Electrolyte design holds the greatest opportunity for the development of batteries that are capable of sub-zero temperature operation.To get the most energy storage out of the battery at low temperatures,improvements ...Electrolyte design holds the greatest opportunity for the development of batteries that are capable of sub-zero temperature operation.To get the most energy storage out of the battery at low temperatures,improvements in electrolyte chemistry need to be coupled with optimized electrode materials and tailored electrolyte/electrode interphases.Herein,this review critically outlines electrolytes’limiting factors,including reduced ionic conductivity,large de-solvation energy,sluggish charge transfer,and slow Li-ion transportation across the electrolyte/electrode interphases,which affect the low-temperature performance of Li-metal batteries.Detailed theoretical derivations that explain the explicit influence of temperature on battery performance are presented to deepen understanding.Emerging improvement strategies from the aspects of electrolyte design and electrolyte/electrode interphase engineering are summarized and rigorously compared.Perspectives on future research are proposed to guide the ongoing exploration for better low-temperature Li-metal batteries.展开更多
In the field of Internet, an image is of great significance to information transmission. Meanwhile, how to ensure and improve its security has become the focus of international research. We combine DNA codec with quan...In the field of Internet, an image is of great significance to information transmission. Meanwhile, how to ensure and improve its security has become the focus of international research. We combine DNA codec with quantum Arnold transform(QAr T) to propose a new double encryption algorithm for quantum color images to improve the security and robustness of image encryption. First, we utilize the biological characteristics of DNA codecs to perform encoding and decoding operations on pixel color information in quantum color images, and achieve pixel-level diffusion. Second, we use QAr T to scramble the position information of quantum images and use the operated image as the key matrix for quantum XOR operations. All quantum operations in this paper are reversible, so the decryption operation of the ciphertext image can be realized by the reverse operation of the encryption process. We conduct simulation experiments on encryption and decryption using three color images of “Monkey”, “Flower”, and “House”. The experimental results show that the peak value and correlation of the encrypted images on the histogram have good similarity, and the average normalized pixel change rate(NPCR) of RGB three-channel is 99.61%, the average uniform average change intensity(UACI) is 33.41%,and the average information entropy is about 7.9992. In addition, the robustness of the proposed algorithm is verified by the simulation of noise interference in the actual scenario.展开更多
基金The work described in this paper was fully supported by a Grant from the City University of Hong Kong(Project No.9610641).
文摘Electrolyte design holds the greatest opportunity for the development of batteries that are capable of sub-zero temperature operation.To get the most energy storage out of the battery at low temperatures,improvements in electrolyte chemistry need to be coupled with optimized electrode materials and tailored electrolyte/electrode interphases.Herein,this review critically outlines electrolytes’limiting factors,including reduced ionic conductivity,large de-solvation energy,sluggish charge transfer,and slow Li-ion transportation across the electrolyte/electrode interphases,which affect the low-temperature performance of Li-metal batteries.Detailed theoretical derivations that explain the explicit influence of temperature on battery performance are presented to deepen understanding.Emerging improvement strategies from the aspects of electrolyte design and electrolyte/electrode interphase engineering are summarized and rigorously compared.Perspectives on future research are proposed to guide the ongoing exploration for better low-temperature Li-metal batteries.
基金Project supported by the Natural Science Foundation of Shandong Province, China (Grant No. ZR2021MF049)Joint Fund of Natural Science Foundation of Shandong Province (Grant Nos. ZR2022LLZ012 and ZR2021LLZ001)the Key R&D Program of Shandong Province, China (Grant No. 2023CXGC010901)。
文摘In the field of Internet, an image is of great significance to information transmission. Meanwhile, how to ensure and improve its security has become the focus of international research. We combine DNA codec with quantum Arnold transform(QAr T) to propose a new double encryption algorithm for quantum color images to improve the security and robustness of image encryption. First, we utilize the biological characteristics of DNA codecs to perform encoding and decoding operations on pixel color information in quantum color images, and achieve pixel-level diffusion. Second, we use QAr T to scramble the position information of quantum images and use the operated image as the key matrix for quantum XOR operations. All quantum operations in this paper are reversible, so the decryption operation of the ciphertext image can be realized by the reverse operation of the encryption process. We conduct simulation experiments on encryption and decryption using three color images of “Monkey”, “Flower”, and “House”. The experimental results show that the peak value and correlation of the encrypted images on the histogram have good similarity, and the average normalized pixel change rate(NPCR) of RGB three-channel is 99.61%, the average uniform average change intensity(UACI) is 33.41%,and the average information entropy is about 7.9992. In addition, the robustness of the proposed algorithm is verified by the simulation of noise interference in the actual scenario.
