential for development,but their device performance needs to be further improved.Recently,metal nanostructures have been successfully applied in the field of solar cells to improve their performance.Nano Ag-enhanced power conversion efficiency(PCE)in one CsPbIBr_(2)perovskite solar cell utilizing localized surface plasmons of Ag nanoparticles(NPs)on the surface has been researched experimentally and by simulation in this paper.The localized surface plasmon resonance of Ag NPs has a near-field enhancement effect,which is expected to improve the light absorption of CsPbIBr_(2)perovskite photovoltaic devices.In addition,Ag NPs have a forward-scattering effect on the incident light,which can also improve the performance of CsPbIBr_(2)-based perovskite photovoltaic devices.By directly assembling Ag NPs(with a size of about 150 nm)on the surface of fluorine-doped tin oxide it is found when the particle surface coverage is 10%,the CsPbIBr_(2)perovskite photovoltaic device achieves a best PCE of 2.7%,which is 9.76%higher than that of the control group.Without changing any existing structure in the ready-made solar cell,this facile and efficient method has huge applications.To the best of our knowledge,this paper is the first report on nano Ag-enhanced photoelectric conversion efficiency in this kind of CsPbIBr_(2)perovskite solar cell.展开更多
文摘Turquoise, a hydrous phosphate of copper and aluminum, is highly valued for its unique colour and historical significance. The similarity in colour, quality, and pattern between turquoises from different localities may lead to confusion in determining their origins. This is particularly evident in the case of turquoises from Meiduk in Iran and Tongling in China(Fig.1).In Iran, turquoise deposits are typically associated with magmatic zones, specifically in the Meiduk mine, located 85 kilometers northwest of the Sar Cheshmeh porphyry copper deposit in Kerman Province. The deposit is hosted by Eocene volcanic rocks of andesitic-basaltic composition with porphyry-type mineralization associated with two Miocene calc-alkaline intrusive phases. Five distinct zones of the hypogene alteration include potassic, potassic-phyllic, phyllic, and propylitic zones, which are rich in magnetite. Mineralization processes include stockwork, dissemination, veinlets, and veins rich in garnet, chalcopyrite, magnetite, and anhydrite. Turquoise is found in transitional, leached, and supergene zones, primarily as fracture and seam fillers. In contrast, Chinese turquoises are more often found in sedimentary rocks, with significant exceptions in places like the Tongling mine in Anhui Province, which are hosted within magmatic rocks. The turquoise from Tongling is found in the Tongling area within the Middle-lower Yangtze Metallogenic Belt, an area characterized by complex tectonics and intense magmatic and metallogenic activities. The turquoise deposits are associated with iron-copper polymetallic mineralization within Early Cretaceous volcanic rocks.The turquoise from Meiduk exhibited a specific gravity range of 2.22 g/cm^(3)to 2.71 g/cm^(3), SWUV fluorescence from none to medium, and LWUV fluorescence from faint to strong, indicating diverse mineralogical compositions. SEM examination of turquoise from Meiduk reveals a variety of mineral morphologies. The turquoise displays closely packed arrays of elongated needle-like crystals, measuring 2 μm to 9 μm in length and 0.1 μm to 0.4 μm in thickness, indicating a dynamic growth environment. The density and alignment of these crystals suggest the space-constrained setting, likely influenced by rapid deposition from mineral-laden fluids, with crystals interlocked due to simultaneous nucleation events. Some crystals appear similarly elongated but are more dispersed, with greater separation between individual crystals. In other areas, the elongated turquoise crystals are tightly intergrown, creating a dense textural appearance, pointing to a stage where growth space became limited, resulting in an interlocking matrix. Additionally, some crystals radiate outward from a central point, forming a spherical pattern reaching about 18 μm. The turquoise from Tongling show a specific gravity range of 2.26 g/cm^(3)to 2.60 g/cm^(3), with consistent medium SWUV fluorescence and strong LWUV fluorescence. SEM examination reveals needle structures, plate-like structures, and spheroidal aggregates composed of needle and plate-like microcrystals. These spherical aggregates, some with diameters around 26 μm, exhibit the concentric growth structure covered by turquoise microcrystals, with crystal lengths of 8 μm. The surface needle-like microcrystals vary in size, approximately 3 μm in length, 2 μm in width, and 0.2 to 0.6 μm in thickness.Optical microscopy, Raman and FTIR spectroscopy reported the presence of quartz, gypsum, iron oxides such as jarosite and goethite, biotite, sericite, pyrite, galena, bornite, graphene oxide, malachite, and azurite as major associated minerals of Meiduk's. In contrast, the Tongling mine features minerals such as quartz, anatase, barite, sodium feldspar, illite, and malachite.Through EPMA and LA-ICP-MS results, the turquoises of Tongling exhibit similar average iron content(1.28% and 1.26% respectively), but significant differences in copper content. The turquoises of Meiduk have the average copper content of 6.97%, whereas Tongling samples show the higher content of 11.38%. Na, K, and Ca concentrations are also higher in Meiduk samples, suggesting interaction with alkali-rich fluids and potassic alteration. Trace elements such as Ti, Cr, Zn, Se, and Mo serve as tracing agents for Meiduk samples, while Be and W are associated with Tongling samples. Regarding rare earth elements(REEs), Meiduk samples show diverse δCe(0.14-4.62) and δEu(0.65-15.78) values, indicating a wide range of oxidation states and europium anomalies. The significant variability in LREE/HREE ratios(0.39-31.74) and ΣREE concentrations(0.25-240.72 ppm) suggests heterogeneous REE fractionation patterns. In contrast, Tongling samples display δCe(0.070-2.51) and δEu(0.238-4.87) ranges, with more consistent LREE/HREE ratios(0.128-10.2) and ΣREE values(0.069-4.08 ppm), indicating stable REE fractionation dynamics.This comparative study of turquoises from the Meiduk mine in Iran and the Tongling mine in China reveals significant similarities and differences in their geochemical and mineralogical characteristics. Both deposits are hosted within magmatic rocks and produce turquoise as a byproduct in open-pit copper mining operations, exhibiting comparable colors, patterns, and morphologies. However, distinct differences are noted in their mineral compositions and trace elements, with turquoise from Meiduk associated with a complex hydrothermal system rich in various sulfide and oxide minerals and higher copper, Na, K, and Ca concentrations, indicating alkali-rich fluid interactions. In contrast, the turquoise from Tongling, influenced by both volcanic and sedimentary processes, shows a higher copper content, presence of barite, and different trace elements such as Be and W. The REE patterns also highlight the contrasting geological histories and environmental conditions at each site, with Meiduk samples showing a broader range of oxidation states and europium anomalies compared to the more stable REE fractionation dynamics in Tongling samples. These differences underscore the importance of detailed geochemical and mineralogical analyses for accurate provenance determination in gemmological and archaeological contexts.
基金partially supported by Nation Science Foundation of China (61661025, 61661026)Foundation of A hundred Youth Talents Training Program of Lanzhou Jiaotong University (152022)
文摘In recent years,high-speed railways(HSRs)have developed rapidly with a high transportation capacity and high comfort level.A tunnel is a complex high-speed rail terrain environment.It is very important to establish an accurate channel propagation model for a railway tunnel environment to improve the safety of HSR operation.In this paper,a method for finite-state Markov chain(FSMC)channel modeling with least squares fitting based on non-uniform interval division is proposed.First,a path loss model is obtained according to measured data.The communication distance between the transmitter and receiver in the tunnel is non-uniformly divided into several large non-overlapping intervals based on the path loss model.Then,the Lloyd-Max quantization method is used to determine the threshold of the signal-to-noise ratio(SNR)and the channel state quantization value and obtain the FSMC state transition probability matrix.Simulation experiments show that the proposed wireless channel model has a low mean square error(MSE)and can accurately predict the received signal power in a railway tunnel environment.
基金Project supported by the Science Challenge Project(Grant No.TZ2016001)the National Key Research and Development Program of China(Grants Nos.2017YFA0403200 and 2017YFA0402300)+1 种基金the Funds for Innovative Fundamental Research Group Project of Gansu Province,China(Grant No.20JR5RA541)the National Natural Science Foundation of China(Grants Nos.11774037 and 12064041)。
文摘Debye-screening effects on the electron-impact excitation(EIE)processes for the dipole-allowed transition 1 s_(2)^(1)S→1 s2 p^(1)P in He-like Al^(11+)and Fe^(24+)ions are investigated using the fully relativistic distorted-wave methods with the Debye-Huckel(DH)model potential.Debye-screening effects on the continuum-bound(CB)interaction and target ion are discussed,both of which result in reduction of EIE cross sections.This reduction due to screening on the CB interaction is dominant.The non-spherical and spherical DH potentials are adopted for considering the screening effect on the CB interaction.It is found that the spherical DH potential could significantly overestimate the influence of plasma screening on EIE cross sections for multielectron He-like ions.
基金supported by the National Natural Science Foundation of China(Grant Nos.12204288,11934004,and 12274040)
文摘The electron excitation processes of H(1s)+He(1s^(2))→H(2s/2p)+He(1s^(2))are studied in impact energy range of 20-2000 e V/u by using the quantum-mechanical molecular orbital close-coupling(QMOCC)method.Total and state-selective cross sections have been obtained and compared with the available theoretical and experimental results.The results agree well with available measurements in the overlapping energy regions overall.The comparison of our results with other theoretical calculations further demonstrates the importance of considering a sufficient number of channels.The datasets presented in this paper,including the excitation cross sections,are openly available at https://www.doi.org/10.57760/sciencedb.j00113.00083.
基金the Natural Science Foundation of China(Grant No:22309180)Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No:XDB0600000,XDB0600400)+3 种基金Liaoning Binhai Laboratory,(Grant No:LILBLB-2023-04)Dalian Revitalization Talents Program(Grant No:2022RG01)Youth Science and Technology Foundation of Dalian(Grant No:2023RQ015)the University of Waterloo.
文摘Zinc-air batteries(ZABs)are promising energy storage systems because of high theoretical energy density,safety,low cost,and abundance of zinc.However,the slow multi-step reaction of oxygen and heavy reliance on noble-metal catalysts hinder the practical applications of ZABs.Therefore,feasible and advanced non-noble-metal elec-trocatalysts for air cathodes need to be identified to promote the oxygen catalytic reaction.In this review,we initially introduced the advancement of ZABs in the past two decades and provided an overview of key developments in this field.Then,we discussed the work-ing mechanism and the design of bifunctional electrocatalysts from the perspective of morphology design,crystal structure tuning,interface strategy,and atomic engineering.We also included theoretical studies,machine learning,and advanced characterization technologies to provide a comprehensive understanding of the structure-performance relationship of electrocatalysts and the reaction pathways of the oxygen redox reactions.Finally,we discussed the challenges and prospects related to designing advanced non-noble-metal bifunctional electrocatalysts for ZABs.
基金supported by the National Key Research and Development Program of China (Grant No.2022YFA 1602500)the National Natural Science Foundation of China (Grant Nos.11934004 and 12241410).
文摘The semiclassical non-perturbative atomic orbital close-coupling approach has been employed to study the electron capture and excitation processes in He^(2+)-H(1s)and He^(2+)-H(2s)collision systems.In order to ensure the accuracy of our calculated cross sections,a large number of high excited states and pseudostates are included in the expansion basis sets which are centered on the target and projectile,respectively.The total and partial charge transfer and excitation cross sections are obtained for a wide-energy domain ranging from 1 keV/amu to 200 keV/amu.The present calculations are also compared with the results from other theoretical methods.These cross section data are useful for the investigation of astrophysics and laboratory plasma.
基金supported by Natural ScienceFoundation of China(No.31270697)the Fundamental Research Fundsfor the Central Universities(TD2011-2)+1 种基金State Forestry Administrative public service sector project"Key management techniques for the health of typical forest types in China"(20100400201)National‘973’project"Soil carbon stock and its temporal and spatial distribution pattern in natural forests"(2011CB403201)
文摘Soil organic carbon （SOC） is an effective indicator of soil fertility and productivity, and it varies spatially and temporally in relation to other soil properties. Spatial variability of SOC in the forestlands of northeast China was characterized using geostatistics. Soil samples at the depths of 0-20 era, 20-40 cm and 40-60 cm were collected from six- ty-three temporary plots to evaluate SOC concentration and density （SOCD） and other soil properties. We analyzed correlations between SOC and soil properties. Soil organic carbon concentrations were high. The total amount of C stored in soil （0-60 cm） was 16.23 kg·m-2 with the highest SOCD of 7.98 kg·m-2 in topsoil. Soil properties in most cases differed by horizon, suggesting different processes and effects in each horizon. Soil organic carbon had positive relationships with total N, P and K as well as readily available K, but did not show a significant posi- tive correlation with available P. Spatial factors including elevation, slope and aspect affected SOC distribution. Soil organic carbon at 0-60 cm had strong spatial autocorrelation with nugget/sill ratio of 5.7%, and moderate structured dependence was found at 0-20 cm, which indicated the existence of a highly developed spatial structure. Spatial distributionsof SOC concentration and SOCD were estimated using regres- sion-kriging, with higher prediction accuracy than ordinary kriging. The fractal dimension of SOC indicated the preferential pattern of SOC dis- tribution, with the greatest spatial heterogeneity and strongest spatial dependence in the northeast-southwest direction.
基金jointly supported by National Key R&D Program of China(Grant No.2017YFC0504002)Natural Science Foundation of China(No.31270679)
文摘Soil organic carbon(SOC)mineralization is closely related to carbon source or sink of terrestrial ecosystem.Natural stands of Larix olgensis on the Jincang forest farm,Jilin Province were selected to investigate the dynamics of SOC mineralization and its correlations with other soil properties in a young forest and mid-aged forest at soil depths of 0–10,>10–20,>20–40 and>40–60 cm.The results showed that compared with a mid-aged forest,the SOC stock in the young forest was 32%higher.Potentially mineralizable soil carbon(C0)in the young forest was 1.1–2.5 g kg^-1,accounting for 5.5–8.1%of total SOC during the 105 days incubation period and 0.3–1.5 g kg^-1 in the mid-aged forest at different soil depths,occupying 2.8–3.4%of total SOC.There was a significant difference in C0 among the soil depths.The dynamics of the SOC mineralization was a good fit to a three-pool(labile,intermediate and stable)carbon decomposition kinetic model.The SOC decomposition rate for different stand ages and different soil depths reached high levels for the first 15 days.Correlation analysis revealed that the C0 was significantly positively related with SOC content,soil total N(TN)and readily available K(AK)concentration.The labile soil carbon pool was significantly related to SOC and TN concentration,and significantly negatively correlated with soil bulk density.The intermediate carbon pool was positively associated with TN and AK.The stable carbon pool had negative correlations with SOC,TN and AK.
基金supported in part by the National Key R&D Program of China under Grant 2018YFE0205503in part by the National Natural Science Foundation of China (NSFC) under Grant 61671081+4 种基金in part by the Funds for International Cooperation and Exchange of NSFC under Grant 61720106007in part by the 111 Project under Grant B18008in part by the Beijing Natural Science Foundation under Grant 4172042in part by the Fundamental Research Funds for the Central Universities under Grant 2018XKJC01in part by the BUPT Excellent Ph.D. Students Foundation under Grant CX2019213
文摘The popularity of wearable devices and smartphones has fueled the development of Mobile Augmented Reality(MAR),which provides immersive experiences over the real world using techniques,such as computer vision and deep learning.However,the hardware-specific MAR is costly and heavy,and the App-based MAR requires an additional download and installation and it also lacks cross-platform ability.These limitations hamper the pervasive promotion of MAR.This paper argues that mobile Web AR(MWAR)holds the potential to become a practical and pervasive solution that can effectively scale to millions of end-users because MWAR can be developed as a lightweight,cross-platform,and low-cost solution for end-to-end delivery of MAR.The main challenges for making MWAR a reality lie in the low efficiency for dense computing in Web browsers,a large delay for real-time interactions over mobile networks,and the lack of standardization.The good news is that the newly emerging 5G and Beyond 5G(B5G)cellular networks can mitigate these issues to some extent via techniques such as network slicing,device-to-device communication,and mobile edge computing.In this paper,we first give an overview of the challenges and opportunities of MWAR in the 5G era.Then we describe our design and development of a generic service-oriented framework(called MWAR5)to provide a scalable,flexible,and easy to deploy MWAR solution.We evaluate the performance of our MWAR5 system in an actually deployed 5G trial network under the collaborative configurations,which shows encouraging results.Moreover,we also share the experiences and insights from our development and deployment,including some exciting future directions of MWAR over 5G and B5G networks.
文摘BACKGROUND:This study aimed to observe the effect of early goal directed therapy(EGDT)on tissue perfusion,microcirculation and tissue oxygenation in patients with septic shock.METHODS:Patients with early septic shock(<24 hours) who had been admitted to the ICU of Zhongda Hospital Affiliated to Southeast University from September 2009 through May 2011 were enrolled(research time:12 months),and they didn't meet the criteria of EGDT.Patients who had one of the following were excluded:stroke,brain injury,other types of shock,severe heart failure,acute myocardial infarction,age below 18 years,pregnancy,end-stage disease,cardiac arrest,extensive burns,oral bleeding,difficulty in opening the mouth,and the onset of septic shock beyond 24 hours.Patients treated with the standard protocol of EGDT were included.Transcutaneous pressure of oxygen and carbon dioxide(PtcO_2,PtcCO_2) were monitored and hemodynamic measurements were obtained.Side-stream dark field(SDF) imaging device was applied to obtain sublingual microcirculation.Hemodynamics,tissue oxygen,and sublingual microcirculation were compared before and after EGDT.If the variable meets the normal distribution,Student's t test was applied.Otherwise,Wilcoxon's rank-sum test was used.Correlation between variables was analyzed with Pearson's product-moment correlation coefficient method.RESULTS:Twenty patients were involved,but one patient wasn't analyzed because he didn't meet the EGDT criteria.PtcO_2 and PtcCO_2 were monitored in 19 patients,of whom sublingual microcirculation was obtained.After EGDT,PtcO_2 increased from 62.7+24.0 mmHg to 78.0±30.9mmHg(P<0.05) and tissue oxygenation index(PtcO_2/FiO_2) was 110.7+60.4 mmHg before EGDT and 141.6±78.2 mmHg after EGDT(P<0.05).The difference between PtcCO_2 and PCO_2 decreased significantly after EGDT(P<0.05).The density of perfused small vessels(PPV) and microcirculatory flow index of small vessels(MFI) tended to increase,but there were no significant differences between them(P>0.05).PtcO_2,PtcO_2/FiO_2,and PtcCO_2 were not linearly related to central venous saturation,lactate,oxygen delivery,and oxygen consumption(P>0.05).CONCLUSION:Peripheral perfusion was improved after EGDT in patients with septic shock,and it was not exactly reflected by the index of systemic perfusion.
基金This work was supported in part by the National Science Foundation of China(Nos.U2032145,11875125,12047568,11790323,11790325,and 12075085)the National Key Research and Development Program of China(No.2020YFE0202002)the"Ten Thousand Talent Program"of Zhejiang Province(No.2018R52017).
文摘Background:The masses of-2500 nuclei have been measured experimentally;however,>7000 isotopes are predicted to exist in the nuclear landscape from H(Z=1)to Og(Z=118)based on various theoretical calculations.Exploring the mass of the remaining isotopes is a popular topic in nuclear physics.Machine learning has served as a powerful tool for learning complex representations of big data in many fields.Purpose:We use Light Gradient Boosting Machine(LightGBM),which is a highly efficient machine learning algorithm,to predict the masses of unknown nuclei and to explore the nuclear landscape on the neutron-rich side from learning the measured nuclear masses.Methods:Several characteristic quantities(e.g.,mass number and proton number)are fed into the LightGBM algorithm to mimic the patterns of the residual δ(Z,A)between the experimental binding energy and the theoret-ical one given by the liquid-drop model(LDM),Duflo–Zucker(DZ,also dubbed DZ28)mass model,finite-range droplet model(FRDM,also dubbed FRDM2012),as well as the Weizsacker–Skyrme(WS4)model to refine these mass models.Results:By using the experimental data of 80%of known nuclei as the training dataset,the root mean square devia-tions(RMSDs)between the predicted and the experimental binding energy of the remaining 20%are approximately 0.234±0.022,0.213±0.018,0.170±0.011,and 0.222±0.016 MeV for the LightGBM-refined LDM,DZ model,WS4 model,and FRDM,respectively.These values are approximately 90%,65%,40%,and 60%smaller than those of the corresponding origin mass models.The RMSD for 66 newly measured nuclei that appeared in AME2020 was also significantly improved.The one-neutron and two-neutron separation energies predicted by these refined models are consistent with several theoretical predictions based on various physical models.In addition,the two-neutron separation energies of several newly measured nuclei(e.g.,some isotopes of Ca,Ti,Pm,and Sm)pre-dicted with LightGBM-refined mass models are also in good agreement with the latest experimental data.Conclusions:LightGBM can be used to refine theoretical nuclear mass models and predict the binding energy of unknown nuclei.Moreover,the correlation between the input characteristic quantities and the output can be inter-preted by SHapley additive exPlanations(a popular explainable artificial intelligence tool),which may provide new insights for developing theoretical nuclear mass models.
基金funded by the National Key Research and Development Program of China(2016YFC0501605)the National Sci-Tech Basic Program of China(2014FY210100)+1 种基金the National Natural Science foundation of China(31200332)the University Youth Teacher Training Program by Education Department of Henan Province(2016GGJS-062)
文摘We estimated forest biomass carbon storage and carbon density from 1949 to 2008 based on nine consecutive forest inventories in Henan Province,China.According to the definitions of the forest inventory,Henan forests were categorized into five groups: forest stands,economic forests,bamboo forests,open forests,and shrub forests.We estimated biomass carbon in forest stands for each inventory period by using the continuous biomass expansion factor method.We used the mean biomass density method to estimate carbon stocks in economic,bamboo,open and shrub forests.Over the 60-year period,total forest vegetation carbon storage increased from34.6 Tg(1 Tg = 1×10;g) in 1949 to 80.4 Tg in 2008,a net vegetation carbon increase of 45.8 Tg.By stand type,increases were 39.8 Tg in forest stands,5.5 Tg in economic forests,0.6 Tg in bamboo forests,and-0.1 Tg in open forests combine shrub forests.Carbon storageincreased at an average annual rate of 0.8 Tg carbon over the study period.Carbon was mainly stored in young and middle-aged forests,which together accounted for 70–88%of the total forest carbon storage in different inventory periods.Broad-leaved forest was the main contributor to forest carbon sequestration.From 1998 to 2008,during implementation of national afforestation and reforestation programs,the carbon storage of planted forest increased sharply from 3.9 to 37.9 Tg.Our results show that with the growth of young planted forest,Henan Province forests realized large gains in carbon sequestration over a 60-year period that was characterized in part by a nation-wide tree planting program.
基金We thank the National Key Research and Development Program of China(2022YFB3803300)the open research fund of Songshan Lake Materials Laboratory(2021SLABFK02)+1 种基金the National Natural Science Foundation of China(21961160720 and 52203217)the China Postdoctoral Science Foundation(2021M690805)for financial support.
文摘After fast developing of single-junction perovskite solar cells and organic solar cells in the past 10 years,it is becoming harder and harder to improve their power conversion efficiencies.Tandem solar cells are receiving more and more attention because they have much higher theoretical efficiency than single-junction solar cells.Good device performance has been achieved for perovskite/silicon and perovskite/perovskite tandem solar cells,including 2-terminal and 4-terminal structures.However,very few studies have been done about 4-terminal inorganic perovskite/organic tandem solar cells.In this work,semi-transparent inorganic perovskite solar cells and organic solar cells are used to fabricate 4-terminal inorganic perovskite/organic tandem solar cells,achieving a power conversion efficiency of 21.25%for the tandem cells with spin-coated perovskite layer.By using drop-coating instead of spin-coating to make the inorganic perovskite films,4-terminal tandem cells with an efficiency of 22.34%are made.The efficiency is higher than the reported 2-terminal and 4-terminal inorganic perovskite/organic tandem solar cells.In addition,equivalent 2-terminal tandem solar cells were fabricated by connecting the sub-cells in series.The stability of organic solar cells under continuous illumination is improved by using semi-transparent perovskite solar cells as filter.
基金the support from National Natural Science Foundation of China (22179006)International Science & Technology Cooperation Program of China under Contract No.2019YFE0100200+3 种基金National Natural Science Foundation of China (52072036)NSAF (No.U1930113)Guangdong Key Laboratory of Battery Safety,China (No.2019B121203008)China Postdoctoral Science Foundation (No.2021TQ0034)。
文摘Lithium metal batteries represent promising candidates for high-energy-density batteries, however, many challenges must still be overcome,e.g., interface instability and dendrite growth. In this work, nano silica aerogel was employed to generate a hybrid film with high lithium ion conductivity(0.6 mS cm^(-1)at room temperature) via an in situ crosslinking reaction. TOF-SIMS profile analysis has revealed conversion mechanism of hybrid film to Li–Si alloy/Li F biphasic interface layer, suggesting that the Li–Si alloy and Li F-rich interface layer promoted rapid Li+transport and shielded the Li anodes from corrosive reactions with electrolyte-derived products. When coupled with nickel-cobalt-manganese-based cathodes, the batteries achieve outstanding capacity retention over 1000 cycles at 1 C. Additionally the developed film coated on Li enabled high coulombic efficiency(99.5%) after long-term cycling when coupled with S cathodes. Overall, the results presented herein confirm an effective strategy for the development of high-energy batteries.
基金financially supported by the National Science Foundation of China(21773112,21173119,and 21273109)the National Key Technology R&D Program of China(2017YFB0310704)the Fundamental Research Funds for the Central Universities and the Hubei Key Laboratory for Processing and Application of Catalytic Materials(CH201401)。
文摘Development of high-performance and cost-effective catalysts for electrocatalytic hydrogen evolution reaction(HER)play crucial role in the growing hydrogen economy.Recently,the atomically dispersed metal catalysts have attracted increasing attention due to their ultimate atom utilization and great potential for highly cost-effective and high-efficiency HER electrocatalyst.Herein,we propose a hightemperature treatment strategy to furtherly improve the HER performance of atomically dispersed Ptbased catalyst.Interestingly,after appropriate high-temperature treatment on the atomically dispersed Pt0.8@CN,the Pt species on the designed N-doped porous carbon substrate with rich defect sites can be re-dispersed to single atom state with new coordination environment.The obtained Pt0.8@CN-1000 shows superior HER performance with overpotential of 13 m V at 10 m A cm^(-2)and mass activity of 11,284 m A/mgPtat-0.1 V,much higher than that of the pristine Pt0.8@CN and commercial Pt/C catalyst.The experimental and theoretical investigations indicate that the high-temperature treatment induces the restructuring of coordination environment and then the optimized Pt electronic state leads to the enhanced HER performances.This work affords new strategy and insights to develop the atomically dispersed high-efficiency catalysts.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11504264,21802092,51501128,52072005,and 51872279)the Scientific Research Plan Project of Tianjin Municipal Education Commission(Grant No.2017KJ097)
文摘All-inorganic,hole-transporting-layer-free CsPbIBr_(2)perovskite solar cells have great potential for development,but their device performance needs to be further improved.Recently,metal nanostructures have been successfully applied in the field of solar cells to improve their performance.Nano Ag-enhanced power conversion efficiency(PCE)in one CsPbIBr_(2)perovskite solar cell utilizing localized surface plasmons of Ag nanoparticles(NPs)on the surface has been researched experimentally and by simulation in this paper.The localized surface plasmon resonance of Ag NPs has a near-field enhancement effect,which is expected to improve the light absorption of CsPbIBr_(2)perovskite photovoltaic devices.In addition,Ag NPs have a forward-scattering effect on the incident light,which can also improve the performance of CsPbIBr_(2)-based perovskite photovoltaic devices.By directly assembling Ag NPs(with a size of about 150 nm)on the surface of fluorine-doped tin oxide it is found when the particle surface coverage is 10%,the CsPbIBr_(2)perovskite photovoltaic device achieves a best PCE of 2.7%,which is 9.76%higher than that of the control group.Without changing any existing structure in the ready-made solar cell,this facile and efficient method has huge applications.To the best of our knowledge,this paper is the first report on nano Ag-enhanced photoelectric conversion efficiency in this kind of CsPbIBr_(2)perovskite solar cell.
