摘要
碳笼氧化物对碳笼的官能团化研究具有重要意义,因而激起了人们的研究兴趣。本文对碳笼氧化物C60On、C70On、C76On、C78On及C80On的结构、电子光谱、红外光谱及核磁共振谱的研究进展进行综合评述。介绍了国内外近十几年来众多研究小组的工作,并结合作者本人在此方面的理论研究成果,进一步探索碳笼氧化物的结构特点以及光谱性质的规律性。在对C60及C70氧化物研究结果与实验符合的基础上,预测高碳笼氧化物的结构和光谱。
FuUerene oxides play an important role in studying functionalization of carbon dusters, which stimulated the interest of scientists. The progress in study of the structures, electronic spectra, IR spectra and NMR spectra for the fullerene oxides C60On, C70On, C76On, C78On and C80On is reviewed comprehensively. Relevant works worldwide hitherto are introduced. The regularity of structural characteristics and spectroscopy for fullerene oxides is further explored according to author＇ s own theoretical research in this field. Based on the agreement between calculating and experimental results on oxides of C60 and C70, the structures and spectra of oxides for higher fullerenes are predicted.
出处
《化学进展》
SCIE
CAS
CSCD
北大核心
2006年第11期1446-1451,共6页
Progress in Chemistry
作者简介
通讯联系人e-mail：wushi@zju．edu．cn
