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An Efficient Boron Source Activation Strategy for the Low‑Temperature Synthesis of Boron Nitride Nanotubes
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作者 Ying Wang kai zhang +10 位作者 Liping Ding Liyun Wu Songfeng E Qian He Nanyang Wang Hui Zuo Zhengyang Zhou Feng Ding Yue Hu Jin zhang Yagang Yao 《Nano-Micro Letters》 SCIE EI CAS 2025年第1期548-558,共11页
Lowering the synthesis temperature of boron nitride nanotubes(BNNTs)is crucial for their development.The primary reason for adopting a high temperature is to enable the effective activation of highmelting-point solid ... Lowering the synthesis temperature of boron nitride nanotubes(BNNTs)is crucial for their development.The primary reason for adopting a high temperature is to enable the effective activation of highmelting-point solid boron.In this study,we developed a novel approach for efficiently activating boron by introducing alkali metal compounds into the conventional MgO–B system.This approach can be adopted to form various low-melting-point AM–Mg–B–O growth systems.These growth systems have improved catalytic capability and reactivity even under low-temperature conditions,facilitating the synthesis of BNNTs at temperatures as low as 850℃.In addition,molecular dynamics simulations based on density functional theory theoretically demonstrate that the systems maintain a liquid state at low temperatures and interact with N atoms to form BN chains.These findings offer novel insights into the design of boron activation and are expected to facilitate research on the low-temperature synthesis of BNNTs. 展开更多
关键词 Boron nitride nanotubes LOW-TEMPERATURE Boron activation Density functional theory
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Carbon Nanofiber/Polyaniline Composite Aerogel with Excellent Electromagnetic Interference Shielding,Low Thermal Conductivity,and Extremely Low Heat Release
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作者 Mingyi Chen Jian Zhu +5 位作者 kai zhang Hongkang Zhou Yufei Gao Jie Fan Rouxi Chen Hsing-Lin Wang 《Nano-Micro Letters》 2025年第4期77-95,共19页
The rapid development of communication technology and high-frequency electronic devices has created a need for more advanced electromagnetic interference(EMI)shielding materials.In response to this demand,a study has ... The rapid development of communication technology and high-frequency electronic devices has created a need for more advanced electromagnetic interference(EMI)shielding materials.In response to this demand,a study has been conducted to develop multifunctional carbon nanofibers(CNFs)/polyaniline(PANI)aerogels with excellent electromagnetic interference shielding,flame retardancy,and thermal insulation performance.The process involved freeze-drying of electrospun CNFs and PANI nanoparticles followed by in situ growth PANI to coat the CNFs,creating the core-shell structured CNFs/PANI composite fiber and its hybrid aerogels(CP-3@PANI).The interaction between PANI and aniline(ANI)provides attachment sites,allowing additional ANI adsorption into the aerogel for in situ polymerization.This results in PANI uniformly covering the surface of the CNFs,creating a core-shell composite fiber with a flexible CNF core and PANI shell.This process enhances the utilization rate of the ANI monomer and increases the PANI content loaded onto the aerogel.Additionally,effective connections are established between the CNFs,forming a stable,conductive three-dimensional network structure.The prepared CP-3@PANI aerogels exhibit excellent EMI shielding efficiency(SE)of 85.4 dB and specific EMI SE(SE d^(-1))of 791.2 dB cm^(3)g^(-1)in the X-band.Due to the synergistic flame-retardant effect of CNFs,PANI,and the dopant(phytic acid),the CP-3@PANI aerogels demonstrate outstanding flame-retardant and thermal insulation properties,with a peak heat release rate(PHRR)as low as 7.8 W g^(-1)and a total heat release of only 0.58 kJ g^(-1).This study provides an effective strategy for preparing multifunctional integrated EMI shielding materials. 展开更多
关键词 CNFs/PANI hybrid aerogels EMI shielding Flame retardancy Thermal insulation
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Intermittent disturbance mechanical behavior and fractional deterioration mechanical model of rock under complex true triaxial stress paths 被引量:3
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作者 Zhi Zheng Hongyu Xu +3 位作者 kai zhang Guangliang Feng Qiang zhang Yufei Zhao 《International Journal of Mining Science and Technology》 SCIE EI CAS CSCD 2024年第1期117-136,共20页
Mechanical excavation,blasting,adjacent rockburst and fracture slip that occur during mining excavation impose dynamic loads on the rock mass,leading to further fracture of damaged surrounding rock in three-dimensiona... Mechanical excavation,blasting,adjacent rockburst and fracture slip that occur during mining excavation impose dynamic loads on the rock mass,leading to further fracture of damaged surrounding rock in three-dimensional high-stress and even causing disasters.Therefore,a novel complex true triaxial static-dynamic combined loading method reflecting underground excavation damage and then frequent intermittent disturbance failure is proposed.True triaxial static compression and intermittent disturbance tests are carried out on monzogabbro.The effects of intermediate principal stress and amplitude on the strength characteristics,deformation characteristics,failure characteristics,and precursors of monzogabbro are analyzed,intermediate principal stress and amplitude increase monzogabbro strength and tensile fracture mechanism.Rapid increases in microseismic parameters during rock loading can be precursors for intermittent rock disturbance.Based on the experimental result,the new damage fractional elements and method with considering crack initiation stress and crack unstable stress as initiation and acceleration condition of intermittent disturbance irreversible deformation are proposed.A novel three-dimensional disturbance fractional deterioration model considering the intermediate principal stress effect and intermittent disturbance damage effect is established,and the model predicted results align well with the experimental results.The sensitivity of stress states and model parameters is further explored,and the intermittent disturbance behaviors at different f are predicted.This study provides valuable theoretical bases for the stability analysis of deep mining engineering under dynamic loads. 展开更多
关键词 True triaxial static and disturbance test Mechanical properties Failure mechanism and precursor Intermittent disturbance effect Fractional mechanical model
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聚对羟基苯乙烯衍生物及其共聚物的制备与成膜性能
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作者 廖耘皎 张睿杰 +2 位作者 王雨楠 张凯 杨鸣波 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2024年第10期36-45,共10页
聚对羟基苯乙烯成膜树脂因其优异的抗刻蚀能力和良好的深紫外透过率被广泛用于光刻技术,然而,其衍生物聚对叔丁氧酰氧基苯乙烯的玻璃化转变温度低,成膜性较差,导致其在光刻胶中的应用受到限制。为解决该问题,文中引入刚性结构3-羟基-1-... 聚对羟基苯乙烯成膜树脂因其优异的抗刻蚀能力和良好的深紫外透过率被广泛用于光刻技术,然而,其衍生物聚对叔丁氧酰氧基苯乙烯的玻璃化转变温度低,成膜性较差,导致其在光刻胶中的应用受到限制。为解决该问题,文中引入刚性结构3-羟基-1-金刚烷基甲基丙烯酸酯(HADMA)来探究刚性结构及含量对树脂玻璃化转变温度和成膜性的影响。通过傅里叶变换红外光谱、核磁共振氢谱、凝胶渗透色谱证明了共聚物的合成。进一步通过差示扫描量热法、热重分析仪等方法表征了材料的热性能,利用流变仪、台阶仪、扫描电子显微镜、原子力显微镜讨论了刚性结构对材料成膜性能的影响。结果表明,随着HADMA含量的增加,聚合物的玻璃化转变温度从111.7℃提升至132.4℃,聚合物膜开裂和孔洞情况得到显著改善,表面粗糙度保持在2nm内,证明引入刚性结构3-羟基-1-金刚烷基甲基丙烯酸酯能有效提高其玻璃化转变温度和成膜性能。 展开更多
关键词 聚对羟基苯乙烯 共聚物 玻璃化转变温度 成膜性
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Multi-surrogate framework with an adaptive selection mechanism for production optimization 被引量:1
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作者 Jia-Lin Wang Li-Ming zhang +10 位作者 kai zhang Jian Wang Jian-Ping Zhou Wen-Feng Peng Fa-Liang Yin Chao Zhong Xia Yan Pi-Yang Liu Hua-Qing zhang Yong-Fei Yang Hai Sun 《Petroleum Science》 SCIE EI CAS CSCD 2024年第1期366-383,共18页
Data-driven surrogate models that assist with efficient evolutionary algorithms to find the optimal development scheme have been widely used to solve reservoir production optimization problems.However,existing researc... Data-driven surrogate models that assist with efficient evolutionary algorithms to find the optimal development scheme have been widely used to solve reservoir production optimization problems.However,existing research suggests that the effectiveness of a surrogate model can vary depending on the complexity of the design problem.A surrogate model that has demonstrated success in one scenario may not perform as well in others.In the absence of prior knowledge,finding a promising surrogate model that performs well for an unknown reservoir is challenging.Moreover,the optimization process often relies on a single evolutionary algorithm,which can yield varying results across different cases.To address these limitations,this paper introduces a novel approach called the multi-surrogate framework with an adaptive selection mechanism(MSFASM)to tackle production optimization problems.MSFASM consists of two stages.In the first stage,a reduced-dimensional broad learning system(BLS)is used to adaptively select the evolutionary algorithm with the best performance during the current optimization period.In the second stage,the multi-objective algorithm,non-dominated sorting genetic algorithm II(NSGA-II),is used as an optimizer to find a set of Pareto solutions with good performance on multiple surrogate models.A novel optimal point criterion is utilized in this stage to select the Pareto solutions,thereby obtaining the desired development schemes without increasing the computational load of the numerical simulator.The two stages are combined using sequential transfer learning.From the two most important perspectives of an evolutionary algorithm and a surrogate model,the proposed method improves adaptability to optimization problems of various reservoir types.To verify the effectiveness of the proposed method,four 100-dimensional benchmark functions and two reservoir models are tested,and the results are compared with those obtained by six other surrogate-model-based methods.The results demonstrate that our approach can obtain the maximum net present value(NPV)of the target production optimization problems. 展开更多
关键词 Production optimization Multi-surrogate models Multi-evolutionary algorithms Dimension reduction Broad learning system
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Electrolyte Design for Low‑Temperature Li‑Metal Batteries:Challenges and Prospects 被引量:1
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作者 Siyu Sun Kehan Wang +3 位作者 zhanglian Hong Mingjia Zhi kai zhang Jijian Xu 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第2期365-382,共18页
Electrolyte design holds the greatest opportunity for the development of batteries that are capable of sub-zero temperature operation.To get the most energy storage out of the battery at low temperatures,improvements ... Electrolyte design holds the greatest opportunity for the development of batteries that are capable of sub-zero temperature operation.To get the most energy storage out of the battery at low temperatures,improvements in electrolyte chemistry need to be coupled with optimized electrode materials and tailored electrolyte/electrode interphases.Herein,this review critically outlines electrolytes’limiting factors,including reduced ionic conductivity,large de-solvation energy,sluggish charge transfer,and slow Li-ion transportation across the electrolyte/electrode interphases,which affect the low-temperature performance of Li-metal batteries.Detailed theoretical derivations that explain the explicit influence of temperature on battery performance are presented to deepen understanding.Emerging improvement strategies from the aspects of electrolyte design and electrolyte/electrode interphase engineering are summarized and rigorously compared.Perspectives on future research are proposed to guide the ongoing exploration for better low-temperature Li-metal batteries. 展开更多
关键词 Solid electrolyte interphase Li metal Low temperature Electrolyte design BATTERIES
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Deep learning CNN-APSO-LSSVM hybrid fusion model for feature optimization and gas-bearing prediction
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作者 Jiu-Qiang Yang Nian-Tian Lin +3 位作者 kai zhang Yan Cui Chao Fu Dong zhang 《Petroleum Science》 SCIE EI CAS CSCD 2024年第4期2329-2344,共16页
Conventional machine learning(CML)methods have been successfully applied for gas reservoir prediction.Their prediction accuracy largely depends on the quality of the sample data;therefore,feature optimization of the i... Conventional machine learning(CML)methods have been successfully applied for gas reservoir prediction.Their prediction accuracy largely depends on the quality of the sample data;therefore,feature optimization of the input samples is particularly important.Commonly used feature optimization methods increase the interpretability of gas reservoirs;however,their steps are cumbersome,and the selected features cannot sufficiently guide CML models to mine the intrinsic features of sample data efficiently.In contrast to CML methods,deep learning(DL)methods can directly extract the important features of targets from raw data.Therefore,this study proposes a feature optimization and gas-bearing prediction method based on a hybrid fusion model that combines a convolutional neural network(CNN)and an adaptive particle swarm optimization-least squares support vector machine(APSO-LSSVM).This model adopts an end-to-end algorithm structure to directly extract features from sensitive multicomponent seismic attributes,considerably simplifying the feature optimization.A CNN was used for feature optimization to highlight sensitive gas reservoir information.APSO-LSSVM was used to fully learn the relationship between the features extracted by the CNN to obtain the prediction results.The constructed hybrid fusion model improves gas-bearing prediction accuracy through two processes of feature optimization and intelligent prediction,giving full play to the advantages of DL and CML methods.The prediction results obtained are better than those of a single CNN model or APSO-LSSVM model.In the feature optimization process of multicomponent seismic attribute data,CNN has demonstrated better gas reservoir feature extraction capabilities than commonly used attribute optimization methods.In the prediction process,the APSO-LSSVM model can learn the gas reservoir characteristics better than the LSSVM model and has a higher prediction accuracy.The constructed CNN-APSO-LSSVM model had lower errors and a better fit on the test dataset than the other individual models.This method proves the effectiveness of DL technology for the feature extraction of gas reservoirs and provides a feasible way to combine DL and CML technologies to predict gas reservoirs. 展开更多
关键词 Multicomponent seismic data Deep learning Adaptive particle swarm optimization Convolutional neural network Least squares support vector machine Feature optimization Gas-bearing distribution prediction
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The real-time dynamic liquid level calculation method of the sucker rod well based on multi-view features fusion
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作者 Cheng-Zhe Yin kai zhang +4 位作者 Jia-Yuan Liu Xin-Yan Wang Min Li Li-Ming zhang Wen-Sheng Zhou 《Petroleum Science》 SCIE EI CAS CSCD 2024年第5期3575-3586,共12页
In the production of the sucker rod well, the dynamic liquid level is important for the production efficiency and safety in the lifting process. It is influenced by multi-source data which need to be combined for the ... In the production of the sucker rod well, the dynamic liquid level is important for the production efficiency and safety in the lifting process. It is influenced by multi-source data which need to be combined for the dynamic liquid level real-time calculation. In this paper, the multi-source data are regarded as the different views including the load of the sucker rod and liquid in the wellbore, the image of the dynamometer card and production dynamics parameters. These views can be fused by the multi-branch neural network with special fusion layer. With this method, the features of different views can be extracted by considering the difference of the modality and physical meaning between them. Then, the extraction results which are selected by multinomial sampling can be the input of the fusion layer.During the fusion process, the availability under different views determines whether the views are fused in the fusion layer or not. In this way, not only the correlation between the views can be considered, but also the missing data can be processed automatically. The results have shown that the load and production features fusion(the method proposed in this paper) performs best with the lowest mean absolute error(MAE) 39.63 m, followed by the features concatenation with MAE 42.47 m. They both performed better than only a single view and the lower MAE of the features fusion indicates that its generalization ability is stronger. In contrast, the image feature as a single view contributes little to the accuracy improvement after fused with other views with the highest MAE. When there is data missing in some view, compared with the features concatenation, the multi-view features fusion will not result in the unavailability of a large number of samples. When the missing rate is 10%, 30%, 50% and 80%, the method proposed in this paper can reduce MAE by 5.8, 7, 9.3 and 20.3 m respectively. In general, the multi-view features fusion method proposed in this paper can improve the accuracy obviously and process the missing data effectively, which helps provide technical support for real-time monitoring of the dynamic liquid level in oil fields. 展开更多
关键词 Dynamic liquid level Multi view Features fusion Sucker rod well Dynamometer cards
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Performance Limits and Advancements in Single 2D Transition Metal Dichalcogenide Transistor
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作者 Jing Chen Ming-Yuan Sun +8 位作者 Zhen-Hua Wang Zheng zhang kai zhang Shuai Wang Yu zhang Xiaoming Wu Tian-Ling Ren Hong Liu Lin Han 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第12期134-188,共55页
Two-dimensional(2D)transition metal dichalcogenides(TMDs)allow for atomic-scale manipulation,challenging the conventional limitations of semiconductor materials.This capability may overcome the short-channel effect,sp... Two-dimensional(2D)transition metal dichalcogenides(TMDs)allow for atomic-scale manipulation,challenging the conventional limitations of semiconductor materials.This capability may overcome the short-channel effect,sparking significant advancements in electronic devices that utilize 2D TMDs.Exploring the dimension and performance limits of transistors based on 2D TMDs has gained substantial importance.This review provides a comprehensive investigation into these limits of the single 2D-TMD transistor.It delves into the impacts of miniaturization,including the reduction of channel length,gate length,source/drain contact length,and dielectric thickness on transistor operation and performance.In addition,this review provides a detailed analysis of performance parameters such as source/drain contact resistance,subthreshold swing,hysteresis loop,carrier mobility,on/off ratio,and the development of p-type and single logic transistors.This review details the two logical expressions of the single 2D-TMD logic transistor,including current and voltage.It also emphasizes the role of 2D TMD-based transistors as memory devices,focusing on enhancing memory operation speed,endurance,data retention,and extinction ratio,as well as reducing energy consumption in memory devices functioning as artificial synapses.This review demonstrates the two calculating methods for dynamic energy consumption of 2D synaptic devices.This review not only summarizes the current state of the art in this field but also highlights potential future research directions and applications.It underscores the anticipated challenges,opportunities,and potential solutions in navigating the dimension and performance boundaries of 2D transistors. 展开更多
关键词 Two-dimensional transistors Dimension limits Performance limits Memory devices Artificial synapses
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Better use of experience from other reservoirs for accurate production forecasting by learn-to-learn method
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作者 Hao-Chen Wang kai zhang +7 位作者 Nancy Chen Wen-Sheng Zhou Chen Liu Ji-Fu Wang Li-Ming zhang Zhi-Gang Yu Shi-Ti Cui Mei-Chun Yang 《Petroleum Science》 SCIE EI CAS CSCD 2024年第1期716-728,共13页
To assess whether a development strategy will be profitable enough,production forecasting is a crucial and difficult step in the process.The development history of other reservoirs in the same class tends to be studie... To assess whether a development strategy will be profitable enough,production forecasting is a crucial and difficult step in the process.The development history of other reservoirs in the same class tends to be studied to make predictions accurate.However,the permeability field,well patterns,and development regime must all be similar for two reservoirs to be considered in the same class.This results in very few available experiences from other reservoirs even though there is a lot of historical information on numerous reservoirs because it is difficult to find such similar reservoirs.This paper proposes a learn-to-learn method,which can better utilize a vast amount of historical data from various reservoirs.Intuitively,the proposed method first learns how to learn samples before directly learning rules in samples.Technically,by utilizing gradients from networks with independent parameters and copied structure in each class of reservoirs,the proposed network obtains the optimal shared initial parameters which are regarded as transferable information across different classes.Based on that,the network is able to predict future production indices for the target reservoir by only training with very limited samples collected from reservoirs in the same class.Two cases further demonstrate its superiority in accuracy to other widely-used network methods. 展开更多
关键词 Production forecasting Multiple patterns Few-shot learning Transfer learning
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短玻纤增强聚丙烯水辅助注射成型纤维取向数值模拟 被引量:4
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作者 张伟 柳和生 +3 位作者 黄兴元 余忠 章凯 陈忠仕 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2019年第8期105-111,117,共8页
基于Folgar-Tucker纤维取向模型,利用Moldex3D对三维长直管件进行溢流法水辅助注射成型可视化研究。结果表明,在制品初始段位置的水道层区域纤维取向倾向于无序状态,而在制品的中间段及末尾段位置的纤维倾向于沿流动方向形成取向;通过... 基于Folgar-Tucker纤维取向模型,利用Moldex3D对三维长直管件进行溢流法水辅助注射成型可视化研究。结果表明,在制品初始段位置的水道层区域纤维取向倾向于无序状态,而在制品的中间段及末尾段位置的纤维倾向于沿流动方向形成取向;通过适当的增加注水延迟时间可以有效地改善制品初始段位置的纤维沿流动方向的取向。另外,还发现沿流动方向的纤维取向最有序的位置是靠近壳层位置的芯层区域;在制品的末端位置,注水压力、熔体温度显著影响纤维沿流动方向的取向。 展开更多
关键词 短玻纤增强聚合物复合材料 水辅助注射成型 纤维取向 数值模拟
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针对非高分子专业学生进行高分子化学课程综合教学模式的探索与实践 被引量:3
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作者 刘轶 林权 +6 位作者 刘堃 张皓 宋文龙 史作森 崔占臣 张恺 张俊虎 《大学化学》 CAS 2021年第8期6-10,共5页
由于受到新型冠状病毒肺炎疫情的影响,教师无法顺利开展2020春季学期线下教学活动。为了更好地落实教育部提出的"停课不停教、停课不停学"的要求,确保教学质量,特别是针对化学专业(非高分子专业)的100多名本科生的教学,吉林... 由于受到新型冠状病毒肺炎疫情的影响,教师无法顺利开展2020春季学期线下教学活动。为了更好地落实教育部提出的"停课不停教、停课不停学"的要求,确保教学质量,特别是针对化学专业(非高分子专业)的100多名本科生的教学,吉林大学化学学院高分子教学团队利用吉林大学在线学堂作为线上教学平台,后期配合线下教学课堂,同时辅助采用以课堂教学为切入点的课程思政体系建设,成功地开展了高分子化学课程在线教学的探索和实践。本课程根据化学专业本科生的教学基础和特点,以培养学生对于高分子学科的研究兴趣,而非直接灌输学生大量的概念、公式让学生死记硬背为理念,实现思想政治教育与知识体系教育的有机统一。通过在线和线下教学形式的组合有效地重组了教学资源,优化了教学过程,特别是思政元素与线上及线下课堂教学各环节的融合,有力地保证了新冠疫情防控期间教学进度的顺利完成与教学质量的提升。 展开更多
关键词 高分子化学 线上教学 探索与实践 课程思政
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煤炭行业特色高校有机化学课程思政教学设计与实践 被引量:1
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作者 王启宝 刘骞 +3 位作者 王立艳 刘迪 张凯 张香兰 《大学化学》 CAS 2022年第10期182-187,共6页
根据我校建设世界一流能源大学的目标,推进煤炭工业绿色低碳发展,在有机化学教学实践中,以一碳化学的“煤化路线”为切入点,结合教材中重要化合物的合成及应用,介绍中国现代“煤化工”发展成就;通过教师课内讲授与学生课外调研相结合,... 根据我校建设世界一流能源大学的目标,推进煤炭工业绿色低碳发展,在有机化学教学实践中,以一碳化学的“煤化路线”为切入点,结合教材中重要化合物的合成及应用,介绍中国现代“煤化工”发展成就;通过教师课内讲授与学生课外调研相结合,充分利用自媒体辅助课程思政教学,实现对学生的价值塑造、能力培养和知识传授的教学目的,培养煤炭行业创新型人才。 展开更多
关键词 有机化学 课程思政 教学设计 煤炭行业特色
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不同流道截面型腔的水穿透行为
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作者 黄益宾 章凯 +4 位作者 余忠 李厅 柳和生 匡唐清 应忠 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2023年第11期82-92,共11页
纤维取向分布直接影响水辅注塑成型制品的使用性能,如冲击强度、屈服强度及拉伸强度等。多样化的流道截面型腔用于满足水辅制品在不同场合中的应用,不同的流道截面型腔势必会影响水辅制品中纤维取向分布。文中旨在研究圆形、上圆下方形... 纤维取向分布直接影响水辅注塑成型制品的使用性能,如冲击强度、屈服强度及拉伸强度等。多样化的流道截面型腔用于满足水辅制品在不同场合中的应用,不同的流道截面型腔势必会影响水辅制品中纤维取向分布。文中旨在研究圆形、上圆下方形及方形的截面流道型腔中短玻纤增强聚丙烯复合材料的水辅助注射成型过程。结果发现,随着熔体温度的升高、注水压力的增大及注水延迟时间的缩短,3种流道截面型腔制品的中间端处残余壁厚减薄及短玻纤沿聚合物熔体流动方向的取向度提高,且在相同加工变量下,圆形截面流道型腔制品的中间端处残余壁厚最薄及短玻纤沿聚合物熔体流动方向的取向度最高,其次是上圆下方形,最后是方形。综合制品的中间端1处及2处残余壁厚可知,聚合物熔体温度在210~230℃、注水压力7~10 MPa及注水延迟时间1~5 s时,上圆下方形截面型腔制品的中间端处残余壁厚及短玻纤沿聚合物熔体流动方向的取向度更趋近于圆形。 展开更多
关键词 型腔截面 溢流法 残余壁厚 水辅助注射成型 纤维取向
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水辅注塑成型注射方法对方管纤维取向和收缩性的影响 被引量:4
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作者 陈忠仕 柳和生 +2 位作者 余忠 章凯 张伟 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2020年第2期112-119,共8页
基于聚合物复合材料黏弹性本构方程(White-Metzner方程)和流体动力学三大控制方程,采用改进的iARD-RPR纤维取向模型,以直线构成的方形截面管材为研究对象,运用有限体积法开发的软件,模拟分析了溢流法和短射法对制品纤维取向和收缩率的影... 基于聚合物复合材料黏弹性本构方程(White-Metzner方程)和流体动力学三大控制方程,采用改进的iARD-RPR纤维取向模型,以直线构成的方形截面管材为研究对象,运用有限体积法开发的软件,模拟分析了溢流法和短射法对制品纤维取向和收缩率的影响,且有相应实验验证。结果显示,2种注射方法的制件在竖切面(对边中心点连线处切面)上沿流动方向的纤维取向度从表层到水道层逐渐减小,且短射法制件竖切面后段纤维取向的有序区域比前段大;在对角切面(方形截面对角线切面)上,纤维取向度比对应的制件竖切面高;溢流法制件由于穿透截面形状趋于圆形,且壁厚相对较厚,4个直角处及整体收缩率较高,而短射法穿透截面形状趋于截面形状,制件冷却均匀,所以4个直角和整体的收缩率很低,随着注射量增加,收缩率增大。 展开更多
关键词 水辅注塑 注射方法 方形截面 纤维取向 收缩率
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相变微胶囊/环氧树脂复合泡沫的制备及性能 被引量:6
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作者 丁泽 陈昭朋 +4 位作者 张凯 杨文彬 范敬辉 吴菊英 何方方 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2019年第1期136-141,共6页
以石蜡@密胺树脂微胶囊(Pn@MF)为相变填料,环氧树脂为支撑材料,通过将相变微胶囊封装在环氧树脂泡沫中得到一种复合相变材料(CPCMs)。通过扫描电镜表征表明相变微胶囊与环氧树脂泡沫相容性良好。随着微胶囊含量的增加,差示扫描量热分析... 以石蜡@密胺树脂微胶囊(Pn@MF)为相变填料,环氧树脂为支撑材料,通过将相变微胶囊封装在环氧树脂泡沫中得到一种复合相变材料(CPCMs)。通过扫描电镜表征表明相变微胶囊与环氧树脂泡沫相容性良好。随着微胶囊含量的增加,差示扫描量热分析表明CPCMs的相变焓值增大,当Pn@MF含量为40%时,焓值达到102. 2 J/g,其泄漏率仅为1. 31%,具有较低的渗漏率; CPCMs的热导率始终低于0. 14 W/(m·K)。随着发泡剂含量的增加,CPCMs的渗漏率降低,热导率降低,而力学性能先升高后降低。发泡温度的升高会对渗漏率、热导率和力学性能产生不利影响。CPCMs的低导热率和低泄漏率可应用于热能储存领域。 展开更多
关键词 复合相变材料 微胶囊 环氧树脂 渗漏率 热导率
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基于“三线五面”膜解剖的腹腔镜根治性膀胱切除术治疗男性膀胱癌的疗效观察(附34例报告) 被引量:5
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作者 叶超 吴志坚 +3 位作者 陈晓峰 孙建明 张凯 邹义华 《中国内镜杂志》 2021年第4期63-68,共6页
目的探讨基于"三线五面"膜解剖的腹腔镜根治性膀胱切除术治疗男性膀胱癌的安全性、疗效与优势。方法选取2018年1月-2020年4月郴州市第一人民医院泌尿外科收治的34例男性膀胱癌患者,均实施腹腔镜下根治性膀胱切除术。患者年龄5... 目的探讨基于"三线五面"膜解剖的腹腔镜根治性膀胱切除术治疗男性膀胱癌的安全性、疗效与优势。方法选取2018年1月-2020年4月郴州市第一人民医院泌尿外科收治的34例男性膀胱癌患者,均实施腹腔镜下根治性膀胱切除术。患者年龄54~83岁,平均(66.6±7.9)岁;多发肿瘤12例,单发肿瘤22例,其中位于三角区3例,左侧壁6例,右侧壁7例,底部4例,顶部2例;肿瘤直径1.5~7.5 cm,平均(3.6±1.6) cm;术前临床分期:cT_(2)N_(0)M_(0)20例,cT_(3)N_(0)M_(0)10例,cT_(4a)N_(0)M_(0)4例。手术均由同一高年资医师完成,按照"三线五面"("三线"即三条主线:输尿管、输精管和脐内侧韧带;"五面"即五个无血管平面:输尿管鞘平面、直肠前平面、脐动脉外侧平面、骨盆侧壁平面、耻骨后平面)的手术思路,运用膜解剖技术精准分离,先行根治性膀胱切除术,再行盆腔淋巴结清扫,最后行尿流改道。结果34例患者均顺利完成手术,根治性膀胱切除及盆腔淋巴结清扫术时间为160~240 min,平均(185.6±20.3) min,术中出血量200~500 mL,无输血病例。术后病检结果:pT_(1)N_(0)M_(0)2例,pT_(2)N_(0)M_(0)18例,pT_(3)N_(0)M_(0)11例,pT_(4a)N_(0)M_(0)3例;低级别尿路上皮癌4例,高级别尿路上皮癌30例,其中高级别尿路上皮癌伴肉瘤样癌1例;手术切缘均为阴性。术后肠道功能恢复时间(2.8±0.6) d,术后出现1例粘连性肠梗阻,经非手术治疗后肠道功能恢复,术中术后无严重并发症,术后住院时间10~15 d,平均(12.5±2.6) d,术后疼痛评分1~5分,平均(3.1±1.1)分,术后随访6~28个月,平均(12.5±7.8)个月,暂无局部复发与远处转移。结论按照"三线五面"手术思路,运用膜解剖技术实施腹腔镜根治性膀胱切除术,术中解剖标志清晰、组织层次分明,并发症可控,手术安全性高,疗效满意,值得临床推广运用。 展开更多
关键词 膜解剖 腹腔镜 膀胱癌 根治性膀胱切除术
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细菌纤维素/氧化铝/二氧化硅改性石墨烯复合导热膜的结构与性能 被引量:3
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作者 宋攀 冯昌平 +4 位作者 张凯 白露 刘正英 杨鸣波 杨伟 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2021年第6期140-145,共6页
采用真空辅助抽滤方法制备了细菌纤维素(BC)/球形氧化铝粒子/改性石墨烯纳米片(SiO_(2)@GNPs)薄膜热界面材料,研究了球形氧化铝粒子粒径对热界面材料形态结构和导热性能的影响。结果表明,球形粒子与二维片状导热粒子复配时,可有效构筑... 采用真空辅助抽滤方法制备了细菌纤维素(BC)/球形氧化铝粒子/改性石墨烯纳米片(SiO_(2)@GNPs)薄膜热界面材料,研究了球形氧化铝粒子粒径对热界面材料形态结构和导热性能的影响。结果表明,球形粒子与二维片状导热粒子复配时,可有效构筑面外方向导热通路。调节氧化铝粒子和改性石墨烯纳米片的直径比可有效调整改性石墨烯纳米片在复合薄膜中在面外方向的取向程度,从而提高复合材料的面外导热系数。随着球形氧化铝的直径从2μm增加到60μm,导热薄膜的面外导热系数从0.5 W/(m·K)提高到4.2 W/(m·K),导热系数提高了7.4倍。 展开更多
关键词 热界面材料 面外导热通路 导热性能
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乳化法制备石蜡/三元乙丙橡胶定形相变材料及其性能 被引量:3
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作者 丁泽 程弘 +4 位作者 张凯 杨文彬 范敬辉 吴菊英 何方方 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2019年第2期171-174,182,共5页
以石蜡(Paraffin)为相变材料,三元乙丙橡胶(EPDM)为支撑材料,通过乳化法将石蜡和EPDM同时乳化,再热压硫化成型得到石蜡/EPDM定形相变材料。采用扫描电子显微镜表征了定形相变材料的断面微观形貌,结果表明石蜡与EPDM的相容性良好。通过... 以石蜡(Paraffin)为相变材料,三元乙丙橡胶(EPDM)为支撑材料,通过乳化法将石蜡和EPDM同时乳化,再热压硫化成型得到石蜡/EPDM定形相变材料。采用扫描电子显微镜表征了定形相变材料的断面微观形貌,结果表明石蜡与EPDM的相容性良好。通过差示扫描量热仪测试了定形相变材料的焓值,表明随着石蜡含量的增加,其焓值增加。通过渗漏测试表明PCMs-30%的渗漏率可低至0.5%。通过电子万能试验机测试表明PCMs-30%的力学性能达到较为良好的状态,拉伸强度达到0.866 MPa,断裂伸长率达到480%。 展开更多
关键词 三元乙丙橡胶 石蜡 定形相变材料 渗漏率
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金属锂负极的成核机制与载体修饰 被引量:5
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作者 邱晓光 刘威 +3 位作者 刘九鼎 李俊志 张凯 程方益 《物理化学学报》 SCIE CAS CSCD 北大核心 2021年第1期73-83,共11页
金属锂具有电位低、比容量高等突出优点,是极具吸引力的下一代高能量密度电池的负极材料,然而存在枝晶、死锂、副反应严重、库伦效率低、循环稳定性差等问题,限制了其实际应用。金属锂负极的成核是电化学沉积过程中的重要步骤,锂在集流... 金属锂具有电位低、比容量高等突出优点,是极具吸引力的下一代高能量密度电池的负极材料,然而存在枝晶、死锂、副反应严重、库伦效率低、循环稳定性差等问题,限制了其实际应用。金属锂负极的成核是电化学沉积过程中的重要步骤,锂在集流体或导电载体上的均匀成核和稳定生长对于抑制枝晶死锂、提高充放电效率和循环性能具有关键作用。本文从成核机制与载体效应的角度概述了锂金属负极的研究进展,介绍了锂成核驱动力、异相成核模型、空间电荷模型等内容,分析了锂核尺寸及分布与过电位和电流密度的关系,并通过三维载体分散电流密度、异相晶核/电场诱导成核、晶格匹配等方面的研究实例讨论了载体修饰对锂负极的性能提升。 展开更多
关键词 金属锂电池 枝晶 成核机制 载体改性
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