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过氧化氢合成的研究进展 被引量:8

Progress in Research of the Synthesis of Hydrogen Peroxide
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摘要 过氧化氢(H2O2)是一种重要的化工产品,且需求量不断增加。综述了近几年来过氧化氢的研究进展,系统地介绍了燃料电池法,O2、CO、H2O催化合成法、贵金属直接催化合成法和H2/O2介质阻挡放电等离子体法等合成过氧化氢的方法。提出了当前需要解决的问题并对今后的研究工作进行了展望。 Hydrogen peroxide ( H2O2 ) is a very important chemical product. Nowadays, most H2O2 is manufactured by conventional process, the anthraquinone process, in a multistep operation with high energy consumption. It is, therefore, of great practical interest to produce H2O2 more economically and cleanly by a novel process. In this paper, recent progress in research of synthesis of hydrogen peroxide ( including fuel cells, synthesis from CO/O2/H2O mixtures, direct synthesis of H2O2 by noble metal catalyst, synthesis of H2O2 via hydrogen - oxygen plasma under dielectric barrier discharge) was reviewed, and an outlook was made.
出处 《化工时刊》 CAS 2008年第7期54-59,共6页 Chemical Industry Times
基金 滨州学院青年人才创新工程(BZXYQNLG200612 BZXYQNLG200614)
关键词 过氧化氢 合成 氢气 氧气 hydrogen peroxide synthesis hydrogen oxygen
作者简介 苟建霞(1980-),女,硕士,助教,主要从事介质阻挡放电等离子体方面的研究 E-mail:goujianxia@163.com
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参考文献45

  • 1Beckman E J. Production of H2O2 in CO2 and its use in the direct synthesis of propylene oxide [ J ]. Green Chem. 2003, 5(3) :332 -336
  • 2刘国柱,王莅,米镇涛,陈四海,凌太平.蒽醌法制过氧化氢用氢化反应器的研究进展[J].现代化工,2003,23(2):19-22. 被引量:3
  • 3Francisco Alcaide, Enric Brillas, Pere - Liuis Cabot.Electrogeneration of hydroperoxide ion using an anlkaline fuel cell[J]. J. Electrochem. Soc, 1998, 145(10) : 3444 - 3449
  • 4Enric Bfillas, Francisco Alcaide, Pere - Llu's Cabot. A small - scale flow alkaline fuel cell for on - site production of hydrogen peroxide [ J ]. Electrochimica Acta, 2002, 48 (4) :331 -340
  • 5Elena Lobyntseva, Tanja Kallio, Kyosti Kontturi. Bipolar membranes in forward bias region for fuel cell reactors[ J]. Electrochimica Acta, 2006, 51 (7) : 1165 - 1171
  • 6Yamanaka I, Onizawa T, Takenaka S. , et al. Direct and continuous production of hydrogen peroxide with 93% selectivity using a fuel - cell system [ J ]. Angew. Chem. Int. Ed., 2003,42:3653 -3655
  • 7Vaik K, Sarapuu A, Tammeveski K. , et al. Oxygen reduction on phenanthrenequinone - modified glassy carbon electrodes in0.1 mol/L KOH[J]. J. Electroanal. Chem. 2004, 564, 159-166
  • 8Hossain M S, Tryk D, Yeager E. The electrochemistry of graphite and modified graphite surfaces: The reduction of O2[J]. Electrochim. Acta, 1989, 34(12):1733-1737
  • 9Chen P, McCreery R L. Control of electron transfer kinetics at glassy carbon electrodes by specific surface modification[J]. Anal. Chem. 1996, 68(22): 3958-3965
  • 10Bianchi Daniele, Bortolo Rossella, D'Aloisio Rino., et al. A novel palladium catalyst for the synthesis of hydrogen peroxide from carbon monoxide, water and oxygen [J]. Journal of Molecular Catalysis A :Chemical, 1999, 150(1 -2) : 87 -94

二级参考文献20

  • 1李慧青,邹吉军,张月萍,刘昌俊.电晕放电等离子体甲醇分解制氢[J].化工学报,2004,55(12):1989-1993. 被引量:11
  • 2[1]Lunsford J H.The direct formation of H2O2 from H2 and O2 over palladium catalysts[J].Journal of Catalysis,2003,216:455-460.
  • 3[2]Landon P,Collier P J,Papworth A J,et al.Direct formation of hydrogen peroxide from H2/O2 using a gold catalyst[J].Chem Commun,2002,2058-2060.
  • 4[3]Choudhary V R,Samanta C,Gaikwad A G.Drastic increase of selectivity for H2O2 formation in direct oxidation of H2 to H2O2 over supported Pd catalysts due to their bromination[J].Chem Commun,2004,2054-2056.
  • 5[4]Venugopalan M,Jones R A.Chemistry of dissociated water vapor and related systems[J].Chem Rev,1966,66:133-160.
  • 6[5]Zhou Juncheng,Guo Hongchen,Wang Xiangsheng,et al.Direct and continuous synthesis of concentrated hydrogen peroxide by the gaseous reaction of H2/O2 non-equilibrium plasma[J].Chem Commun,2005,1631-1633.
  • 7[6]Moane S,Raftery D P,Smyth M R,et al.Decomposition of peroxides by transition metal ions in anaerobic adhesive cure chemistry[J].International Journal of Adhesion & Adhesives,1999,19:49-57.
  • 8[7]Zhou H,Shen Y F,Wang J,et al.Studies of decomposition of H2O2 over manganese oxide octahedral molecular sieve materials[J].Journal of Catalysis,1998,176:321-328.
  • 9[8]Pietsch G J.Peculiarities of dielectric barrier discharges[J].Contrib Plasma Phys,2001,41(6):620-628.
  • 10[9]Atkinson R,Baulch D L,Cox R A,et al.Evaluated kinetic and photochemical data for atmospheric chemistrys[J].Journal of Physical and Chemical Reference Data,1997,26 (6):1329-1496.

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