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铝溶胶胶体颗粒比表面积的测定方法

Determination Method of the Specific Surface Area of Alumina Sol
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摘要 铝溶胶是催化裂化催化剂制备中最重要的粘结剂之一.由于铝溶胶在干燥过程中颗粒从纳米级可以长大到微米级,目前尚没有铝溶胶比表面积测定的报道.采用将一定量的铝溶胶预先高度分散到大孔硅胶孔道内,从而避免铝溶胶颗粒在干燥过程中的长大,将其干燥后测定其比表面积,外推到铝溶胶含量,采用BET法测得铝溶胶比表面积为310 m2/g. Alumina sol is one of the most important binders for the fluid catalytic cracking catalysts.Up to now there is no report on the determination of the specific surface area of alumina sol due to the sintering of nano-alumina particles during the drying process.Alumina sol is dispersed to pores of silica gel and is dried without sintering,the determined specific surface area of alumina sol is 310 m2/g.
作者 文建军
出处 《湖南师范大学自然科学学报》 CAS 北大核心 2013年第3期56-59,共4页 Journal of Natural Science of Hunan Normal University
基金 科技部973计划资助项目(2006CB202500)
关键词 铝溶胶 比表面积 粘结剂 催化裂化 alumina sol specific surface area binder FCC
作者简介 通讯作者。E-mail:wenjj.chji@sinopec.com
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参考文献14

  • 1MAGEE J S, MITCHELL M M. Fluid Catalytic Cracking:Science and Technology[ M]. Amsterdam: Elsevier Science Publish- ers, 1993.
  • 2SCHERZER J. Attrition resistant cracking catalyst: US, 4987110 [ P]. 1991-01-22.
  • 3吕玉康,李才英,顾文娟.一种裂化催化剂及其制备方法:中国,CNl098130A[P].1995-02-01.
  • 4宋家庆,田素贤,李茹华,等.一种裂化催化剂的制备方法:中国,CNl246515A[P].2000-03-08.
  • 5严加松.铝基粘结剂及其粘结的FCC催化剂的强度和孔结构的研究[D].北京:中国石化石油化工科学研究院,2004.
  • 6于珍,路登明.铝溶胶生产工艺中温度的选择[J].化学工程与设备,2010(10):39-40.
  • 7尹忠亮.铝溶胶生产工艺条件的研究[J].精细石油化工进展,2003,4(6):52-54. 被引量:7
  • 8FU G, NAZAR L F. Aging process of alumina sol-gel : characterization of new aluminum polyoxycation by AL NMR spectroscopy [J]. Chem Mater, 1991(3) :600-610.
  • 9冯利,汤鸿霄.Al_(13)形态的研究进展[J].环境科学进展,1997,5(6):44-51. 被引量:17
  • 10CASTELLANI R, POULESQUEN A, MARCHAL P. Ions effects on sol-gel transition and rheological behavior in alumina slur- ries [ J ]. Colloids and Surfaces A : Physicochem Eng, 2013 (430) :39-45. .

二级参考文献45

  • 1孙强,于艳春,姚小华,苏永成,张振权.多核磺化酞菁镍(Ⅱ)的使用寿命及其对环己烯环氧化反应的催化机理[J].河南师范大学学报(自然科学版),1996,24(1):55-57. 被引量:3
  • 2李辉勇,金密,周军,李志光,戴翔,赵律.纳米TiO_2的制备及其对甲醛的光催化降解性能[J].精细化工中间体,2006,36(4):43-45. 被引量:4
  • 3Tsai P P,Soil Sci Soc Am J,1985年,49卷,1060页
  • 4Tsai P P,Soil Sci Soc Am J,1984年,48卷,59页
  • 5MADHAVA R, PUNNIYAMURTHY T, IQBAL J. Cobalt catalyzed oxidation of cyclic alkenes with molecular oxygen: allylic oxidation versus double bound attack [J]. Tetrahedron Lett, 1995,26(20) :159-162.
  • 6BIMBAUM E, GRINSTAFF'M W, LABINGER J A, et al. On the mechanism of catalytic alkene oxidation by molecular oxygen and halogenated iron porphyrins [J]. J Mol Cata A: Chem, 1995,104(2) :119-122.
  • 7MASTRORILLI P, NOBILE C F. Aerobic epoxidation of olefins catalyzed by polymerizable/3-ketoesterate complexes of iron (Ⅲ), nickel(Ⅱ) and cobalt(Ⅱ) [J]. J Mol Cata A: Chem, 1994,94(1) :19-26.
  • 8FOX M A, CHEN C C. Mechanistic features of the semiconductor photocatalyzed olefin-to-carbonyl oxidative cleavage [ J ]. J Am Chem Soc, 1981,103(22) :6757-6759.
  • 9HONG X T, WANG Z P, CAI W M, et al. Visible-light-activated nanoparticle photocatalyst of iodine-doped titanium dioxide [J]. Chem Mater, 2005,17(6) :1548-1552.
  • 10CHEN C C, LI X Z, MAW H, et al. Effect of transition metal ions on the TiO2-assisted photodegradation of dyes under visible Irradiation, a probe for the inteffacial electron transfer process and reaction mechanism [J]. J Phys Chem B, 2002,106 (2) :318-324.

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